溶剂热法合成不同形貌MnFe2O4纳米颗粒及其在污水处理中的应用

doi:10.3724/SP.J.1077.2014.13519

摘要/Abstract

摘要：

通过简单溶剂热法合成表面粗糙的立方体结构MnFe₂O₄颗粒, 样品粒径约为150 nm, 立方体表面球状突起的直径约为10 nm, 该特征增加了样品的比表面积。反应过程中, 通过改变表面活性剂CTAB的加入量, 有效影响晶体各个晶面方向的生长速度, 最终合成不同形貌的样品(立方体、多面体、正八面体结构)。合成样品在室温下都表现出典型的铁磁性质。通过对刚果红和重金属离子Cr^VI和Pb^II溶液的吸附实验证明, 表面粗糙的立方体结构MnFe₂O₄颗粒在污水处理过程中, 可以更高效地去除水中的污染物, 通过磁分离技术回收样品以便再利用, 提高废水净化率。

关键词: 磁性材料, 晶体生长, 微观结构, 污水处理

Abstract:

Manganese ferrite (MnFe₂O₄) with rough surface was synthesized by a simple solvothermal method. The average diameter of particles was about 150 nm, and the tubes of rough surface about 10 nm. Here, magnetic MnFe₂O₄ particles with different morphologies (cube, polyhedron and octahedron) were successfully prepared by controlling CTAB concentration. Both of the samples with different morphologies exhibit ferromagnetic behavior at room temperature. The saturation magnetization (M_s) and coercivity (H_c) of MnFe₂O₄ with non-smooth surface are 58.7 Am²/kg and 6.23 kA/m, respectively. The particles with rough surface also show good performance in removal of pollutants like Congo red (92.4 mg/g), Cr^VI(54.4 mg/g), and Pb^II(84.4 mg/g) from waste water by adsorption experiments. Because the particles are recollected by magnetic separation, the waste water purification rate can be improved, which expands the applications of magnetic materials.

Key words: magnetic materials, crystal growth, microstructure, water treatment

中图分类号:

O614

段连峰, 张雨, 王立民, 金松哲, 吴化. 溶剂热法合成不同形貌MnFe₂O₄纳米颗粒及其在污水处理中的应用[J]. 无机材料学报, 2014, 29(7): 763-768.

DUAN Lian-Feng, ZHANG Yu, WANG Li-Min, JIN Song-Zhe, WU Hua. Synthesis and Characterization of MnFe₂O₄ with Different Morphologies and Their Application in Water Treatment[J]. Journal of Inorganic Materials, 2014, 29(7): 763-768.

图/表 6

图1 样品S2 的低倍扫描电镜照片(a)、透射电镜照片(b)、高分辨率透射电镜照片及其电子衍射图(c)和XRD图谱(d)

Fig. 1 FESEM (a), TEM (b), HRTEM images and SEAD pattern (c) and XRD pattern (d) of sample S2

图2 样品S1、S3和S4的高倍扫描电镜照片

Fig. 2 Higher magnification FESEM images of samples S1, S3 and S4 (a) S1, 0 g; (b) S3,1 g; (c) S4, 2 g

图3 样品S1、S3和S4的XRD图谱

Fig. 3 XRD patterns of samples S1, S3 and S4

图4 在室温下测得不同形貌样品的磁滞回线表1 不同样品磁学参数

Fig. 4 Hysteresis loops of the magnetite with special morphologies tested at room temperature

表1 不同样品磁学参数

Table 1 Magnetism parameters of different samples

Samples	S2	S3	S4
M_s /(Am²·kg^-1)	58.7	76.7	61.3
M_{r /}(Am²·kg^-1)	6.5	1.3	7.4
H_c /(kA·m^-1)	6.23	0.95	6.87

图5 样品S2、S3、S4对CR、Cr6+、Pb2+溶液的吸附曲线(a、c、e)和样品S2对不同浓度CR、Cr6+、Pb2+溶液的吸附曲线(b、 d、f)

Fig. 5 Adsorption capacity of samples S2, S3 and S4 adsorbed CR, Cr6+ and Pb2+ solution (a, c and e) and adsorption capacity of sample S2 adsorbed CR, Cr6+ and Pb2+solution (b, d and f) with different concentrations

参考文献 28

[1]	CUI Y, LIEBER C M. Functional nanoscale electronic devices assembled using silicon nanowire building blocks. Science, 2001, 291(851): 851-853.
[2]	WANG X, ZHUANG J, PENG Q, et al. A general strategy for nanocrystal synthesis. Nature, 2005, 437(121-124): 121-124.
[3]	DUAN L F, JIA S S, ZHAO L J. Study on morphologies of Co microcrystals produced by solvothermal method with different solvents. Materials Research Bulletin, 2010, 45(4): 373-376.
[4]	LIU Q,LV L,WANG Y. Electric and magnetic properties of NiFe2O4- BaTiO3 composites synthesized by hydrothermalmethod. Bulletin of the Chinese Ceramic Society, 2012, 33(1): 50-55.
[5]	FU F L, WANG Q. Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage., 2011, 92(3): 407-418.
[6]	WANG Y H, LIN S H, JUAN R S. Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents. J. Hazard. Mater., 2003, 102(2/3): 291-302.
[7]	KURNIAWAN T A, CHAN G Y S, LO W H, et al. Physico- chemical treatment techniques for wastewater laden with heavy metals. Chem. Eng. J. , 2006, 118(1/2): 83-98.
[8]	LI M, QIAN F Y, LI X Y. Characterization of organic pollutants in bio-treated effluents of dyeing and textile wastewater and removal behavior during magnesium sulfate coagulation process. Environmental Chemistry, 2012, 31(1): 88-93.
[9]	MERIC S, KAPTAN D, OLMEZ T. Color and COD removal from wast-e-water containing Reactive Black 5 using Fenton's oxidation process. Chemosphere, 2004, 54(3): 435-441.
[10]	PAN B J, PAN B C, ZHANG W M, et al. Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters. Chem. Eng. J., 2009, 151(1/2/3): 19-29.
[11]	MISHRA S P, SINGH V K, TIWARI D. Radiotracer technique in adsorption study. 14. Efficient removal of mercury from aqueous solutions by hydrous zirco-nium oxide. Appl. Radiat. Isot. , 1996 47(1): 15-21.
[12]	VANBENSCHOTEN J E, REED B E, MATSUMOTO M R, et al. Metal removal by soil washing for an iron-oxide coated sandy soil. Water Environ. Res. , 1994(66): 168-174.
[13]	DING Z H, FENG J M. Surface characters of iron-(hydro) oxides andtheir adsorption of heavy metal ions. Acta Mineralogica Sinica, 2000(20): 349-352.
[14]	AGRAWAL A, SAHU K K. Kinetic and isotherm studies of cadmium adsorption on manganese nodule residue. J. Hazard. Mater., 2006(137): 915-924.
[15]	MANDAVIAN A R, MIRRAHIMI M A S. Efficient separation of heavy metal cations by anchoring polyacrylic acid on superparamagnetic magnetite nanoparticles through surface modification. Chem. Eng. J. , 2010, 159(1/2/3): 264-271.
[16]	ZHAO X, LV L, PAN B, et al. Polymer-supported nanoco-m-posites for environmental application-a review. Chem. Eng. J., 2011, 170(2/3): 381-394.
[17]	ZHAO M Y, DUAN L F, WU H, et al. Synthesis of hollow Fe3O4 submicrospheres and their adsorption-desorption capability for Congo red. Chin. J. Inorg. Chem., 2012, 28(10): 2186-2192.
[18]	WANG Y Q, CHENG R M, WEN Z, et al. Synthesis and characteriz-ation of single-crystalline MnFe2O4 ferrite nanocrystals and their possible application in water treatment. Eur. J.Inorg.Chem., 2011, 19(1): 2942-2947.
[19]	ZHUO NA, LI LI, GAO YU, et al. CTAB-assisted synthesis of nano-composite Ag/ZnO-TiO2 and its UV photocatalytic activity. Chin. J. Inorg. Chem., 2013, 29(5): 991-998.
[20]	ZHU Y F, ZHAO W R, CHEN H R, et al. A Simple one-pot self-assem-bly route to nanoporous and monodispersed Fe3O4 particles with oriented attachment structure and magnetic property. Phys. J. Chem. C, 2007, 111(14): 5281-5285.
[21]	DIMITROV D A, WYSIN G M. Effects of surface anisotropy on hysteresis in fine magnetic particles. Phys. Rev. B, 1994, 50(5): 3077-3084.
[22]	KODOMA R H, BERKOWITZ A E. Atomic-scale magnetic modeling of oxide nanoparticles. Phys. Rev. B, 1999, 59(9): 6321-6336.
[23]	WANG L X, LI J C, JIANG Q, et al. Water-soluble Fe3O4 nanopart-icles with high solubility for removal of heavy-metal ions from waste water. Dalton Trans., 2012, 41(15): 4544-4551.
[24]	GUO MING, HUANG FENG-QIN, LIU MI-MI, et al. Performance of binding interaction between Cr(Ⅵ) and serum proteome. Chin. J. Inorg.Chem., 2013, 29(5): 1037-1044.
[25]	WANG X S, CHEN J P. Biosorption of congo red from aqueous solution using wheat bran and rice bran: batch studies. Sep.Sci. Technol. , 2009, 44(6): 1452-1466.
[26]	PANDAG C, DAS S K, GUHA A K. Effect of method of crystallization on the IV-III and IV-II polymorphic transitions of ammonium nitrate. J. Hazard. Mater., 2009, 161(1): 373-379.
[27]	JIANG M Q, WANG Q P, JIN X Y, et al. Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay. J. Hazard. Mater., 2009, 170(1): 332-339.
[28]	HU J, LO I M C, CHEN G H. Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe2O4) nanoparticles. Langmuir, 2005, 21(24): 11173-11179.

溶剂热法合成不同形貌MnFe₂O₄纳米颗粒及其在污水处理中的应用

Synthesis and Characterization of MnFe₂O₄ with Different Morphologies and Their Application in Water Treatment

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 28

相关文章 15

编辑推荐

Metrics

本文评价

[1]	范武刚, 曹雄, 周响, 李玲, 赵冠楠, 张兆泉. 8YSZ陶瓷在模拟压水堆水环境中的耐腐蚀性能[J]. 无机材料学报, 2024, 39(7): 803-809.
[2]	姜灵毅, 庞生洋, 杨超, 张悦, 胡成龙, 汤素芳. C/SiC-BN复合材料的制备及氧化行为[J]. 无机材料学报, 2024, 39(7): 779-786.
[3]	薛轶凡, 李玮洁, 张中伟, 庞旭, 刘愚. 碳纤维布表面PyC界面相微观结构及均匀性的工艺调控[J]. 无机材料学报, 2024, 39(4): 399-408.
[4]	蔡豪, 汪琦航, 邹朝勇. 镁离子调控无定形碳酸钙制备一水碳酸钙结晶过程[J]. 无机材料学报, 2024, 39(11): 1275-1282.
[5]	郝永鑫, 秦娟, 孙军, 杨金凤, 李清连, 黄贵军, 许京军. 坩埚底角形状对提拉法生长同成分铌酸锂晶体的影响[J]. 无机材料学报, 2024, 39(10): 1167-1174.
[6]	秦娟, 梁丹丹, 孙军, 杨金凤, 郝永鑫, 李清连, 张玲, 许京军. 提拉法生长平肩同成分铌酸锂晶体的研究[J]. 无机材料学报, 2023, 38(8): 978-986.
[7]	吴爽, 苟燕子, 王永寿, 宋曲之, 张庆雨, 王应德. 高温热处理对国产KD-SA型SiC纤维组成结构与力学性能的影响[J]. 无机材料学报, 2023, 38(5): 569-576.
[8]	林思琪, 李艾燃, 付晨光, 李荣斌, 金敏. Zintl相Mg₃X₂(X=Sb, Bi)基晶体生长及热电性能研究进展[J]. 无机材料学报, 2023, 38(3): 270-279.
[9]	杨佳雪, 李雯, 王燕, 朱昭捷, 游振宇, 李坚富, 涂朝阳. Dy³⁺: Y₃Al₅O₁₂晶体的光谱与黄色激光性能[J]. 无机材料学报, 2023, 38(3): 350-356.
[10]	吴振, 李慧芳, 张中晗, 张振, 李阳, 蓝江河, 苏良碧, 武安华. 面向磁光应用的CeF₃晶体生长与性能表征[J]. 无机材料学报, 2023, 38(3): 296-302.
[11]	齐雪君, 张健, 陈雷, 王绍涵, 李翔, 杜勇, 陈俊锋. 坩埚下降法生长大尺寸Bi₁₂GeO₂₀晶体的宏观缺陷[J]. 无机材料学报, 2023, 38(3): 280-287.
[12]	齐占国, 刘磊, 王守志, 王国栋, 俞娇仙, 王忠新, 段秀兰, 徐现刚, 张雷. GaN单晶的HVPE生长与掺杂进展[J]. 无机材料学报, 2023, 38(3): 243-255.
[13]	张超逸, 唐慧丽, 李宪珂, 王庆国, 罗平, 吴锋, 张晨波, 薛艳艳, 徐军, 韩建峰, 逯占文. 新型GaN与ZnO衬底ScAlMgO₄晶体的研究进展[J]. 无机材料学报, 2023, 38(3): 228-242.
[14]	陈昆峰, 胡乾宇, 刘锋, 薛冬峰. 多尺度晶体材料的原位表征技术与计算模拟研究进展[J]. 无机材料学报, 2023, 38(3): 256-269.
[15]	李建波, 田震, 蒋全伟, 于砺锋, 康慧君, 曹志强, 王同敏. 不同元素掺杂对CaTiO₃微观结构及热电性能的影响[J]. 无机材料学报, 2023, 38(12): 1396-1404.