磷烯光催化分解水研究进展

doi:10.15541/jim20190307

无机材料学报 ›› 2020, Vol. 35 ›› Issue (6): 647-653.DOI: 10.15541/jim20190307 CSTR: 32189.14.10.15541/jim20190307

磷烯光催化分解水研究进展

郑云^1,²,陈亦琳¹,高碧芬¹,林碧洲¹

^1. 华侨大学材料科学与工程学院, 厦门 361021
^2. 福州大学化学学院, 能源与环境光催化国家重点实验室, 福州 350116

收稿日期:2019-06-24 修回日期:2019-08-23 出版日期:2020-06-20 网络出版日期:2019-09-18
作者简介:郑云(1990-), 女, 博士, 讲师. E-mail: zheng-yun@hqu.edu.cn;
ZHENG Yun(1990-), female, PhD, lecturer. E-mail: zheng-yun@hqu.edu.cn
基金资助:
国家自然科学基金(21902051);福建省自然科学基金(2019J05090);福建省自然科学基金(2017J01014);福建省石墨烯复合材料研究中心(2017H2001);华侨大学科研基金(605-50Y17060);福州大学能源与环境光催化国家重点实验室开放课题(SKLPEE-201803)

Progress on Phosphorene for Photocatalytic Water Splitting

ZHENG Yun^1,²,CHEN Yilin¹,GAO Bifen¹,LIN Bizhou¹

^1. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
^2. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, China

Received:2019-06-24 Revised:2019-08-23 Published:2020-06-20 Online:2019-09-18
Supported by:
National Natural Science Foundation of China(21902051);Natural Science Foundation of Fujian Province(2019J05090);Natural Science Foundation of Fujian Province(2017J01014);Graphene Power and Composite Research Center of Fujian Province(2017H2001);Scientific Research Funds of Huaqiao University(605-50Y17060);The Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment of Fuzhou University(SKLPEE-201803)

摘要/Abstract

摘要：

半导体光催化分解水被认为是解决全球能源短缺和环境污染问题的潜在途径之一。近年来, 磷烯(BP)由于具有带隙可调、空穴迁移率高、吸收光谱宽等特性而在光催化分解水方面得到了广泛关注。本文综述了国内外近年来在磷烯光催化分解水领域所取得的重要研究进展, 总结了磷烯基光催化剂的合成方法、表面修饰和异质结构构建等改性策略, 阐述了磷烯基光催化剂的构-效关系和电荷转移机制, 并展望了磷烯基光催化剂所面临的机遇和挑战, 揭示了磷烯基材料在太阳能利用和转化方面的重要应用潜力。

关键词: 磷烯, 光催化, 分解水, 二维材料, 综述

Abstract:

Semiconductor photocatalytic water splitting has been considered as a potential strategy to overcome global energy shortage and environmental pollution. In recent years, phosphorene (BP) attracted great attention in photocatalytic water splitting due to its adjustable band gap, high hole mobility and wide absorption spectrum. This review summarizes the recent significant advances on designing high-performance BP-based photocatalysts for water splitting. The synthetic methods and modification strategies (e.g., surface modification and heterostructure design) of BP-based photocatalysts are described. Furthermore, in order to elucidate the structure-activity relationship of BP-based photocatalysts, the charge transfer mechanism is illustrated. Finally, the ongoing challenges and opportunities for the future development of BP-based photocatalysts in the exciting research area are highlighted.

Key words: phosphorene, photocatalysis, water splitting, two-dimensional materials, review

中图分类号:

O643

郑云,陈亦琳,高碧芬,林碧洲. 磷烯光催化分解水研究进展[J]. 无机材料学报, 2020, 35(6): 647-653.

ZHENG Yun,CHEN Yilin,GAO Bifen,LIN Bizhou. Progress on Phosphorene for Photocatalytic Water Splitting[J]. Journal of Inorganic Materials, 2020, 35(6): 647-653.

图/表 9

图1 磷烯的合成、表面修饰、异质结构设计及光催化分解水应用

Fig. 1 Synthesis, surface modification and heterostructure design of phosphorene-based photocatalysts for half-reactions and overall reactions of water splitting

图2 在pH=8.0的一般条件下沿a轴7%拉伸应变, 沿b轴5%拉伸应变时磷烯的能带图[13]

Fig. 2 Band edge alignments of phosphorene at ambient condition, under 7% tensile strain along a axis and 5% tensile strain along b axis when pH=8.0[13]

图3 BP-BM纳米片的合成示意图[15]

Fig. 3 Schematic diagram of the synthetic process of BP-BM nanosheets[15]

图4 溶剂热法合成磷烯纳米片的示意图[16]

Fig. 4 Schematic illustration of the preparation of few-layered BP nanosheets by a solvothermal process[16]

图5 BP/CN催化剂在可见光和近红外光驱动下光催化分解水的机理示意图[29]

Fig. 5 Schematic diagram for the visible and NIR light driven photocatalytic H2 evolution reaction over BP/CN catalyst[29]

图6 CdS与BP复合催化剂的光催化分解水的机理示意图[34]

Fig. 6 Schematic illustration of the mechanism of CdS and BP hybrid catalyst for photocatalytic water splitting[34]

图7 BP-Au/LTO在(a)可见光和(b)近红外光照射下光催化制取氢气的原理图[39]

Fig. 7 Schematic diagrams of photocatalytic H2 production using BP-Au/LTO under (a)visible and (b)NIR light irradiation[39]

图8 可见光照射下BP/BiVO4的Z型光催化裂解水系统原理图[45]

Fig. 8 Schematic diagram of Z-scheme photocatalytic water splitting system using BP/BiVO4 under visible light irradiation[45]

图9 (a)BP/CN异质结构光催化剂在可见光照射下产生超氧自由基(·O2-)的电子自旋共振谱图, (b)在可见光照射下降解四唑氮蓝溶液以测定BP/CN复合材料产生·O2-的性能曲线[46]

Fig. 9 (a) Electron spin resonance spectra of ·O2- radicals over BP/CN hybrid with visible-light irradiation, and (b) time-dependent degradation of nitroblue tetrazolium solution to detect ·O2- evolution over BP/CN hybrid under visible-light irradiation[46]

参考文献 55

[1]	FUJISHIMA A, HONDA K . Electrochemical photolysis of water at a semiconductor electrode. Nature, 1972,238(5358):37-38. DOI URL
[2]	ZHENG D, ZHANG G, WANG X . Integrating CdS quantum dots on hollow graphitic carbon nitride nanospheres for hydrogen evolution photocatalysis. Appl. Catal. B-Environ, 2015,179:479-488. DOI URL
[3]	LU Q, HUA L, CHEN Y , et al. Preparation and property of oxygen- deficient Bi₂WO₆-_x photocatalyst active in visible light. J. Inorg. Mater., 2015,30(4):413-419. DOI URL
[4]	WAN J, HU D, LU P , et al. Preparation of anatase TiO₂ nanocube with exposed (001) facet and its photocatalytic properties. J. Inorg. Mater., 2016,31(8):845-849. DOI URL
[5]	YI Z, YE J, KIKUGAWA N , et al. An orthophosphate semiconductor with photooxidation properties under visible-light irradiation. Nat. Mater., 2010,9:559. DOI URL
[6]	WANG X, MAEDA K, THOMAS A , et al. A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater., 2008,8:76. DOI URL
[7]	BAI Y, WILBRAHAM L, SLATER B J , et al. Accelerated discovery of organic polymer photocatalysts for hydrogen evolution from water through the integration of experiment and theory. J. Am. Chem. Soc., 2019,141(22):9063-9071. DOI URL
[8]	ZHAO C, CHEN Z, XU J , et al. Probing supramolecular assembly and charge carrier dynamics toward enhanced photocatalytic hydrogen evolution in 2D graphitic carbon nitride nanosheets. Appl. Catal. B-Environ, 2019,256:117867. DOI URL
[9]	YANG X, TIAN L, ZHAO X , et al. Interfacial optimization of g- C₃N₄-based Z-scheme heterojunction toward synergistic enhancement of solar-driven photocatalytic oxygen evolution. Appl. Catal. B-Environ, 2019,244:240-249. DOI URL
[10]	LI J, LI H, ZHAN G , et al. Solar water splitting and nitrogen fixation with layered bismuth oxyhalides. Acc. Chem. Res., 2017,50(1):112-121. DOI URL
[11]	LI B, LAI C, ZENG G , et al. Black phosphorus, a rising star 2D nanomaterial in the post-graphene era: synthesis, properties, modifications, and photocatalysis applications. Small, 2019,15(8):1804565. DOI URL
[12]	YAN J, VERMA P, KUWAHARA Y , et al. Recent progress on black phosphorus-based materials for photocatalytic water splitting. Small Methods, 2018,2(12):1800212. DOI URL
[13]	SA B, LI Y L, QI J , et al. Strain engineering for phosphorene: the potential application as a photocatalyst. J. Phys. Chem. C, 2014,118(46):26560-26568. DOI URL
[14]	RAHMAN MZ, BATMUNKH M, BAT-ERDENE M , et al. p-type BP nanosheet photocatalyst with AQE of 3.9% in the absence of a noble metal cocatalyst: investigation and elucidation of photophysical properties. J. Mater. Chem. A, 2018,6(38):18403-18408. DOI URL
[15]	ZHU X, ZHANG T, SUN Z , et al. Black phosphorus revisited: a missing metal-free elemental photocatalyst for visible light hydrogen evolution. Adv. Mater., 2017,29(17):1605776. DOI URL
[16]	TIAN B, TIAN B, SMITH B , et al. Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution. Proc. Natl. Acad. Sci., 2018,115(17):4345-4350. DOI URL
[17]	ZHAO G, WANG T, SHAO Y , et al. A novel mild phase-transition to prepare black phosphorus nanosheets with excellent energy applications. Small, 2017,13(7):1602243. DOI URL
[18]	ZHU M, ZHAI C, FUJITSUKA M , et al. Noble metal-free near- infrared-driven photocatalyst for hydrogen production based on 2D hybrid of black phosphorus/WS₂. Appl. Catal. B-Environ, 2018,221:645-651. DOI URL
[19]	YUAN Y J, WANG P, LI Z , et al. The role of bandgap and interface in enhancing photocatalytic H₂ generation activity of 2D-2D black phosphorus/MoS₂ photocatalyst. Appl. Catal. B-Environ, 2019,242:1-8. DOI URL
[20]	TIAN B, TIAN B, SMITH B , et al. Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K. Nat. Commun., 2018,9:1397. DOI URL
[21]	LIANG Q, SHI F, XIAO X , et al. In situ growth of CoP nanoparticles anchored on black phosphorus nanosheets for enhanced photocatalytic hydrogen production. ChemCatChem, 2018,10(10):2179-2183. DOI URL
[22]	VISHNOI P, GUPTA U, PANDEY R , et al. Stable functionalized phosphorenes with photocatalytic HER activity. J. Mater. Chem. A, 2019,7(12):6631-6637. DOI URL
[23]	WU J, HUANG S, JIN Z , et al. Black phosphorus: an efficient co- catalyst for charge separation and enhanced photocatalytic hydrogen evolution. J. Mater. Sci., 2018,53(24):16557-16566. DOI URL
[24]	ELBANNA O, ZHU M, FUJITSUKA M , et al. Black phosphorus sensitized TiO₂ mesocrystal photocatalyst for hydrogen evolution with visible and near-infrared light irradiation. ACS Catal., 2019,9(4):3618-3626. DOI URL
[25]	ZHAO H, LIU H, SUN R , et al. A Zn_0.5Cd_0.5S photocatalyst modified by 2D black phosphorus for efficient hydrogen evolution from water. ChemCatChem, 2018,10(19):4395-4405. DOI URL
[26]	ZHENG Y, LIN L, YE X , et al. Helical graphitic carbon nitrides with photocatalytic and optical activities. Angew. Chem. Int. Ed., 2014,53(44):11926-11930. DOI URL
[27]	ZHENG Y, LIN L, WANG B , et al. Graphitic carbon nitride polymers toward sustainable photoredox catalysis. Angew. Chem. Int. Ed., 2015,54(44):12868-12884. DOI URL
[28]	ZHENG Y, YU Z, LIN F , et al. Sulfur-doped carbon nitride polymers for photocatalytic degradation of organic pollutant and reduction of Cr(VI). Molecules, 2017,22(4):572. DOI URL
[29]	ZHU M, KIM S, MAO L , et al. Metal-free photocatalyst for H₂ evolution in visible to near-infrared region: black phosphorus/graphitic carbon nitride. J. Am. Chem. Soc., 2017,139(37):13234-13242. DOI URL
[30]	WEN M, WANG J, TONG R , et al. A low-cost metal-free photocatalyst based on black phosphorus. Adv. Sci., 2019,6(1):1801321. DOI URL
[31]	RAN J R, GUO W W, WANG H L , et al. Metal-free 2D/2D phosphorene/g-C₃N₄ van der Waals heterojunction for highly enhanced visible-light photocatalytic H₂ production. Adv. Mater., 2018,30(25):1800128. DOI URL
[32]	DU H, LIU Y, SHEN C , et al. Nanoheterostructured photocatalysts for improving photocatalytic hydrogen production. Chin. J. Catal., 2017,38(8):1295-1306. DOI URL
[33]	LEI W, MI Y, FENG R , et al. Hybrid 0D-2D black phosphorus quantum dots-graphitic carbon nitride nanosheets for efficient hydrogen evolution. Nano Energy, 2018,50:552-561. DOI URL
[34]	RAN J, ZHU B, QIAO S Z . Phosphorene co-catalyst advancing highly efficient visible-light photocatalytic hydrogen production. Angew. Chem. Int. Ed., 2017,56(35):10373-10377. DOI URL
[35]	HU J, CHEN D , MO Z et al. Z-scheme 2D/2D heterojunction of black phosphorus/monolayer Bi₂WO₆ nanosheets with enhanced photocatalytic activities. Angew. Chem. Int. Ed., 2019,58(7):2073-2077. DOI URL
[36]	ZHANG Y, WANG L, PARK S H , et al. Single near-infrared-laser driven Z-scheme photocatalytic H₂ evolution on upconversion material@Ag₃PO₄@black phosphorus. Chem. Eng. J., 2019,375:121967. DOI URL
[37]	ZHU M, OSAKADA Y, KIM S , et al. Black phosphorus: a promising two dimensional visible and near-infrared-activated photocatalyst for hydrogen evolution. Appl. Catal. B-Environ, 2017,217:285-292. DOI URL
[38]	ZHU M, FUJITSUKA M, ZENG L , et al. Dual function of graphene oxide for assisted exfoliation of black phosphorus and electron shuttle in promoting visible and near-infrared photocatalytic H₂ evolution. Appl. Catal. B-Environ, 2019,256:117864. DOI URL
[39]	ZHU M, CAI X, FUJITSUKA M , et al. Au/La₂Ti₂O₇ nanostructures sensitized with black phosphorus for plasmon-enhanced photocatalytic hydrogen production in visible and near-infrared light. Angew. Chem. Int. Ed., 2017,56(8):2064-2068. DOI URL
[40]	RAN J, WANG X, ZHU B , et al. Strongly interactive 0D/2D heterostructure of a Zn_xCd₁-_xS nanoparticle decorated phosphorene nanosheet for enhanced visible-light photocatalytic H₂ production. Chem. Commun., 2017,53(71):9882-9885. DOI URL
[41]	REDDY DA, KIM E H, GOPANNAGARI M , et al. Few layered black phosphorus/MoS₂ nanohybrid: a promising co-catalyst for solar driven hydrogen evolution. Appl. Catal. B-Environ, 2019,241:491-498. DOI URL
[42]	BOPPELLA R, YANG W, TAN J , et al. Black phosphorus supported Ni₂P co-catalyst on graphitic carbon nitride enabling simultaneous boosting charge separation and surface reaction. Appl. Catal. B-Environ, 2019,242:422-430. DOI URL
[43]	HU J, JI Y, MO Z , et al. Engineering black phosphorus to porous g-C₃N₄-metal-organic framework membrane: a platform for highly boosting photocatalytic performance. J. Mater. Chem. A, 2019,7(9):4408-4414. DOI URL
[44]	YAN J, JI Y, KONG L , et al. Black phosphorus-based compound with few layers for photocatalytic water oxidation. ChemCatChem, 2018,10(16):3424-3428. DOI URL
[45]	ZHU M, SUN Z, FUJITSUKA M , et al. Z-scheme photocatalytic water splitting on a 2D heterostructure of black phosphorus/bismuth vanadate using visible light. Angew. Chem. Int. Ed., 2018,57(8):2160-2164. DOI URL
[46]	ZHENG Y, YU Z, OU H , et al. Black phosphorus and polymeric carbon nitride heterostructure for photoinduced molecular oxygen activation. Adv. Funct. Mater., 2018,28(10):1705407. DOI URL
[47]	RUDENKO A N, KATSNELSON M I . Quasiparticle band structure and tight-binding model for single- and bilayer black phosphorus. Phys. Rev. B, 2014,89(20):201408. DOI URL
[48]	TRAN V, SOKLASKI R, LIANG Y , et al. Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Phys. Rev. B, 2014,89(23):235319. DOI URL
[49]	ZHOU Q, CHEN Q, TONG Y , et al. Light-induced ambient degradation of few-layer black phosphorus: mechanism and protection. Angew. Chem. Int. Ed., 2016,55(38):11437-11441. DOI URL
[50]	QIU M, WANG D, LIANG W , et al. Novel concept of the smart NIR-light-controlled drug release of black phosphorus nanostructure for cancer therapy. Proc. Natl. Acad. Sci., 2018,115(3):501-506. DOI URL
[51]	PENG X, WEI Q, COPPLE A . Strain-engineered direct-indirect band gap transition and its mechanism in two-dimensional phosphorene. Phys. Rev. B, 2014,90(8):085402. DOI URL
[52]	TANG X, LIANG W, ZHAO J , et al. Fluorinated phosphorene: electrochemical synthesis, atomistic fluorination, and enhanced stability. Small, 2017,13(47):1702739. DOI URL
[53]	MAO L, CAI X, YANG S , et al. Black phosphorus-CdS-La₂Ti₂O₇ ternary composite: effective noble metal-free photocatalyst for full solar spectrum activated H₂ production. Appl. Catal. B-Environ, 2019,242:441-448. DOI URL
[54]	FENG R, LEI W, LIU G , et al. Visible- and NIR-light responsive black-phosphorus-based nanostructures in solar fuel production and environmental remediation. Adv. Mater., 2018,30(49):1804770. DOI URL
[55]	ZHANG K, JIN B, PARK C , et al. Black phosphorene as a hole extraction layer boosting solar water splitting of oxygen evolution catalysts. Nat. Commun., 2019,10(1):2001. DOI URL

磷烯光催化分解水研究进展

Progress on Phosphorene for Photocatalytic Water Splitting

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 55

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈明俊, 缪洪康, 肖英俊, 邓建波, 张翔, 赵九蓬, 李垚. 光-热双响应材料研究进展: 从设计策略到智能窗应用[J]. 无机材料学报, 2026, 41(6): 723-738.
[2]	宋坤洁, 解荣军. 机器学习驱动新型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 689-703.
[3]	胡钰晴, 朱一新, 乐先浩, 万青. 钽酸锂晶圆减薄技术及其热释电红外探测器应用进展[J]. 无机材料学报, 2026, 41(6): 764-774.
[4]	刘春帆, 陈科, 葛芳芳, 黄庆. 核用耐铅铋腐蚀涂层的研究进展[J]. 无机材料学报, 2026, 41(6): 775-786.
[5]	胡扬, 谢敏, 张筱怡, 李想, 郭新伟, 姜南, 周文瀚, 张胜利, 曾海波. 计算与数据驱动环保型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 704-722.
[6]	王俊卜, 黄泽皑, 杨茗凯, 蒙颖, 周明炜, 周莹. 甲烷转化用抗积碳催化材料研究进展[J]. 无机材料学报, 2026, 41(6): 739-750.
[7]	王金文, 杨振, 周欢, 夏丹, 杨磊. 可注射无机材料及其生物医学应用[J]. 无机材料学报, 2026, 41(6): 751-763.
[8]	孙丽, 徐永善, 高义华. 石墨烯/Bi₂O₂Se/石墨烯双异质结器件的光探测和仿生突触研究[J]. 无机材料学报, 2026, 41(6): 795-804.
[9]	李涵涛, 沈强, 罗国强, 王雪飞, 高明, 陈晨. 机械球磨法调控硅基负极材料结构与性能的研究进展[J]. 无机材料学报, 2026, 41(5): 561-572.
[10]	解陈一, 缪花明, 张蔚然, 刘荣军, 王衍飞, 李端. 理论计算在高熵陶瓷领域的研究进展[J]. 无机材料学报, 2026, 41(5): 545-560.
[11]	李璇, 叶奎材, 冯佳音, 邱家军, 钱文昊, 邢敏. 钛基牙种植体表面改性促进软组织封闭的研究进展[J]. 无机材料学报, 2026, 41(4): 432-444.
[12]	彭德招, 李瑞, 王文鸿, 王梓瑞, 章志珍. 钠氯化物固态电解质研究进展[J]. 无机材料学报, 2026, 41(4): 409-420.
[13]	陈坤, 姜勇刚, 冯军宗, 李良军, 胡艺洁, 冯坚. 锆酸镧多孔隔热材料研究进展[J]. 无机材料学报, 2026, 41(4): 421-431.
[14]	韦连金, 齐志杰, 汪信, 朱俊武, 付永胜. 纳米金刚石改性及其在电催化氧还原反应中的应用[J]. 无机材料学报, 2026, 41(3): 273-288.
[15]	刘占一, 李勉, 欧阳晓平, 柴之芳, 黄庆. 干法后处理熔盐中Sr/Cs去除方法的研究进展[J]. 无机材料学报, 2026, 41(2): 150-158.