 
 Journal of Inorganic Materials ›› 2020, Vol. 35 ›› Issue (11): 1193-1202.DOI: 10.15541/jim20190628
Special Issue: 封面文章; 结构陶瓷论文精选(2020); 【虚拟专辑】气凝胶,玻璃(2020~2021)
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													LIU Fengqi( ),FENG Jian(
),FENG Jian( ),JIANG Yonggang,LI Liangjun
),JIANG Yonggang,LI Liangjun
												  
						
						
						
					
				
Received:2019-12-11
															
							
																	Revised:2020-01-12
															
							
															
							
																	Published:2020-11-20
															
							
																	Online:2020-03-03
															
						About author:LIU Fengqi, male, PhD candidate. E-mail: nudtliufengqi@163.com				
													Supported by:CLC Number:
LIU Fengqi, FENG Jian, JIANG Yonggang, LI Liangjun. Preparation and Application of Boron Nitride Aerogels[J]. Journal of Inorganic Materials, 2020, 35(11): 1193-1202.
 
																													Fig. 3 (a) Schematic illustration of the metastructure design of BN aerogels; (b) The lightest hBN aerogels sample compared with other ultralight materials; (c) The ultimate stress, Young’s modulus, and relative height for 100 compression cycles; (d) Optical and SEM images of BN aerogels under different pressures[26]
 
																													Fig. 5 (a) Schematic representation of aerogel production by a critical point drying method; (b) Picture of the as-obtained BN aerogels, MoS2 aerogels and GA[40]
 
																													Fig. 6 (a) Schematic illustration of the freeze-drying method for preparing nano-ribbon BN aerogels; (b, c) The flexibility of BN nano-ribbon aerogels in liquid nitrogen and flame[41]
 
																													Fig. 9 (a) The absorption of CO2 and N2 at 273 and 298 K by BN aerogel and (b) corresponding histograms[28]; (c) SEM image of Pt nanocrystals/BN aerogel; (d) Response/recovery curve of Pt nanocrystal/BN aerogel towards propane[52]
 
																													Fig. 10 (a) SEM images of Pt/BN-GA catalyst[55]; (b) ECSA comparison chart of Pt/BN-GA, Pt/GA, Pt/G and Pt/C and (c) corresponding current-time curves[57]
 
																													Fig. 11 (a-d) The Wetting behaviour and oil absorption capacity of rGO/BN sponge; (e) The ability of rGO/BN sponge to absorb different organic liquids; (f) The rGO/BN sponge repetitively absorbed hexane and released its vapour under heat treatment (85 ℃); (g) Recyclability of the rGO/BN sponge for absorption of hexane under absorption-squeezing cycles[59]
| [1] | 冯伟 . 不同衬底上氮化硼薄膜制备与场发射性质研究. 长春: 吉林大学硕士学位论文, 2004. | 
| [2] | DU M, LI Y, ZHANG G R ,et al. Progress in preparation and application of boron nitride nanosheets. Inorganic Chemicals Industry, 2019,51(2):8. | 
| [3] | WANG G Z . Summarization about the peculiarities of cBN. Jewellery Science and Technology, 2005,17(5):41-45. | 
| [4] | WANG G Z . Synthesis and structure transformation of wBN under HPHT. Inorganic Chemicals Industry, 2006,18(4):21-24. | 
| [5] | YANG Y P, LI B, ZHANG C Y ,et al. The Morphology, synthesis, properties, and applications of graphene-like two-dimensional h-BN nanomaterials. Materials Review, 2016,30(11):143-148. | 
| [6] | PAKDEL A, BANDO Y, GOLBERG D . Nano boron nitride flatland. Chemistry Society Reviews, 2014,43(3):934-959. DOI URL | 
| [7] | LIN Y, CONNELL J W . Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanosheets, and hybrids with graphene. Nanoscale, 2012,4(22):6908-6939. DOI URL | 
| [8] | ZHI C Y, BANDO Y, TANG C C , et al. Large-scale fabrication of boron nitride nanosheets and their utilization in polymeric composites with improved thermal and mechanical properties. Advanced Materials, 2009,21(28):2889-2893. DOI URL | 
| [9] | ZHAO Y, WU X J, YANG J L , et al. Oxidation of a two-dimensional hexagonal boron nitride monolayer: a first-principles study. Physical Chemistry Chemical Physics, 2012,14(16):5545-5550. DOI URL | 
| [10] | WATANABE K, TANIGUCHI T, KANDA H . Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal. Nature Materials, 2004,3(6):404-409. DOI URL PMID | 
| [11] | LI L H, CHEN Y . Atomically thin boron nitride: unique properties and applications. Advanced Functianal Materials, 2016,26(16):2594-2608. | 
| [12] | DUAN X M, YANG J H, WANG Y J ,et al. Research and application progress of hexagonal boron nitride (h-BN) based composite ceramics. Materials China, 2015,34(10):770-782. | 
| [13] | JIANG X F, WENG Q, WANG X B ,  et a1. Recent progress on fabrications and applications of boron nitride nanomaterials: a review. Journal of Materials Science & Technology, 2015,31(6):589-598. DOI URL | 
| [14] | NICOLA H U S . Aerogels-airy materials: chemistry, structure, and properties. Angewandte Chemie International Edition, 1998,37(1/2):22-45. DOI URL | 
| [15] | XIAO Y Y, JIANG Y G, FENG J Z ,et al. Research progress of polyurethane based aerogel insulation materials. Materials Review, 2018,32(1):449-453. | 
| [16] | LUO Y, JIANG Y G, FENG J Z ,et al. Progress on the preparation of SiO2 aerogel composites by ambient pressure drying technique. Materials Review, 2018,32(5):780-787. | 
| [17] | WATANABE K, TANIGUCHI T, KANDA H . Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal. Nature Materials, 2004,3(6):404. DOI URL PMID | 
| [18] | MENG Y, CHEN J J, LIANG W X ,et al. Progress in catalysis of hexagonal boron nitride and boron nitride nanosheets. Journal of Southwest University for Nationalities (Natural Science Edition), 2015,41(3):331-337. | 
| [19] | LI J, LI L J, GAO Y F , et al. Preparation of nanomaterials employing template method. Materials Review, 2011(s2):5-9. | 
| [20] | RUAN X, DONG L, YU J , et al. The progress of nanomaterials prepared in the presence of soft template. Materials Review, 2012,26(1):56-60. | 
| [21] | WENG Q, WANG X, BANDO Y ,et al. One-step template-free synthesis of highly porous boron nitride microsponges for hydrogen storage. Advanced Energy Materials, 2014,4(7):130-152. | 
| [22] | DAI J, WU X, YANG J ,et al. Unusual metallic microporous boron nitride networks. Journal of Physical Chemistry Letters, 2013,4(20):3484-3488. DOI URL | 
| [23] | DAI J, WU X, YANG J , et al. Porous boron nitride with tunable pore size. Journal of Physical Chemistry Letters, 2014,5(2):393-398. DOI URL | 
| [24] | HAN W Q, BRUTCHEY R, TILLEY T D ,et al. Activated boron nitride derived from activated carbon. Nano Letters, 2004,4(1):173-176. DOI URL | 
| [25] | RUSHTON B, MOKAYA R . Mesoporous boron nitride and boron- nitride-carbon materials from mesoporous silica templates. Journal of Materials Chemistry, 2007,18(2):235-241. DOI URL | 
| [26] | XU X, ZHANG Q Q, HAO M L ,  et al. Double-negative-index ceramic aerogels for thermal superinsulation. Science, 2019,363:723-727. DOI URL PMID | 
| [27] | ZHANG Q, XU X, LIN D ,et al. Hyperbolically patterned 3D graphene metamaterial with negative poisson ratio and superelasticity. Advanced Materials, 2016,28(11):2229-2237. DOI URL PMID | 
| [28] | KUTTY R G, SREEJITH S, KONG X ,  et al. A topologically substituted boron nitride hybrid aerogel for highly selective CO2 uptake. Nano Research, 2018,11(12):6325-6335. DOI URL | 
| [29] | YIN J, LI X, ZHOU J ,et al. Ultralight three-dimensional boron nitride foam with ultralow perm ittivity and superelasticity. Nano Letters, 2013,13(7):3232-3236. DOI URL PMID | 
| [30] | ALAUZUN J G, NGURN S, BRUN N ,et al. Novel monolith-type boron nitride hierarchical foams obtained through integrative chemistry. Journal of Materials Chemistry, 2011,21(36):14025-14030. DOI URL | 
| [31] | HUANG Y F, LIU H E, WANG Z Y ,et al. Preparation of graphene aerogels with soft templates and their oil adsorption mechanism from water. Journal of Chemical Engineering of Chinese Universities, 2012,26(1):56-60. | 
| [32] | YAMAUCHI Y, KURODA K . Rational design of mesoporous metals and related nanomaterials by a soft-template approach. Chemistry - An Asian Journal, 2010,3(4):664-676. DOI URL | 
| [33] | WANG H, FAN G, ZHENG C , et al. Facile sodium alginate assisted assembly of Ni/Al layered double hydroxide nanostructures. Industrial & Engineering Chemistry Research, 2010,49(6):2759-2767. | 
| [34] | XIU R, DONG L, JING Y U , et al. The progress of nanomaterials prepared in the presence of soft template. Materials Review, 2012,1:56-60. | 
| [35] | BERNARD S, MIELE P . Nanostructured and architectured boron nitride from boron, nitrogen and hydrogen-containing molecular and polymeric precursors. Materials Today, 2014,17(9):443-450. DOI URL | 
| [36] | MALENFANT P R L, WAN J, TAYLOR S T ,et al. Self-assembly of an organic-inorganic block copolymer for nano-ordered ceramics. Nature Nanotechnology, 2007,2(1):43-46. DOI URL PMID | 
| [37] | QIAN X H, LIU H B, LI Y L . Self-assembly low dimensional inorganic/organic heterojunction nanomaterials. Chinese Science Bulletin, 2014(1):1-14. | 
| [38] | KLOK H A, LECOMMANDOUX S . Supramolecular materials via block copolymer self-assembly. Advanced Materials, 2010,13(16):1217-1229. DOI URL | 
| [39] | CIFERRI A . Assembling nano and macrostructures and the supramolecular liquid crystal. Progress in Polymer Science, 1995,20(6):1081-1120. DOI URL | 
| [40] | JUNG S M, JUNG H Y, DRESSELHAUS M S ,et al. A facile route for 3D aerogels from nanostructured 1D and 2D materials. Scientific Reports, 2013,2(11):849. | 
| [41] | LI G Y, ZHU M Y, GONG W B , et al. Boron nitride aerogels with super-flexibility ranging from liquid nitrogen temperature to 1000 ℃. Advanced Functional Materials, 2019,29:1900188. | 
| [42] | GAO G, GAO W, CANNUCCIA E ,et al. Artificially stacked atomic layers: toward new van der waals solids. Nano Letters, 2012,12(7):3518-3525. DOI URL | 
| [43] | LI H, LIN J, TAY R Y , et al. Multifunctional and highly compressive cross-linker-free sponge based on reduced graphene oxide and boron nitride nanosheets. Chemical Engineering Journal, 2017,328:825-833. DOI URL | 
| [44] | NAG A, RAIDONGIA K, HEMBRAM K P ,et al. Graphene analogues of BN: novel synthesis and properties. ACS Nano, 2010,4(3):1539-1544. DOI URL PMID | 
| [45] | MENG X, LUN N, QI Y , et al. Low-temperature synthesis of meshy boron nitride with a large surface area. European Journal of Inorganic Chemistry, 2010(20):3174-3178. DOI URL | 
| [46] | MENG X L, LUN N, QI Y X ,et al. Simple synthesis of mesoporous boron nitride with strong cathodoluminescence emission. Journal of Solid State Chemistry, 2011,184(4):859-862. DOI URL | 
| [47] | MENG W, LI M, XU L ,et al. High yield synthesis of novel boron nitride submicro-boxes and their photocatalytic application under visible light irradiation. Catalysis Science & Technology, 2011,1(7):1159. | 
| [48] | LEI W, PORTEHAULT D, LIU D ,et al. Porous boron nitride nanosheets for effective water cleaning. Nature Communications, 2016,4(2):1777. DOI URL | 
| [49] | ZHANG Q, XIANG X, HUI L ,et al. Mechanically robust honeycomb graphene aerogel multifunctional polymer composites.  Carbon, 2015,93:659-670. DOI URL | 
| [50] | SONG X, LIN L, RONG M ,et al. Mussel-inspired, ultralight, multifunctional 3D nitrogen-doped graphene aerogel. Carbon, 2014,80(1):174-182. DOI URL | 
| [51] | JHI S H, KWON Y K . Hydrogen adsorption on boron nitride nanotubes: a path to room temperature hydrogen storage. Physical Review B, 2004,69(24):245407. | 
| [52] | HARLEY-TROCHIMCZYK A, PHAM T, CHANG J ,et al. Gas sensors: platinum nanoparticle loading of boron nitride aerogel and its use as a novel material for low-power catalytic gas sensing. Advanced Functional Materials, 2016,26(3):314. | 
| [53] | ZHENG M T, LIU Y L, GU Y L ,et al. Synthesis and characterization of boron nitride sponges as a noveI support for metal nanoparticles. Science China Chemistry, 2008,51(3):205-210. DOI URL | 
| [54] | PERDIGON-MELON J A, AUROUX A, GUIMON C ,et al. Micrometric BN powders used as catalyst support: influence of the precursor on the properties of the BN ceramic. Journal of Solid State Chemistry, 2004,177(2):609-615. DOI URL | 
| [55] | LI M, JIANG Q, YAN M ,et al. Three-dimensional boron- and nitrogen-codoped graphene aerogel supported pt nanoparticles as highly active electrocatalysts for methanol oxidation reaction. ACS Sustainable Chemistry & Engineering, 2018,6:6644-6653. | 
| [56] | WENG Q, IDE Y, WANG X , et al. Design of BN porous sheets with richly exposed (002) plane edges and their application as TiO2 visible light sensitizer. Nano Energy, 2015,16:19-27. DOI URL | 
| [57] | LI M, JIANG Q, YAN M , et al. Three-dimensional boron- and nitrogen-codoped graphene aerogel supported Pt nanoparticles as highly active electrocatalysts for methanol oxidation reaction. ACS Sustainable Chemistry & Engineering, 2018,6:6644-6653. | 
| [58] | LIU D, LEI W, QIN S , et al. Template-free synthesis of functional 3D BN architecture for removal of dyes from water. Scientific Reports, 2014,4:4453. DOI URL PMID | 
| [59] | LI H, LIN J, TAY R Y ,et al. Multifunctional and highly compressive cross-linker-free sponge based on reduced graphene oxide and boron nitride nanosheets. Chemical Engineering Journal, 2017,328:825-833. DOI URL | 
| [60] | ZHAO H, SONG X, ZENG H . 3D graphene foam scavengers: vesicant-assisted foaming boosts the gram-level yield and forms hierarchical pores for super-strong pollutant removal applications. NPG Asia Mater., 2015,7(3):l68. | 
| [61] | PHAM T, GOLDSTEIN A P, LEWICK J P ,et al. Nanoscale structure and superhydrophobicity of sp 2-bonded boron nitride aerogels. Nanoscale , 2015,7(23):10449-10458. DOI URL PMID | 
| [62] | SONG Y, LI B, YANG S ,et al. Ultralight boron nitride aerogels via template-assisted chemical vapor deposition. Scientific Reports, 2015,5:10337. DOI URL PMID | 
| [63] | XUE Y, DAI P, JIANG X ,et al. Template-free synthesis of boron nitride foam-like porous monoliths and their high-end applications in water purification. Journal of Materials Chemistry A, 2016,4(4):1469-1478. DOI URL | 
| [64] | AN F, LI X, MIN P ,et al. Highly anisotropic graphene/boron nitride hybrid aerogels with long-range ordered architecture and moderate density for highly thermally conductive composites. Carbon, 2018,126:119-127. DOI URL | 
| [65] | NURUNNABI M, NAFIUJJAMAN M, LEE S J , et al. Preparation of ultrathin hexagonal boron nitride nanoplates for cancer cell imaging and neurotransmitter sensing. Chemical Communications, 2016,52(36):6146-6149. DOI URL PMID | 
| [66] | LU F S, WANG F, CAO L ,et al. Hexagonal boron nitride nanomaterials: advances towards bio-applications. Nanoscience and Nanotechnology Letters, 2012,4(10):949-961. DOI URL | 
| [67] | WENG Q, WANG B, WANG X ,et al. Highly water-soluble, porous, and biocompatible boron nitrides for anticancer drug delivery. ACS Nano, 2014,8(6):6123-6130. DOI URL PMID | 
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