二氧化钛基纳米材料及其在清洁能源技术中的研究进展

doi:10.3724/SP.J.1077.2012.00001

无机材料学报 ›› 2012, Vol. 27 ›› Issue (1): 1-10.DOI: 10.3724/SP.J.1077.2012.00001 CSTR: 32189.14.SP.J.1077.2012.00001

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二氧化钛基纳米材料及其在清洁能源技术中的研究进展

张青红

(东华大学纤维改性国家重点实验室, 上海201620)

收稿日期:2011-09-22 修回日期:2011-09-27 出版日期:2012-01-09 网络出版日期:2011-12-19
作者简介:张青红, 男, 博士, 东华大学教授, 博士生导师. 主要从事光催化、染料敏化太阳能电池、自组装、有机/无机杂化材料的研究, 在二氧化钛纳米结构的晶相控制、形貌调控、构效关系、锐钛矿水性溶胶、可见光催化等方面成果突出, 已在Chem. Commun., Appl. Catal. B: Environ., Langmuir, J. Mater. Chem., J. Am. Ceram. Soc. 等国内外核心刊物发表学术论文80余篇, 论文他引超过1100余篇次, 单篇论文他引超过200余篇次, 获20余项中国发明专利授权, 合著《纳米氧化钛光催化材料及应用》一部. 先后主持科技部十一五支撑计划子课题1项、国家自然科学基金项目3项, 参与上海市纳米科技专项3项, 作为主要研究人员分别于2002年、2006年获得上海市自然科学奖二等奖各1项.
基金资助:
国家自然科学基金(50772127);中央高校基本科研基金

Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology

ZHANG Qing-Hong

(State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China)

Received:2011-09-22 Revised:2011-09-27 Published:2012-01-09 Online:2011-12-19
Supported by:
National Natural Science Foundation of China (50772127);Chinese Central Universities Funds

摘要/Abstract

摘要：

二氧化钛纳米材料是当前纳米科技的研究热点, 其在太阳能光催化分解水制氢、二氧化碳的光催化还原、染料敏化太阳能电池等清洁能源技术方面均显示了重大的应用前景. 本文主要综述了近年来二氧化钛基纳米材料的研究趋势、存在的主要问题, 以及这些材料在上述清洁能源利用中的最新进展. 对备受关注的非金属掺杂、高能面暴露的二氧化钛、染料敏化太阳能电池阳极致密层等热点问题进行了评述和展望.

关键词: 光解水, 二氧化碳还原, 二氧化钛, 染料敏化太阳能电池, 光催化, 综述

Abstract:

TiO₂ nanomaterials are the research hotspots among recent nanotechnologies, and those are demonstrated having the crucial application prospects in the solar light photocatalytic splitting water into hydrogen, the photocatalytic reduction of CO₂, as well as dye-sensitized solar cells. This article mainly reviewed recent research trends of TiO₂-based nanomaterials, the existing problems, and the advances in the clean energy utilization. Especially, the hot research issues such as non-metallic element doping, high energy facets exposed titania, and compact film for dye-sensitized solar cells, were commented and prospected.

Key words: photocatalytic water splitting, reduction of carbon dioxide, titanium dioxide, dye-sensitized solar cells, photocatalytic, review

中图分类号:

TB321

张青红. 二氧化钛基纳米材料及其在清洁能源技术中的研究进展[J]. 无机材料学报, 2012, 27(1): 1-10.

ZHANG Qing-Hong. Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology[J]. Journal of Inorganic Materials, 2012, 27(1): 1-10.

图/表 4

图1 氮掺杂TiO2[9](A)与TiO2/Ta3N5(B)纳米复合光催化材料的紫外-可见漫反射光谱

Fig. 1 UV-Vis diffuse reflectance spectra of nitrogen doping TiO2[9] and TiO2/Ta3N5 nanocomposite photocatalyst

图2 具有{001}高能面锐钛矿相二氧化钛的扫描电镜照片[27]

Fig. 2 SEM image of anatase TiO2 with {001} facets exposed[27]

图3 (a) 单晶锐钛矿相二氧化钛的XRD图谱; (b) 单晶锐钛矿相二氧化钛的FE-SEM照片; (c) {001}面与{101}面的夹角, 白色虚线分别代表(001)面与(101)面; (d)单晶锐钛矿相二氧化钛暴露的{110}面(以圈表示); (e)单晶锐钛矿相二氧化钛的结构示意图; (f)单晶锐钛矿相二氧化钛与不规整二氧化钛光催化降解亚甲基蓝, 不同反应时间内亚甲基蓝溶液浓度的变化[30]

Fig. 3 (a) XRD pattern of the anatase single crystals; (b) FE-SEM image of the anatase single crystals; (c) Interfacial angle between {001} and {101} facets (68.3°±0.3° on average). The white dashed lines indicate the (001) and (101) crystal planes of anatase TiO2, respectively; (d) Small rhombus {110} facets (indicated by red circle) of the anatase single crystals; (e) Schematic diagram of the anatase single crystal; (f) The variation of MB concentration by photochemical reaction with the anatase TiO2 single crystals and the irregular TiO2 product[30]

图4 锐钛矿型TiO2的晶体形貌和原子结构[32]

Fig. 4 Morphology and atomic structure of anatase TiO2 crystals[32]

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[95]	郝艳明, 石国英, 钱迪峰, 等(HAO Yan-Ming, et al). 基于锐钛矿相二氧化钛溶胶的高效染料敏化太阳能电池. 硅酸盐学报(Journal of the Chinese Ceramic Society), 2011, 39(7): 1091-1097.
[98]	作者学术成就介绍:
[99]	张青红, 男, 博士, 东华大学教授, 博士生导师. 主要从事光催化、染料敏化太阳能电池、自组装、有机/无机杂化材料的研究, 在二氧化钛纳米结构的晶相控制、形貌调控、构效关系、锐钛矿水性溶胶、可见光催化等方面成果突出, 已在Chem. Commun., Appl. Catal. B: Environ., Langmuir, J. Mater. Chem., J. Am. Ceram. Soc. 等国内外核心刊物发表学术论文80余篇, 论文他引超过1100余篇次, 单篇论文他引超过200余篇次, 获20余项中国发明专利授权, 合著《纳米氧化钛光催化材料及应用》一部. 先后主持科技部十一五支撑计划子课题1项、国家自然科学基金项目3项, 参与上海市纳米科技专项3项, 作为主要研究人员分别于2002年、2006年获得上海市自然科学奖二等奖各1项.

二氧化钛基纳米材料及其在清洁能源技术中的研究进展

Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology

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二氧化钛基纳米材料及其在清洁能源技术中的研究进展

Progress on TiO2-based Nanomaterials and Its Utilization in the Clean Energy Technology

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Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology