基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展

doi:10.15541/jim20200266

无机材料学报 ›› 2021, Vol. 36 ›› Issue (6): 592-600.DOI: 10.15541/jim20200266 CSTR: 32189.14.10.15541/jim20200266

所属专题：【能源环境】金属有机框架材料(202309)

基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展

李婷婷¹^,²(), 张志明¹, 韩正波²()

1.华北理工大学材料科学与工程学院, 唐山 063009
2.辽宁大学化学学院, 沈阳 110036

收稿日期:2020-05-15 修回日期:2020-07-09 出版日期:2021-06-20 网络出版日期:2020-08-28
通讯作者: 韩正波, 教授. E-mail: ceshzb@lnu.edu.cn
作者简介:李婷婷(1980-), 女, 博士. E-mail: litingting2046@163.com
基金资助:
国家自然科学基金面上项目(21671090);国家自然科学基金面上项目(21701076);河北省高等学校科学技术研究重点项目(ZD2018053)

Research Progress in Polymer-based Metal-organic Framework Nanofibrous Membranes Based on Electrospinning

LI Tingting¹^,²(), ZHANG Zhiming¹, HAN Zhengbo²()

1. College of Material Science and Engineering, North China University of Science and Technology, Tangshan 063009, China
2. College of Chemistry, Liaoning University, Shenyang 110036, China

Received:2020-05-15 Revised:2020-07-09 Published:2021-06-20 Online:2020-08-28
Contact: HAN Zhengbo, professor. E-mail: ceshzb@lnu.edu.cn
About author:LI Tingting(1980-), female, PhD. E-mail: litingting2046@163.com
Supported by:
National Natural Science Foundation of China(21671090);National Natural Science Foundation of China(21701076);Science and Technology Project of Hebei Education Department(ZD2018053)

摘要/Abstract

摘要：

基于静电纺丝技术的金属有机骨架纳米纤维膜材料(Metal-Organic Frameworks Nanofibrous Membranes, MOFs NFMs)综合了无机多孔材料和聚合物纳米纤维的优势, 是一类具有广阔应用前景的功能性材料。目前已经开发出不同功能的MOFs NFMs, 其应用领域也在不断扩展。本文介绍了MOFs NFMs从制备研究向应用研究的发展历程, 详述了现阶段制备MOFs NFMs的主要方法, 包括混合纺丝法、原位生长法、多步种子生长法和原子层沉积法等; 阐述了目前MOFs NFMs的主要应用领域, 如吸附分离、多相催化、传感检测等; 展望了MOFs NFMs的发展方向和趋势。

关键词: MOFs纳米纤维膜, 静电纺丝, 综述

Abstract:

Metal organic frameworks(MOFs) nanofibrous membranes (NFMs) based on electrospinning technology integrate the advantages of inorganic porous materials and polymer nanofibers, enabling them a class of functional materials with broad application prospects. MOFs NFMs with different functions are explored continuously and their application fields are expanding. In this work, we briefly introduce the development of MOFs NFMs, which has experienced a gradual transformation from preparation research to application research. Then, the main methods on preparing MOFs NFMs, including mixed electrospinning, in situ growth, multistep seeded growth, and atomic layer deposition, are described in detail. The main application and of current MOFs NFMs, such as adsorption and separation, heterogeneous catalysis, sensing detection are expounded. And, we put forward the future prospect of the development directions and trends of MOFs NFMs.

Key words: MOFs nanofibrous membranes, electrospinning, review

中图分类号:

V258

李婷婷, 张志明, 韩正波. 基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展[J]. 无机材料学报, 2021, 36(6): 592-600.

LI Tingting, ZHANG Zhiming, HAN Zhengbo. Research Progress in Polymer-based Metal-organic Framework Nanofibrous Membranes Based on Electrospinning[J]. Journal of Inorganic Materials, 2021, 36(6): 592-600.

图/表 10

图1 MIL-47/PAN (a)[8]和HKUST-1 (b)[10] NFMs的SEM照片

Fig. 1 SEM images of MIL-47/PAN (a)[8] and HKUST-1 (b) NFMs[10]

图2 PI-ZIF-8 (a)[16]和PAN/MOF-808 (b)[17]的SEM照片

Fig. 2 SEM images of PI-ZIF-8 (a)[16] and PAN/MOF-808 (b) NFMs[17]

图3 (a)ZIF-8/PAN纤维的制备方法和机理[22]; (b)PAN NFM上原位生长UiO-66-NH2示意图[23]; (c)ZIF-8、MIL-88B(Fe)、HKUST-1和MIL-53(Al) NFMs的制备过程[25]

Fig. 3 (a) Preparation method and formation mechanism of the in situ ZIF-8/PAN fibers[22]; (b) Scheme of in situ growth of UiO-66-NH2 on PAN NFM[23]; (c) Fabrication process of ZIF-8, MIL-88B(Fe), HKUST-1 and MIL-53(Al) NFMs[25]

图4 自支撑的柔性HKUST-1 NFM的制备过程[6]

Fig. 4 Preparation process of self-supported and flexible HKUST-1 NFM[6]

图5 (a)PAN/ZnO/ZIF-8和PAN/Al2O3/MIL-53-NH2的SEM照片[28]; (b)ALD法制备UiO-66-NH2 NFM的示意图[29]

Fig. 5 (a) SEM images of PAN/ZnO/ZIF-8 and PAN/Al2O3/MIL-53-NH2 NFMs[28], and (b) schematic illustration of UiO-66-NH2 NFMs prepared through ALD[29]

图6 以聚多巴胺为成核中心在“惰性”聚合物NFM上沉积MOF[30]

Fig. 6 Effective deposition MOF on the ‘‘inert’’ polymer fibrous membranes by using polydopamine layer as nucleation center[30]

图7 (a)PAN/ZIF-8 NFMs对CO2的吸附等温线和CO2/N2的吸附选择率[33]; (b)Bio-MOF/PAN过滤器对阳离子染料的选择性吸附[37]; (c)ZIF-67/CA NFM对Cu(II)和Cr(VI)的吸附机理示意图[39]

Fig. 7 (a) CO2 adsorption isotherms and CO2/N2 adsorption selectivity of PAN/ZIF-8 NFMs[33], (b) selective adsorption of cationic dyes by bio-MOF/PAN filter[37], and (c) adsorption mechanism of Cu(II) and Cr(VI) on the ZIF-67/CA NFM surface[39]

图8 (a)PLA/ZIF-8@GO NFM光催化降解MB的可能机理[41]; (b)UiO-66-NH2 NFM用于处理有毒工业化学品和化学战剂的示意图[42]

Fig. 8 (a) Possible mechanism of photocatalytic degradation of MB on PLA/ZIF-8@GO fibers[41], and (b) illustration of UiO-66-NH2 NFM used for protection against toxic industrial chemicals and chemical warfare agents[42]

图9 (a)Zn-MOF/PST-1NFM的荧光照片[45]; (b)荧光试纸的可逆性实验[47]

Fig. 9 (a) Fluorescent image of Zn-MOF/PST-1 NFM[45], and (b) reversibility test of the fluorescent test paper with NB and methanol[47]

图10 (a)定向静电纺丝纤维中质子传导示意图和横截面取向纳米纤维的HRTEM照片[55]; (b)CS-PEO和CS-PEO-3% ZIF-8 NFMs对金黄色葡萄球菌的抗菌活性[56]

Fig. 10 (a) Proton conductive process of oriented electrospun nanofiber and HRTEM image of cross-sectional aligned nanofiber[55], and (b) antibacterial activities of CS-PEO and CS-PEO-3% ZIF-8 NFMs[56]

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基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展

Research Progress in Polymer-based Metal-organic Framework Nanofibrous Membranes Based on Electrospinning

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