Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Effect of Gaseous Penetration of Pr, Mn into BaTiO3 Ceramics on Structure and Electrical Properties

HAO Su-E, HUANG Jin-Xiang, ZHANG Ju-Sheng, WANG Jin-Fu, LIU Zhi-Gang   

  1. (Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China)
  • Received:2006-08-29 Revised:2007-02-05 Published:2007-09-20 Online:2007-09-20

Abstract: Pure BaTiO3 ceramics and Pr, Mn-doped BaTiO3 ceramics were prepared by a sol-gel method. The pure BaTiO3 ceramics were modified by the penetration of Pr and Mn in gaseous state, their structure and electrical properties were studied. The results show that the resisitivity of Pr-doped BaTiO3 ceramics is decreased to 1.01×105Ω·m, the resisitivity of Mn-doped BaTiO3 ceramics is increased to 1.50×1013Ω·m, while both Pr and Mn penetration can decrease the resisitivity of BaTiO3 ceramics evidently, which is 1.08×103Ω·m and 1.29×105Ω·m, respectively . The Pr-Mn penetrated BaTiO3 ceramics show a distinct NTC effect. The XRD results show that the perovskite structure of Pr or Mn doped BaTiO3 ceramics does not change obviously, but there are new peaks of BaMn0.12Al1.88O4 and Al8Mn4Pr in Pr-Mn penetrated BaTiO3 ceramics. The XPS results show that Pr, Mn and C element are penetrated into BaTiO3 ceramics, leading to the binding energy of modified BaTiO3 ceramics increase and their stability improve. The SEM results show that Pr and Mn penetration can improve the surface state of BaTiO3 ceramics, the grains become finer and grow more integrally than pure BaTiO3 ceramics, the porosity are decreased visibly.

Key words: BaTiO3, rare earth, gaseous penetration, NTC effect

CLC Number: