两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究

doi:10.15541/jim20220025

无机材料学报 ›› 2022, Vol. 37 ›› Issue (8): 911-917.DOI: 10.15541/jim20220025

两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究

刘强¹(), 王倩¹^,², 陈鹏辉²^,³, 李晓英²^,³, 章立轩²^,³, 谢腾飞²^,³, 李江²^,³()

1.江苏大学材料科学与工程学院, 镇江 212013
2.中国科学院上海硅酸盐研究所, 透明光功能无机材料重点实验室, 上海 201899
3.中国科学院大学材料科学与光电工程中心, 北京 100049

收稿日期:2022-01-17 修回日期:2022-03-17 出版日期:2022-08-20 网络出版日期:2022-04-07
通讯作者: 李江, 研究员. E-mail: lijiang@mail.sic.ac.cn
作者简介:刘强(1964-), 男, 教授. E-mail: lq88611338@163.com

Fabrication and Characterizations of Red Ce-doped 8YSZ Transparent Ceramics by Two-step Sintering

LIU Qiang¹(), WANG Qian¹^,², CHEN Penghui²^,³, LI Xiaoying²^,³, ZHANG Lixuan²^,³, XIE Tengfei²^,³, LI Jiang²^,³()

1. School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China
2. Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
3. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2022-01-17 Revised:2022-03-17 Published:2022-08-20 Online:2022-04-07
Contact: LI Jiang, professor. E-mail: lijiang@mail.sic.ac.cn
About author:LIU Qiang (1964-), male, professor. E-mail: lq88611338@163.com
Supported by:
National Key R&D Program of China(2021YFE0104800);Key Research Project of the Frontier Science of the Chinese Academy of Sciences(QYZDB-SSW-JSC022)

摘要/Abstract

摘要：

彩色氧化锆陶瓷具有鲜艳色彩、高折射率、耐磨损、耐腐蚀及对人体无毒等优点, 被广泛应用于电子、装饰等领域。本研究采用共沉淀法合成了平均粒径为15.9 nm的立方相Ce:8YSZ纳米粉体。以经过800 ℃煅烧4 h的粉体为原料, 通过两步烧结技术制备了具有高光学透过率和高红色度的Ce:8YSZ透明陶瓷,并系统研究了空气预烧温度对红色Ce:8YSZ透明陶瓷微观结构、直线透过率和色度的影响。当预烧温度从1200 ℃升高到1300 ℃时, Ce:8YSZ陶瓷的平均晶粒尺寸从0.3 μm增大到2.2 μm, 同时相对密度从87.2%增加到97.1%。经过1275 ℃空气预烧2 h并结合1700 ℃热等静压烧结3 h所得的Ce:8YSZ透明陶瓷表现出最佳的光学质量和最大的红色度值, 在700 nm处的直线透过率为47.6%, 红色度为52.0。

关键词: Ce:8YSZ, 红色透明陶瓷, 空气预烧, 热等静压烧结, 光学性能

Abstract:

Color zirconia ceramics are widely used in electronics and decoration fields due to their bright colors, high refractive index, wear resistance, corrosion resistance, and non-toxicity to the human body. Cubic cerium doped 8% yttria mol percent stabilized zirconia (Ce-doped 8YSZ) nano-powder with average particle size of 15.9 nm was synthesized by co-precipitation method. Using the powder calcined at 800 ℃ for 4 h as starting material, red zirconia transparent ceramics with high optical transparency and high redness value were prepared by two-step sintering method. Influences of pre-sintering temperature on microstructure, in-line transmittance and color performance of the red Ce-doped 8YSZ ceramics were studied. As the pre-sintering temperature increases from 1200 ℃ to 1300 ℃, average grain size of the ceramics increases from 0.3 μm to 2.2 μm and the relative density increases from 87.2% to 97.1%. The Ce-doped 8YSZ ceramics pre-sintered at 1275 ℃ for 2 h and hot isostatic pressed (HIP) at 1700 ℃ for 3 h show the best in-line transmittance of 47.6% at 700 nm and the highest redness of 52.0.

Key words: Ce-doped 8YSZ, red transparent ceramics, air pre-sintering, hot isostatic pressing, optical property

中图分类号:

TQ174

刘强, 王倩, 陈鹏辉, 李晓英, 章立轩, 谢腾飞, 李江. 两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究[J]. 无机材料学报, 2022, 37(8): 911-917.

LIU Qiang, WANG Qian, CHEN Penghui, LI Xiaoying, ZHANG Lixuan, XIE Tengfei, LI Jiang. Fabrication and Characterizations of Red Ce-doped 8YSZ Transparent Ceramics by Two-step Sintering[J]. Journal of Inorganic Materials, 2022, 37(8): 911-917.

图/表 10

Fig. 1 TG-DTA curves of the Ce-doped 8YSZ precursor

Fig. 2 XRD patterns of (a) Ce-doped 8YSZ precursor and (b) the powder calcined at 800 ℃ for 4 h

Fig. 3 FESEM micrographs of (a) Ce-doped 8YSZ precursor and (b) the powder calcined at 800 ℃ for 4 h

Fig. 4 FESEM micrographs of the thermally etched surfaces of Ce-doped 8YSZ ceramics pre-sintered at different temperatures in air for 2 h (a) 1200 ℃; (b) 1230 ℃; (c) 1250 ℃; (d) 1275 ℃; (e) 1300 ℃

Fig. 5 Relative densities and average grain size of the Ce-doped 8YSZ ceramics pre-sintered at 1200-1300 ℃ in air for 2 h

Fig. 6 (a-e) FESEM micrographs of the thermally etched surfaces of Ce-doped 8YSZ ceramics pre-sintered at 1200- 1300 ℃ for 2 h and HIP post-treatment at 1700 ℃ for 3 h; (f-i) EDS element mapping of the Ce-doped 8YSZ ceramics pre-sintered at 1275 ℃ (a) 1200 ℃; (b) 1230 ℃; (c) 1250 ℃; (d) 1275 ℃; (e) 1300 ℃

Fig. 7 XRD patterns of the (a) pre-sintering and (b) HIP-treatment ceramics

Fig. 8 (a) Photograph and (b) in-line transmittance of the Ce-doped 8YSZ ceramics (1 mm thick) pre-sintered at 1200-1300 ℃ in air for 2 h and HIP post-treatment at 1700 ℃ for 3 h under 176 MPa in Ar atmosphere

Fig. 9 Absorption spectra of the ceramics pre-sintered at different temperatures and HIP post-treatment at 1700 ℃

Table 1 CIE value of Ce-doped 8YSZ ceramics pre- sintered at 1230-1300 ℃ for 2 h and HIP post-treatment at 1700 ℃ for 3 h

Pre-sintering temperature/℃	Value of CIE
Pre-sintering temperature/℃	L^*	a^*	b^*
1230	31.8	42.5	54.7
1250	37.4	48.6	64.3
1275	42.4	52.0	72.9
1300	37.7	48.9	64.8

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两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究

Fabrication and Characterizations of Red Ce-doped 8YSZ Transparent Ceramics by Two-step Sintering

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