Electrospun FeMnO3 Nanofibrous Mats: Preparation and Electrochemical Property

doi:10.15541/jim20180409

Abstract

Abstract:

A uniform and stable precursor spinning solution was prepared by using polyvinylpyrrolidone (PVP), ferric nitrate nonahydrate and manganese acetate tetrahydrate as raw materials, anhydrous ethanol and N,N-dimethylformamide as solvent, followed by magnetically stirred. The PVP/Mn(COOH)₂/Fe(NO₃)₃ composite nanofibers were prepared by electrospinning technology. FeMnO₃ nanofibrous mats were obtained after high temperature calcination, which was used as anode material for lithium battery. Apparent morphology and crystal structure of the samples were investigated by FT-IR, XRD, SEM, and BET specific surface area analyzers. All results showed that the fabricated FeMnO₃ nanofibrous mats possessed good structural morphology with the specific surface area of 9.9 m ²/g. TG analysis showed that when temperature reaches 470 ℃, the TG curve becomes gentle while the mass loss is not obvious. Results form charge and discharge, cyclic voltammetry, and cycle performance tests, indicated that FeMnO₃ nanofibrous mats had good electrochemical performance and electrical stability, with a specific capacity of 533 mAh/g at 50 mA/g after 37 cycles. After 50 cycles, the impedance is approximately 170 Ω, which remains essentially unchanged.

Key words: electrospinning, FeMnO₃ nanofibrous mats, lithium battery, electrochemical performance

CLC Number:

TQ340

SUN Xiao-Lu,SONG Xiao-Fei,LIU Yan-Hua,WU Yue,CAI Yi-Bing,ZHAO Hong-Mei. Electrospun FeMnO₃ Nanofibrous Mats: Preparation and Electrochemical Property[J]. Journal of Inorganic Materials, 2019, 34(7): 709-714.

Figures/Tables 8

Fig. 1 TG and DTG curves of PVP/Mn(COOH)2/Fe(NO3)3 composite nanofibers

Fig. 2 Infrared spectra of samples before and after calcination (a) PVP/Mn(COOH)2/Fe(NO3)3 composite nanofibers; (b) FeMnO3 nanofibrous mats

Fig. 3 XRD pattern of FeMnO3 nanofibrous mats

Fig. 4 (a) SEM image of PVP/Mn(COOH)2/Fe(NO3)3 composite nanofibers, and (b) SEM and (c) TEM images of FeMnO3 nanofibrous mats after calcination

Fig. 5 N2 adsorption-desorption isotherm of FeMnO3 nanofibrous mats

Fig. 6 Cyclic voltammograms of FeMnO3 nanofibrous mats

Fig. 7 (a) Charge-discharge and (b) cycle performance curves of FeMnO3 nanofibrous mats

Fig. 8 AC impedance diagram of FeMnO3 nanofibrous mats

References 21

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Electrospun FeMnO₃ Nanofibrous Mats: Preparation and Electrochemical Property

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