中空SiO2微球的制备及其在缓/控释应用中的新进展

doi:10.15541/jim20160234

摘要/Abstract

摘要：

中空二氧化硅(SiO₂)微球具有特殊的内部空腔、吸附渗透性好、物质传递可控等优异性能, 可储存负载并缓慢释放药物、香精、染料、菌素等客体分子, 因此在药物缓释、医学成像、环境保护以及化妆品等领域有着广阔的应用前景。根据国内外研究进展, 本文归纳对比了中空SiO₂微球几种制备方法之间的优劣差异, 着重阐述了其作为缓控释载体表现出的持久性和高效性, 以及功能化的有机/无机杂化微球在响应性控释方面的优越性。并对中空SiO₂微球作为新型缓控释载体的发展前景进行了展望。

关键词: 中空SiO2微球, 传统模板法, 自模板法, 缓释, 响应性控释, 综述

Abstract:

Hollow silica (SiO₂) microspheres with special interior spaces, excellent adsorption and permeability, and controllability of material deliveries are suitable for loading and releasing guest molecules of various functionalities such as drug, fragrances, dyes, bacteria, etc. More importantly, hollow silica (SiO₂) microspheres have attracted much attention due to their tremendous applications in sustained drug release, medical imaging, environmental protection, and cosmetics industry. In this paper, different preparation methods of hollow silica microspheres are reviewed and compared. Besides, the persistence and efficiency of hollow silica microspheres employed as delivery carriers and superiority of functionalized organic/inorganic hybrid microspheres are emphatically summarized. Meanwhile, the vast potential for future development of hollow silica microspheres as a novel type of sustained/controlled release carriers is prospected.

Key words: hollow silica microspheres, traditional template method, self-template method, sustained release, responsive controlled release, review

中图分类号:

TB34

鲍艳, 王彤. 中空SiO₂微球的制备及其在缓/控释应用中的新进展[J]. 无机材料学报, 2016, 31(12): 1269-1278.

BAO Yan, WANG Tong. Recent Advances in Fabrication and Sustained/Controlled-release Application of Hollow Silica Microspheres[J]. Journal of Inorganic Materials, 2016, 31(12): 1269-1278.

图/表 10

图1 传统模板法制备中空SiO2微球示意图[28]

Fig. 1 A schematic of the process for hollow silica microspheres preparation via traditional templating method[28]

图2 以PS微球为模板制备介孔中空SiO2微球的示意图[38]

Fig. 2 A schematic of the process for mesoporous hollow silica microspheres preparation via PS template[38]

图3 (a)软模板法制备中空SiO2微球的机理图; 中空SiO2微球的(b)SEM和(c)TEM照片[44]

Fig. 3 (a) A schematic of the process for hollow silica microspheres preparation via soft-templating method; (b) SEM and (c)TEM images of hollow silica microspheres[44]

图4 (a)金/SiO2摇铃状中空微球, (b)SiO2/SiO2摇铃状中空微球和(c)SiO2/SiO2多重壳层状中空微球的TEM照片[46]

Fig. 4 TEM images of (a) Au/SiO2 yolk/shell hollow silica microspheres, (b) SiO2/SiO2 yolk/shell hollow silica microspheres and (c) SiO2/SiO2 multilayer shell hollow silica microspheres[46]

图5 乙烯基中空SiO2微球的形成机理示意图[57]

Fig. 5 Formation mechanism of vinyl silica hollow spheres[57]

图6 (a)实心SiO2微球的TEM照片, 摇铃结构介孔中空SiO2微球的(b)TEM照片和(c、d)SEM照片和(e)介孔中空SiO2微球的TEM照片[58]

Fig. 6 (a) TEM image of solid silica spheres, (b) TEM and (c, d) SEM images of mesoporous hollow silica nanorattles, (e) TEM image of mesoporous hollow silica microspheres[58]

图7 火花壳状SiO2微胶囊的SEM照片[61]

Fig. 7 SEM images of hollow silica microcapsule[61]

表1 各种制备方法的优劣对比

Table 1 Characteristics and limitations of various preparation methods

Method	Characteristic	Limitation
Hard template	① Adjustable particle size; ② Well-defined structure; ③ Uniform product morphology; ④ Foreseeable and high repetition rate	① Difficult to remove the templates ② The shell easy to collapse; ③ Time-consuming and money-consuming
Soft template	① Easy to prepare and remove the templates ② Simple technology; ③ Time-saving	① Poor structural stability and monodispersity; ② Not easy to control shell thickness; ③ Wide particle size distribution; ④ Low efficiency
Self template	① No additional template; ② Simple step and time-saving synthetic; ③ High repetition rate; ④ Controllable morphology	① Various and complex influence factors; ② Large dependability on environment

图8 不同pH下介孔中空SiO2微球的控制释放曲线图[84]

Fig. 8 Controlled release curve under different pH of hollow mesoporous silica microspheres[84]

图9 杂化中空微球和纯中空微球的香精释放曲线图[85]

Fig. 9 Fragrance release of hybrid hollow spheres and the pure SiO2 hollow spheres[85]

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中空SiO₂微球的制备及其在缓/控释应用中的新进展

Recent Advances in Fabrication and Sustained/Controlled-release Application of Hollow Silica Microspheres

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