聚合物材料表面原子氧防护技术的研究进展

doi:10.15541/jim20180515

无机材料学报 ›› 2019, Vol. 34 ›› Issue (7): 685-693.DOI: 10.15541/jim20180515 CSTR: 32189.14.10.15541/jim20180515

所属专题：药物载体与防护材料

• 综述 • 下一篇

聚合物材料表面原子氧防护技术的研究进展

李昊耕^1,²,谷红宇¹,章俞之^1,²(),宋力昕^1,²(),吴岭南¹,齐振一¹,张涛¹

^1. 中国科学院上海硅酸盐研究所, 中国科学院特种无机涂层重点实验室, 上海 200050
^2. 中国科学院大学材料与光电研究中心, 北京 100049

收稿日期:2018-10-29 修回日期:2018-11-29 出版日期:2019-07-20 网络出版日期:2019-06-26
作者简介:李昊耕(1994-), 男, 博士研究生. E-mail:lihaogeng@student.sic.ac.cn
基金资助:
"十三五"装备预研项目(170441422174);国家自然科学基金青年项目(51802332);上海市青年科技英才扬帆计划项目(18YF1427100);上海硅酸盐研究所创新项目(Y85ZC2120G);上海硅酸盐研究所创新项目(Y75ZC2120G)

Surface Protection of Polymer Materials from Atomic Oxygen: a Review

LI Hao-Geng^1,²,GU Hong-Yu¹,ZHANG Yu-Zhi^1,²(),SONG Li-Xin^1,²(),WU Ling-Nan¹,QI Zhen-Yi¹,ZHANG Tao¹

^1. Key Laboratory of Inorganic Coatings Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
^2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2018-10-29 Revised:2018-11-29 Published:2019-07-20 Online:2019-06-26
Supported by:
Equipment Pre-research Foundation of China(170441422174);National Natural Science Foundation of China(51802332);Shanghai Sailing Program(18YF1427100);The Innovation Fund of Computational Materials Center from SICCAS(Y85ZC2120G);The Innovation Fund of Computational Materials Center from SICCAS(Y75ZC2120G)

摘要/Abstract

摘要：

聚合物材料具有质量轻、强度高等优点, 常被用作航天器表面的复合结构基材。原子氧是低地球轨道空间中成分含量最高的粒子之一, 对暴露在航天器表面的聚合物材料易形成大通量、高能量轰击, 造成其表面氧化侵蚀和质量损失, 使聚合物材料的性能发生不同程度的衰退, 也是导致航天器件可靠性降低、工作寿命缩短的主要环境因素。本文对当前国内外通用的几种聚合物材料表面原子氧防护技术进行了整理归纳, 其中表面化学改性方法结合了体材改性和常用防护涂层的优点, 得到的有机/无机复合改性防护层具有较好的综合防护性能。文中分析了近年来由计算模拟法开展原子氧与表面防护材料相关作用机理的研究, 指出采用计算模拟结合试验的研究方法, 有可能从本质上揭示复合改性层与原子氧的作用机理, 从而促进原子氧防护材料与防护技术的研究发展。

关键词: 原子氧, 聚合物, 空间防护, 表面改性, 聚酰亚胺, 计算模拟, 综述

Abstract:

Polymers, as substrate of composite material on the surface of spacecraft, have such advantages as light mass and high strength. Atomic oxygen (AO) is one of the highest content particles of low earth orbit, and high-energy high-flux AO bombardment causes the polymers’ surface erosion and mass loss at different degree, resulting in polymers degradation. Thus, AO is one of major threats in space environment that reduces reliability of space devices and shortens their working life span. This review summarized current global protection technologies from AO in recent years. Among them, surface chemical modification method with advantages of body-modification and protection coating, providing organic/inorganic composite with modified layer through comprehensive protection performance. This review discussed the method to explore the AO protection reaction mechanism by computational simulation. Computational simulation combined with experiments may reveal nature of the protection, facilitate future researches on AO protection, and provide guidance for fabrication surface polymer materials used in domestic parts of the aerospace craft, especially the large-scale flexible space solar cell array

Key words: atomic oxygen, polymer, space protection, surface modification, polyimide, computational simulation, review

中图分类号:

李昊耕,谷红宇,章俞之,宋力昕,吴岭南,齐振一,张涛. 聚合物材料表面原子氧防护技术的研究进展[J]. 无机材料学报, 2019, 34(7): 685-693.

LI Hao-Geng,GU Hong-Yu,ZHANG Yu-Zhi,SONG Li-Xin,WU Ling-Nan,QI Zhen-Yi,ZHANG Tao. Surface Protection of Polymer Materials from Atomic Oxygen: a Review[J]. Journal of Inorganic Materials, 2019, 34(7): 685-693.

图/表 7

图1 笼型倍半硅氧烷分子结构式(POSS)[24]

Fig. 1 Molecular structure of polyhedral oligomeric silsesquioxane (POSS) [24]

图2 PI表面改性生成聚酰胺酸示意图[50]

Fig. 2 PI surface modification to form polyamic acid: NaOH hydrolysis of PI (Step 1) to form sodium salt of polyamic acid followed by acidification (Step 2) to form polyamic acid[50]

图3 AO轰击(有效积累通量约为2.0×1020 atoms/cm2)下的样品SEM照片[52,53], 未经处理的(a)被遮挡区域及(b)暴露区域; PhotosilTM处理后的(c)被遮挡区域及(d)暴露区域, 和暴露的(e) Implantox处理后的区域以及(f)无防护处理区域

Fig. 3 SEM images of AO exposed (effective fluence ~2.0×1020atoms/cm2) samples: untreated samples[52,53] (a) masked section and (b) exposed section, images of ImplantoxTM treatment being (c) masked and (d) exposed sections, and AO exposed (e) Implantox-treated section and (f) untreated sections

图4 暴露在原子氧辐照后的样品表面形貌[56]: (a)无防护处理的原始PI和(b)镀覆SiO2防护层的PI

Fig. 4 SEM images of AO exposed (effective fluence~ 2.0×1020 atoms/cm2) sample surfaces morphology[56]: untreated original PI and (b) SiO2 coated PI

表1 AO对PI样品的侵蚀量[56]

Table 1 Erosion yield of atomic oxygen on PI samples[56]

Sample	F/(×10²⁰ O atom?cm^-2)	ΔM/mg	A/cm²	(ΔM/A)/(mg?cm^-2)	E/(×10^-24, cm³atom^-1)
Kapton	3.09	5.03	3.14	1.60	3.65
SiO_x coated PI	3.09	0.17	3.14	0.05	0.12

图5 不同PI防护体系遭受AO轰击前(左侧, t=0)和轰击后(右侧, t=35 ps)的计算模拟图像[71]: PI枝接(a)15wt% POSS 和(b) 30wt% POSS; 15wt%石墨稀采用(c)随机取向和(d)定向排列

Fig. 5 Initial (left, t=0) and final (right, t=35 ps) simulation snapshots of different PI protection system under AO impact[71]:PI-grafted (a) 15wt% POSS and (b) 30wt% POSS; 15wt% graphene (c) randomly oriented and (d) aligned

图6 氧原子通过匹配的双空位缺陷渗透进入双层石墨烯隔层的DFT势垒计算[74]

Fig. 6 Potential barrier of an O atom permeating into interlayer of double-layer graphene with matched divacancy defect[74]

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聚合物材料表面原子氧防护技术的研究进展

Surface Protection of Polymer Materials from Atomic Oxygen: a Review

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