磷烯光催化分解水研究进展

doi:10.15541/jim20190307

无机材料学报 ›› 2020, Vol. 35 ›› Issue (6): 647-653.DOI: 10.15541/jim20190307 CSTR: 32189.14.10.15541/jim20190307

磷烯光催化分解水研究进展

郑云^1,²,陈亦琳¹,高碧芬¹,林碧洲¹

^1. 华侨大学材料科学与工程学院, 厦门 361021
^2. 福州大学化学学院, 能源与环境光催化国家重点实验室, 福州 350116

收稿日期:2019-06-24 修回日期:2019-08-23 出版日期:2020-06-20 网络出版日期:2019-09-18
作者简介:郑云(1990-), 女, 博士, 讲师. E-mail: zheng-yun@hqu.edu.cn;
ZHENG Yun(1990-), female, PhD, lecturer. E-mail: zheng-yun@hqu.edu.cn
基金资助:
国家自然科学基金(21902051);福建省自然科学基金(2019J05090);福建省自然科学基金(2017J01014);福建省石墨烯复合材料研究中心(2017H2001);华侨大学科研基金(605-50Y17060);福州大学能源与环境光催化国家重点实验室开放课题(SKLPEE-201803)

Progress on Phosphorene for Photocatalytic Water Splitting

ZHENG Yun^1,²,CHEN Yilin¹,GAO Bifen¹,LIN Bizhou¹

^1. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
^2. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, China

Received:2019-06-24 Revised:2019-08-23 Published:2020-06-20 Online:2019-09-18
Supported by:
National Natural Science Foundation of China(21902051);Natural Science Foundation of Fujian Province(2019J05090);Natural Science Foundation of Fujian Province(2017J01014);Graphene Power and Composite Research Center of Fujian Province(2017H2001);Scientific Research Funds of Huaqiao University(605-50Y17060);The Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment of Fuzhou University(SKLPEE-201803)

摘要/Abstract

摘要：

半导体光催化分解水被认为是解决全球能源短缺和环境污染问题的潜在途径之一。近年来, 磷烯(BP)由于具有带隙可调、空穴迁移率高、吸收光谱宽等特性而在光催化分解水方面得到了广泛关注。本文综述了国内外近年来在磷烯光催化分解水领域所取得的重要研究进展, 总结了磷烯基光催化剂的合成方法、表面修饰和异质结构构建等改性策略, 阐述了磷烯基光催化剂的构-效关系和电荷转移机制, 并展望了磷烯基光催化剂所面临的机遇和挑战, 揭示了磷烯基材料在太阳能利用和转化方面的重要应用潜力。

关键词: 磷烯, 光催化, 分解水, 二维材料, 综述

Abstract:

Semiconductor photocatalytic water splitting has been considered as a potential strategy to overcome global energy shortage and environmental pollution. In recent years, phosphorene (BP) attracted great attention in photocatalytic water splitting due to its adjustable band gap, high hole mobility and wide absorption spectrum. This review summarizes the recent significant advances on designing high-performance BP-based photocatalysts for water splitting. The synthetic methods and modification strategies (e.g., surface modification and heterostructure design) of BP-based photocatalysts are described. Furthermore, in order to elucidate the structure-activity relationship of BP-based photocatalysts, the charge transfer mechanism is illustrated. Finally, the ongoing challenges and opportunities for the future development of BP-based photocatalysts in the exciting research area are highlighted.

Key words: phosphorene, photocatalysis, water splitting, two-dimensional materials, review

中图分类号:

O643

郑云,陈亦琳,高碧芬,林碧洲. 磷烯光催化分解水研究进展[J]. 无机材料学报, 2020, 35(6): 647-653.

ZHENG Yun,CHEN Yilin,GAO Bifen,LIN Bizhou. Progress on Phosphorene for Photocatalytic Water Splitting[J]. Journal of Inorganic Materials, 2020, 35(6): 647-653.

图/表 9

图1 磷烯的合成、表面修饰、异质结构设计及光催化分解水应用

Fig. 1 Synthesis, surface modification and heterostructure design of phosphorene-based photocatalysts for half-reactions and overall reactions of water splitting

图2 在pH=8.0的一般条件下沿a轴7%拉伸应变, 沿b轴5%拉伸应变时磷烯的能带图[13]

Fig. 2 Band edge alignments of phosphorene at ambient condition, under 7% tensile strain along a axis and 5% tensile strain along b axis when pH=8.0[13]

图3 BP-BM纳米片的合成示意图[15]

Fig. 3 Schematic diagram of the synthetic process of BP-BM nanosheets[15]

图4 溶剂热法合成磷烯纳米片的示意图[16]

Fig. 4 Schematic illustration of the preparation of few-layered BP nanosheets by a solvothermal process[16]

图5 BP/CN催化剂在可见光和近红外光驱动下光催化分解水的机理示意图[29]

Fig. 5 Schematic diagram for the visible and NIR light driven photocatalytic H2 evolution reaction over BP/CN catalyst[29]

图6 CdS与BP复合催化剂的光催化分解水的机理示意图[34]

Fig. 6 Schematic illustration of the mechanism of CdS and BP hybrid catalyst for photocatalytic water splitting[34]

图7 BP-Au/LTO在(a)可见光和(b)近红外光照射下光催化制取氢气的原理图[39]

Fig. 7 Schematic diagrams of photocatalytic H2 production using BP-Au/LTO under (a)visible and (b)NIR light irradiation[39]

图8 可见光照射下BP/BiVO4的Z型光催化裂解水系统原理图[45]

Fig. 8 Schematic diagram of Z-scheme photocatalytic water splitting system using BP/BiVO4 under visible light irradiation[45]

图9 (a)BP/CN异质结构光催化剂在可见光照射下产生超氧自由基(·O2-)的电子自旋共振谱图, (b)在可见光照射下降解四唑氮蓝溶液以测定BP/CN复合材料产生·O2-的性能曲线[46]

Fig. 9 (a) Electron spin resonance spectra of ·O2- radicals over BP/CN hybrid with visible-light irradiation, and (b) time-dependent degradation of nitroblue tetrazolium solution to detect ·O2- evolution over BP/CN hybrid under visible-light irradiation[46]

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磷烯光催化分解水研究进展

Progress on Phosphorene for Photocatalytic Water Splitting

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