陶瓷材料的超塑性

摘要/Abstract

摘要： 虽然陶瓷材料在本质上是一种脆性材料；然而研究已表明细晶陶瓷材料具有超塑性，在高温下能产生很大的拉伸形变．本文综述了超塑性的特征和Y₂O₃稳定四方ZrO₂多晶体这种典型的超塑性陶瓷材料的形变机理，形变特征以及动态晶粒生长、玻璃相和产生孔穴对其超塑性形变的影响，此外，还总结了其他陶瓷材料，包括Al₂O₃、Al₂O₃－Y₂O₃稳定四方ZrO₂、纳米陶瓷和玻璃陶瓷的超塑性行为和特征．

关键词: 陶瓷, 超塑性, 塑性形变, 延展性, 晶粒生长, 玻璃相

Abstract: Although ceramic materials are considered inherently brittle, superplastic behavior has been observed in many fine-grained ceramic materials with large elongation to failure at high temperatures. This
paper reviews the major features of superplasticity, the deformation characteristics and mechanism of yttria-stabilized tetragonal zirconia polycrystals, a typical superplastic ceramic, and the effects of dynamic
grain growth, glassy phase and concurrent cavitation on the deformation behavior of Y-TZP. The superplastic behavior of other ceramic materials, including Al₂O₃ Al₂O₃-Y₂O₃ stabilized tetragonal
zirconia composites, covalent ceramic materials, nanostructured ceramics, and glass-ceramics are also summarized.

Key words: ceramics, superplasticity, plastic deformation, ductility, grain growth, glassy phase

中图分类号:

TB301

叶建东,陈楷,A．Dominguez－Rodriguez. 陶瓷材料的超塑性[J]. 无机材料学报.

YE Jian-Dong,CHEN Kai,A．Dominguez－Rodriguez. Superplasticity in Ceramics[J]. Journal of Inorganic Materials.

参考文献

1 Edington J W, Melton K N, Cutler C P. Prog. Mater. Sci., 1976, 21: 61--70
2 Bames A J. In: Heikkenen H C, McNalley T R eds. Superplasticity in Aerospace, Warrendale, PA: Metall. Soc. AIME, 1988. 301--306
3 Day R B, Stokes R J. J. Am. Ceram. Soc., 1966, 49 (7): 345--354
4 Wang J G, Raj R. J. Am. Ceram. Soc., 1984, 67 (6): 399--409
5 Wakai F, Sakaguchi S, Matsuno Y. Adv. Ceram. Mater., 1986, 1 (3): 259--263
6 Wakai F, Sakaguchi S, Kanayama K, et al. In: Bunk W, Hausner H eds. Ceramic Materials and Components for Engines, Saarbrucken, Germany: Deutsche
Keramische Gesellschaft, 1986. 315--322
7 Nich T G, McNally C M, Wadsworth J. Scripta Metallurgica, 1989, 23: 457--460
8 Yoshizawa Y, Sakuma T. Acta Metall Mater, 1992, 40 (11): 2943--2950
9 Xue L A, Chen I-W. J. Am. Ceram. Soc., 1992, 75 (5): 1085--1091
10 Konda N, Wakai F, Nishioka T, et al. J. Mater. Sci. Lett., 1995, 14 (19): 1369--1371
11 Wakai F, Kodama Y, Sakaguchi S, et al. Nature, 1990, 344: 421--423
12 Wakai F, Kodama Y, Sakaguchi S, J. Am. Ceram. Soc., 1990, 73 (2): 457--460
13 Kajihara K, Yoshizawa Y, Sakuma T. Scripta Metall. Mater., 1993, 28: 559--562
14 Nieh T G, Wadsworth J, Acta. Metall. Mater., 1990, 38 (6): 1121--1133
15 Nieh T G, Wadsworth J. Annu. Rev. Mater. Sci., 1990, 20: 117--140
16 Langdon T G. JOM, 1990, 42 (7): 8--13
17 Wakai F. Ceramic International, 1991, 17: 153--163
18 Langdon T G. Metall Trans, 1982, 13A: 689--701
19 Sherby O D, Ruano A O. In: Paton N E, Hamilton C H eds. Superplastic Forming of Structural Alloys, Warrendale, PA: Metall. Soc. AIME, 1982. 241--254
20 Nichols F A. Acta Metallurgica, 1980, 28: 663--673
21 Woodford D A. Trans. Am. Soc. Met., 1969, 62: 291--295
22 Langdon T G. In: Paton N E, Hamilton C H eds. Superplastic Forming of Structural Alloys, Warrendale, PA: Metall. Soc. AIME, 1982. 27--40
23 若井史博, 阪口修司, 加腾英纯. 窑业协会志, 1986, 94 (8): 721--725
24 Nieh T G, McNally C M, Wadsworth J. Scripta Metallurgica, 1988, 22: 1297--1300
25 Nieh T G, McNally C M, Wadsworth J. JOM, 1989, 41 (9): 31--35
26 Hermansson T, Lagerl\ddot{op K P D, Dunlop G L. In: Hamilton C H, Paton N E eds. Superplastic Forming of Structural Alloys, Warrendale, PA: Metall Soc AIME, 1988, 631--635
27 Carry C. In: Kobayashi M, Wakai F eds. Proc. MRS Int Meeting Adv. Mater., Vol 7, Superplasticity, Pittsburgh, PA: MRS, 1989. 199--215
28 Motohashi Y, Watanabe K, Kuboki I, Ohmori M. In: Kobayashi M, Wakai F eds. Proc. MRS Int Meeting Adv.Mater., Vol 7, Superplasticity, Pittsburgh, PA: MRS, 1989. 243--250
29 Duclos R, Crampon J, Amana B. Acta Metallurgica, 1989, 37 (3): 877--883
30 Hermansson T, Swan H, Dunlop G. In: With G de, Terpstra R A, Metselaar R eds. Euro-Ceramics, Vol 3. London: Elsevier, 1989. 3.329--3.333
31 Nauer M, Carry C. In: With G de, Terpstra R A, Metselaar R eds. Euro-Ceramics, Vol 3. London: Elsevier, 1989. 3.323--3.328
32 Akmoulin I A, Dzahazi M, Jonas J J. In: Horis S, Tokizane M, Furushino N eds. Superplasticity in Advanced Materials, Osska, Japan: Society for Research on Superplasticity, 1991. 233--238
33 Amana B, Duclos R, crampon J. Ceramics International, 1992, 18: 385--390
34 Owen D M, Chokshi A H. In: Badwal S P S, Bannister M, Hannink R H J eds. Science and Technology of Zirconia V, Lancaster, PA: Iecnomic Publishing, 1993. 432--439
35 Ye J D, Dominguez-Rodriguez A, Medrano R E, et al. In: Durández J F eds. Third Euro-Ceramics, Vol 3, Castellón de la Planta, Spain: Facenza
Editrice Inérica, 1993. 525--530
36 Ye J D, Dominguez-Rodrigrez A, Ruano O A, et al. In: Yan D S, Fu X R, Shi S X eds. Proc. of 5th Intl Symp on ceramic Materials and Components for Engines, Singapore: World Scientific, 1995. 398--401
37 叶建东(Ye Jiandong), 陈楷(Chen Kai), Dominguez-Rodriguez A. 崐无机材料学报(Joumal of Inorganic Materials), 1997, 12 (2): 181--186
38 Gust M, Goo G, Wolfenstine J, et al. J. Am. Ceram. Soc., 1993, 76 (7): 1681--1690
39 Ma Y, Langdon T G. Acta Metall. Mater., 1994, 42 (8): 2753--2761
40 Langdon T G. In: McNalley T R, Heikkenen H C eds. Superplasticity in Aerospace Ⅱ, Warrendale, PA: Metall. Soc. AIME, 1990. 3--18
41 Wakai f, Kodama Y, Nagano T. Lattice Deffects in Ceramics, Jpn. J. Appl. Phys. Ser., 2, 1989. 57--67
42 Nieh T G, Yaney D L, Wadsworth J. Scripta Metallurgica, 1989, 23: 2007--2012
43 Bravo-Leon A, Jimenez-Melendo M, Dominguez-Rodriguez A. J. Mater. Sci. Lett., 1994, 13 (16): 1169--1170
44 Nieh T G, Wadsworth J. Scripta Metall Mater, 1990, 24: 763--766
45 Chokshi A H. Mater. Sci. Eng., 1993, A 166: 119--133
46 叶建东. “超塑性Y-TZP的高温塑性形变”, 华南理工大学博士学位论?文, 广州, 1997.
47 Bravo-Leon A, Jimenez-Melendo M, Dominguez-Rodriguez A, et al. Seripta Materialis, 1996, 34 (7): 1155--1160
48 Bravo-Leon A, Jimenez-Melendo M, Dominguez-Rodriguez A. Acta Metallurgica, 1992, 40 (10): 2717--2726
49 Dimos D, Kohlstedt D L. J. Am. Ceram. Soc., 1978, 70 (8): 531--536
50 Solmon H, Chaumont J, Dolin C, et al. In: Mason T O, Routbort J L, eds. Ceram. Trans., Vol 24, Westerville, OH; Am. Ceram. Soc., 1991. 175--184
51 叶建东, 陈楷. 中国陶瓷, 1996, 32 (5): 6--9
52 Wakai F, Nagano T. J. Mater. Sci. Lett., 1988, 7: 607--609
53 Yoshizawq Y, Sakuma T. Eng. Frac. Mech., 1991, 40 (4/5): 847--854
54 Nieh T G, Wadsworth J. J. Am. Ceram. Soc., 1989, 72 (8): 1469--1472
55 Rai G, Grant N J. Matall Trans, A, 1975, 6: 385--390
56 Hendrix W, Kuypers S, Vangrunderbeek J, et al. Mater. Sci. Eng., 1993, A 168 (1): 45--47
57 Evans A G, Rice J R, Hirth J P. J. Am. Ceram. Soc., 1980, 63 (7-8): 368--375
58 Ye J D, Dominguez-Rodrigrez A, Chen K. In: Wang T, Chou T eds. progress in Advanced Materials and Mechanics, Proc ICAM ’96, Beijing: Peking University Press, 1996. 447--452
59 Venkatachari K R, Raj R. J. Am. Ceram. Soc., 1986, 69: 135--138
60 Gruffel P, Carry P, Mocellin A. In: Tayler D ed. Science of Ceramics, Vol 24, Shelton, UK: The Institute of Ceramics, 1988. 587--592
61 Carry C, Mocellin A. In: Vincenzini P ed. High Tech Ceramics, Amsterdam. Elsevier Science Publisher, 1987. 1043--1052
62 Yoshizawa Y, Sakuma T. Mater. Sci. Eng., 1991, A 149: 59--64
63 Xue L A. J. Mater. Sic. Lett., 1992, 11: 1395--1397
64 Wakai F, Kato H. Adv. Ceram. Mater., 1988, 3 (1): 71--76
65 Xue L A, Wu X, Chen I W. Adv. Ceram. Mater., 1991, 74: 842--845
66 Wakai F, Kodama Y, Sakaguchi S, et al. In: Kobayashi M, Wakai F eds. Proc. MRS Int Meeting Adv. Mater. Vol 7, Superplasticity, Pittsburgh, PA: MRS, 1989. 259--266
67 Pilling J, Payne J. Scripta. Metall. Mater., 1995, 32 (7): 1091--1097
68 Carry C, Mocellin A. In: Tressler R E, Bradt R C eds. Deformation of Ceramics Ⅱ, New York: Plenum, 1984. 391--403
69 Lange F F, Diaz E S. Am. Ceram. Soc. Bull., 1979, 58: 845--848
70 Rouxel T, Wakai F, Izaki K. J. Am. Ceram. Soc., 1992, 75 (9): 2363--2372
71 Wu X, Chen I W. J. Am. Ceram. Soc., 1992, 75 (10): 2733--2741
72 Langdon T G. Mater. Sci. Eng., 1993, A 166: 67--79
73 Karch J, Birringer R, Gleiter H. Nature, 1987, 330: 556--558
74 Mayo M J, Siegel R W, Narayasamy A, et al. J. Mater. Res., 1990, 5 (5): 1073--1082
75 Mayo M J, In: Hori S, Tokizane M, Furushiro N eds. Superplasticity in Advanced Materials, Osaka, Japan: Japan Society for Research on Superplasticity, 1991. 541--548
76 Wang J G, Raj R. J. Am. Ceram. Soc., 1984, 67 (6): 385--390
77 Idem. J. Am. Ceram. Soc., 1984, 67 (6): 399--409

[1]	魏相霞, 张晓飞, 徐凯龙, 陈张伟. 增材制造柔性压电材料的现状与展望[J]. 无机材料学报, 2024, 39(9): 965-978.
[2]	谭敏, 陈小武, 杨金山, 张翔宇, 阚艳梅, 周海军, 薛玉冬, 董绍明. 流延成型结合反应熔渗制备ZrB₂-SiC陶瓷及其微观结构与氧化行为研究[J]. 无机材料学报, 2024, 39(8): 955-964.
[3]	黄建锋, 梁瑞虹, 周志勇. W/Cr共掺杂对CaBi₂Nb₂O₉陶瓷晶体结构及电学性能的影响[J]. 无机材料学报, 2024, 39(8): 887-894.
[4]	范武刚, 曹雄, 周响, 李玲, 赵冠楠, 张兆泉. 8YSZ陶瓷在模拟压水堆水环境中的耐腐蚀性能[J]. 无机材料学报, 2024, 39(7): 803-809.
[5]	陈乾, 苏海军, 姜浩, 申仲琳, 余明辉, 张卓. 超高温氧化物陶瓷激光增材制造及组织性能调控研究进展[J]. 无机材料学报, 2024, 39(7): 741-753.
[6]	武向权, 滕家琛, 季祥旭, 郝禹博, 张忠明, 徐春杰. 织构化多孔Al₂O₃-SiO₂复合陶瓷片-球混合浆料特性及光强分布仿真[J]. 无机材料学报, 2024, 39(7): 769-778.
[7]	王康龙, 殷杰, 陈晓, 王力, 刘学建, 黄政仁. 颗粒级配对选区激光烧结打印结合常压固相烧结制备碳化硅陶瓷性能的影响[J]. 无机材料学报, 2024, 39(7): 754-760.
[8]	李刘媛, 黄开明, 赵秀艺, 刘会超, 王超. RE-Si-Al-O玻璃相对高熵稀土双硅酸盐微结构及耐CMAS腐蚀性能的影响[J]. 无机材料学报, 2024, 39(7): 793-802.
[9]	张育育, 吴轶城, 孙佳, 付前刚. 聚合物转化SiHfCN陶瓷的制备及其吸波性能[J]. 无机材料学报, 2024, 39(6): 681-690.
[10]	刘焱, 覃显鹏, 甘霖, 周国红, 章天金, 王士维, 陈鹤拓. 亚微米球形Y₂O₃粉体及其透明陶瓷的制备[J]. 无机材料学报, 2024, 39(6): 691-696.
[11]	蔡飞燕, 倪德伟, 董绍明. 高熵碳化物超高温陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 591-608.
[12]	刘国昂, 王海龙, 方成, 黄飞龙, 杨欢. B₄C含量对(Ti_0.25Zr_0.25Hf_0.25Ta_0.25)B₂-B₄C陶瓷力学性能及抗氧化性能的影响[J]. 无机材料学报, 2024, 39(6): 697-706.
[13]	赵日达, 汤素芳. 多孔碳陶瓷化改进反应熔渗法制备陶瓷基复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 623-633.
[14]	方光武, 谢浩元, 张华军, 高希光, 宋迎东. CMC-EBC损伤耦合机理及一体化设计研究进展[J]. 无机材料学报, 2024, 39(6): 647-661.
[15]	张幸红, 王义铭, 程源, 董顺, 胡平. 超高温陶瓷复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 571-590.