Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Research on Growth and Second-Harmonic Generation of YCOB Crystals

LUO Jun1; QIAN Shi-Xiong2; FAN Shi-Ji1; WANG Jin-Chang1; ZHONG Zhen-Wu1; XU Jia-Yue1   

  1. 1.; Shanghai Institute of Ceramics; Chiness Academy of Sciences; Shanghai 200050; China; 2. Department of Physics; Fudan University; Shanghai 200433; China
  • Received:2001-02-21 Revised:2001-03-19 Published:2002-03-20 Online:2002-03-20

Abstract: Crack-free and transparent Ca4YO(BO3)3 (YCOB) crystals with 25 mm diameter were grown by
the vertical Bridgman method in <010> and <001> directions. The results of chemical etching indicate that there are no sub-boundaries or twins
in the crystal, and the density of dislocations observed at top region of a crystal is less than 1800/cm2. The measured transmission spectrum
shows that the crystal has wide transmission range with absorption edge at 200nm. The SHG of a Nd:YAG laser was performed for YCOB crystals in
comparison with KDP crystal, the effective nonlinear coefficients (deff) of YCOB in type I phase matching directions of (θ, φ)=(66.3℃,
143.5℃) and (65.9℃, 36.5℃) were estimated to be 1.45pm/V and o.91pm/V respectively. The bulk damage threshold was observed as
85GW/cm2 for single pulse of a Nd:YAG laser with 10ns pulse duration.

Key words: YCOB, crystal growth, Bridgman method, second-harmonic generation, laser damage threshold

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