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退火温度对Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si异质结微观结构与性能的影响

任明放, 王 华
  

  1. 桂林电子科技大学信息材料科学与工程系, 桂林 541004
  • 收稿日期:2007-08-27 修回日期:2007-11-15 出版日期:2008-07-20 网络出版日期:2008-07-20

Effect of Annealing Temperature on Structure and Properties of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si Heterostructure

REN Ming-Fang, WANG Hua   

  1. Department of Information Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China
  • Received:2007-08-27 Revised:2007-11-15 Published:2008-07-20 Online:2008-07-20

摘要: 采用sol-gel工艺制备了Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si异质结. 研究了退火温度对异质结微观结构与生长行为、漏电流密度和C-V特性等的影响. 研究表明: 成膜温度较低时,SrBi2Ta2O9、Bi4Ti3O12均为多晶薄膜, 但随退火温度升高, Bi4Ti3O12薄膜沿c轴择优生长的趋势增强; 经不同退火温度处理的Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si异质结的C-V曲线均呈现顺时针非对称回滞特性, 且回滞窗口随退火温度升高而增大, 经700℃退火处理后异质结的最大回滞窗口达0.78V; 在550~700℃范围内, Pt/SrBi2Ta2O9/Bi4Ti3O12/\\p-Si异质结的漏电流密度先是随退火温度升高缓慢下降, 当退火温度超过650℃后漏电流密度明显增大, 经650℃退火处理的异质结的漏电流密度可达2.54×10-7A/cm2的最低值.

关键词: 退火温度, SrBi2Ta2O9, Bi4Ti3O12, 异质结

Abstract: Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructures were fabricated by sol-gel method. The effects of annealing temperature on microstructure, crystal growth behavior, leakage current density, and C-V characteristics of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure were investigated. The SrBi2Ta2O9/Bi4Ti3O12 multilayer thin films annealed at low temperature are polycrystalline, and grow in the preferred c-axis orientation with the increase of annealing temperature. The C-V curves of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure annealed at various temperatures all show a clockwise ferroelectric hysteresis loop. The widths of C-V hysteresis loops of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure increase with the increase of annealing temperature and reach a maximum of 0.78V when the heterostructure is annealed at 700℃. The leakage current density of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure decrease slowly with the increase of annealing temperature from 550℃ to 650℃. However, when the annealing temperature is above 650℃, the leakage current density of Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure increase evidently. The lowest leakage current density is 2.54×10-7A/cm2 when Pt/SrBi2Ta2O9/Bi4Ti3O12/p-Si heterostructure is annealed at 650℃.

Key words: annealing temperature, SrBi2Ta2O9, Bi4Ti3O12, heterostructure

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