DCTA对KDP晶体的快速生长与光学性能的影响

doi:10.3724/SP.J.1077.2013.13075

无机材料学报 ›› 2013, Vol. 28 ›› Issue (10): 1148-1152.DOI: 10.3724/SP.J.1077.2013.13075 CSTR: 32189.14.SP.J.1077.2013.13075

DCTA对KDP晶体的快速生长与光学性能的影响

朱胜军, 王圣来, 丁建旭, 程秀凤, 王正平, 许心光

(山东大学晶体材料国家重点实验室, 济南250100)

收稿日期:2013-02-01 修回日期:2013-03-14 出版日期:2013-10-20 网络出版日期:2013-09-18
作者简介:朱胜军(1987-), 男, 博士研究生. E-mail: zhushengjun120623@126.com
基金资助:
国家自然科学基金(50721002; 51202131)

Effect of DCTA on the Rapid Growth and Optical Characterization of KDP Crystal

ZHU Sheng-Jun, WANG Sheng-Lai, DING Jian-Xu, CHENG Xiu-Feng, WANG Zheng-Ping, XU Xin-Guang

(State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, China)

Received:2013-02-01 Revised:2013-03-14 Published:2013-10-20 Online:2013-09-18
About author:ZHU Sheng-Jun. E-mail: zhushengjun120623@126.com
Supported by:
National Natural Science Foundation of China (50721002; 51202131)

摘要/Abstract

摘要： 环己二胺四乙酸(DCTA)作为一种新型添加剂被加入到KDP晶体生长溶液中。采用“点籽晶”快速生长技术, 在掺杂100×10^-6 DCTA的饱和溶液中, 生长了KDP晶体, 生长速度达20 mm/d。研究了这种新型添加剂DCTA对快速生长的KDP晶体的生长习性和光学质量的影响, 并与常用添加剂EDTA的影响效果进行了对比。研究发现, 在KDP晶体生长溶液中添加100×10^-6 DCTA使生长溶液的亚稳区宽度提高了约10℃, 晶体(100)面的生长速度提高了3~10倍; 生长出的晶体在紫外波段的透过率上升了2~8倍, 晶体内部的光散射大大减轻, 激光损伤阈值也有所提高。添加剂DCTA对KDP晶体生长及性能的改善作用比同等浓度的EDTA更加显著。

关键词: KDP晶体, 快速生长, 光学性能, 添加剂

Abstract: Cyclohexanediaminetetraacetic acid (DCTA) as a new additive was added into the KDP growth solution. The KDP crystal was grown from aqueous solution with 100×10^-6 DCTA by the “point seed” rapid growth technique, at growth rate of about 20 mm/d. Effects of the new additive DCTA on growth habit and optical quality of the rapidly grown KDP crystal were investigated and compared with those of EDTA which was a common additive used in the rapid growth of KDP crystal. With 100×10^-6 DCTA added in growth solution, the metastable temperature zone width of solution increased about 10℃ and the growth rate of (100) faces of KDP crystal accelerated by 3–10 times. Furthermore, the optical quality of crystal doped with DCTA was improved significantly: such as 2–8 times rise of UV transmittance, great mitigation of light scattering and a few exaltation of laser damage threshold. Additionally, the beneficial effects of DCTA on growth habit and optical quality of the rapidly grown KDP crystal were more significant than those of EDTA with the same concentration.

Key words: KDP crystal, rapid growth, optical characterization, additive

中图分类号:

TB34

朱胜军, 王圣来, 丁建旭, 程秀凤, 王正平, 许心光. DCTA对KDP晶体的快速生长与光学性能的影响[J]. 无机材料学报, 2013, 28(10): 1148-1152.

ZHU Sheng-Jun, WANG Sheng-Lai, DING Jian-Xu, CHENG Xiu-Feng, WANG Zheng-Ping, XU Xin-Guang. Effect of DCTA on the Rapid Growth and Optical Characterization of KDP Crystal[J]. Journal of Inorganic Materials, 2013, 28(10): 1148-1152.

参考文献

[1] De Yoreo J J, Burnham A K, Whitman P K. Developing KH2PO4 and KD2PO4 crystals for the world’s most power laser. International Materials Reviews, 2002, 47(3): 113-152.

[2] Salo V I, Voronov A P, Tkachenko V F, et al. Growth of KDP single crystal blocks in defined crystallographic direction. Journal of Crystal Growth, 2011, 337(1): 13-19.

[3] Sun Y, Wang S L, Gu Q T, et al. Study of KDP crystal lattice strain and stress by high resolution X-ray diffraction. Acta Physica Sinica, 2012, 61(21): 15-20.

[4] Zaiteseva N, Carman L. Rapid growth of KDP-type crystals. Progress in Crystal Growth and Characterization of Materials, 2001, 43(1): 1-118.

[5] Zhuang X X, Ye L W, Zheng G Z, et al. The rapid growth of large-scale KDP single crystal in brief procedure. Journal of Crystal Growth, 2011, 318(1): 700-702.

[6] Wang S L, Sun X, Tao X T. Growth and Characterization of KDP and Its Analogs. Springer Handbook of Crystal Growth. London: Springer, 2010, Part C: 759-794.

[7] Xu M X, Wang Z P, Wang B, et al. Study on optical property of rapid growth KDP and DKDP crystals. Chinese-Optics-Letters, 2012, 10(B06): 157-160.

[8] Li G H, Su G B, Zhuang X X, et al. Rapid growth of KDP crystal with new additive. Journal of Crystal Growth, 2004, 269(2/3/4): 443-447.

[9] Land T A, Martin T L, Potapenko S, et al. Recovery of surface from impurity poisoning during crystal growth. Nature, 1999, 393: 442-445.

[10] MU Xiao-Ming, WANG Sheng-Lai, FANG Chang-Shui, et al. Effect of Ca2+ ions on the growth habit and optical properties of KDP crystal. Journal of Inorganic Materials, 2007, 22(6): 1103-1107.

[11] Zheng G Z, Su G B, Zhuang X X, et al. Effect of Nd3+ on the growth and quality of KDP crystals. Crystal Research and Technology, 2010, 45(2): 145–148.

[12] DING Jian-Xu, LIU Bing, Wang Sheng-Lai, et al. Effect of Cr3+ dopant on growth habit and optical properties of rapid grown KDP crystal. Journal of Inorganic Materials, 2011, 26(4): 354-358.

[13] Wu W J, LI M W, Cheng M, et al. Investigation on the solution stability of KDP with EDTA and KCl double doped. Journal of Synthetic Crystals, 2011, 40(3): 616-623.

[14] ZHU Sheng-Jun, WANG Sheng-Lai, DING Jian-Xu, et al. Effect of DTPA on rapid growth and performance of KDP crystal. Journal of Inorganic Materials, 2012, 27(4): 405-410.

[15] Srinivasan K, Meera K, Ramasamy P. A contemporary method to enhance the metastable zone width for crystal growth from solution. Materials Science Engineering B, 2001, 84(3): 233-236.

[16] Kuznetsov V A, Okhrimenkoand T M, Miroslawa Rak. Growth promoting effect of organic Impurities on growth kinetics of KAP and KDP crystals. Journal of Crystal Growth, 1998, 193(1/2): 164-173.

[17] Zheng G Z, Zhang W B, Su G B, et al. Effects of organic additives on the growth and optical quality of KDP crystals. Journal of Synthetic Crystals, 2008, 37(3): 519-523.

[18] LIU Bing, WANG Sheng-Lai, FANG Chang-Shui, et al. In situ measurement of the prismatic faces growth rate of KDP crystal. Journal of Inorganic Materials, 2006, 21(1): 22-28.

[19] Rashkovich L N. KDP-family Single Crystals. Bristol, Adam Hiler, 1991: 19.

[20] ZHANG Jian-Qin, WANG Sheng-Lai, FANG Chang-Shui, et al. Effects of anionic impurities on the light scatter in KDP crystal. Journal of Inorganic Materials, 2007, 22(2): 268-272.

[21] Garces N Y, Stevens K T, Halliburton L E, et al. Optical absorption and electron paramagnetic resonance of Fe ions in KDP crystals, Journal of Crystal Growth, 2001 , 225(2/3/4): 435-439.

[22] DeVries S A, Goedtkindt P, Huisman W J, et al. X-ray diffraction studies of potassium dihydrogen phosphate (KDP) crystal sufaces. Journal of Crystal Growth, 1999, 205(1/2): 202-214.

DCTA对KDP晶体的快速生长与光学性能的影响

Effect of DCTA on the Rapid Growth and Optical Characterization of KDP Crystal

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈甜, 罗媛, 朱刘, 郭学益, 杨英. 有机-无机共添加增强柔性钙钛矿太阳能电池机械弯曲及环境稳定性能[J]. 无机材料学报, 2024, 39(5): 477-484.
[2]	吕朝阳, 徐勇, 杨久延, 涂广升, 涂兵田, 王皓. MgF₂助剂对MgAl_1.9Ga_0.1O₄透明陶瓷的制备与光学性能的影响[J]. 无机材料学报, 2024, 39(5): 531-538.
[3]	顾军毅, 范武刚, 张兆泉, 姚琴, 展红全. 还原制备Pr₂O₃粉体及其结构和光学性能研究[J]. 无机材料学报, 2023, 38(7): 771-777.
[4]	李悦, 张旭良, 景芳丽, 胡章贵, 吴以成. 铈掺杂硼酸钙镧晶体的生长与性能研究[J]. 无机材料学报, 2023, 38(5): 583-588.
[5]	王海东, 王燕, 朱昭捷, 李坚富, LAKSHMINARAYANA Gandham, 涂朝阳. Dy³⁺掺杂SrGdGa₃O₇晶体的晶体生长, 结构、光学和可见光荧光特性[J]. 无机材料学报, 2023, 38(12): 1475-1482.
[6]	李文俊, 王皓, 涂兵田, 谌强国, 郑凯平, 王为民, 傅正义. 宽光谱透过Mg_0.9Al_2.08O_3.97N_0.03透明陶瓷的制备与性能研究[J]. 无机材料学报, 2022, 37(9): 969-975.
[7]	刘强, 王倩, 陈鹏辉, 李晓英, 章立轩, 谢腾飞, 李江. 两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究[J]. 无机材料学报, 2022, 37(8): 911-917.
[8]	江依义, 沈旻, 宋半夏, 李南, 丁祥欢, 郭乐毅, 马国强. 双功能电解液添加剂对锂离子电池高温高电压性能的影响[J]. 无机材料学报, 2022, 37(7): 710-716.
[9]	刘雯雯, 胡志蕾, 王立, 曹梦莎, 张晶, 张婧, 张帅, 袁宁一, 丁建宁. L-3-(4-吡啶基)-丙氨酸钝化钙钛矿太阳电池界面缺陷[J]. 无机材料学报, 2021, 36(6): 629-636.
[10]	刘子玉, TOCI Guido, PIRRI Angela, PATRIZI Barbara, 冯亚刚, 陈肖朴, 胡殿君, 田丰, 吴乐翔, VANNINIMatteo, 李江. 固体激光用Nd:Lu₂O₃透明陶瓷的制备和光学性能研究[J]. 无机材料学报, 2021, 36(2): 210-216.
[11]	黄新友, 刘玉敏, 刘洋, 李晓英, 冯亚刚, 陈肖朴, 陈鹏辉, 刘欣, 谢腾飞, 李江. 醇水共沉淀法制备Yb:YAG透明陶瓷及其性能研究[J]. 无机材料学报, 2021, 36(2): 217-224.
[12]	韦家蓓, TOCIGuido, PIRRIAngela, PATRIZIBarbara, 冯亚刚, VANNINIMatteo, 李江. 共沉淀纳米粉体制备Yb:CaF₂激光陶瓷及其性能研究[J]. 无机材料学报, 2019, 34(12): 1341-1348.
[13]	刘小元, 刘宝丹, 姜亚南, 王柯, 周洋, 杨兵, 张兴来, 姜辛. 形貌可控及光学吸收性能可调的钙钛矿型SrTiO₃纳米结构的原位生长[J]. 无机材料学报, 2019, 34(1): 65-71.
[14]	熊浩, 张渤昕, 贾巍, 张青红, 谢华清. 高分子PVP添加剂对钙钛矿太阳电池稳定性的提升[J]. 无机材料学报, 2019, 34(1): 96-102.
[15]	古毓康, 曹磊, 万勇, 高建国. 铝合金基底微碳球作为润滑油添加剂的摩擦学性能及其润滑机理[J]. 无机材料学报, 2017, 32(6): 625-630.