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细晶(Y/Ce,Mg)-PSZ/MgAl2O4陶瓷制备工艺及性能的研究

马亚鲁+; 袁启明; 谈家琪; 朱宣惠   

  1. +天津大学化学系; 天津300072; 天津大学材料科学与工程系 天津 300072
  • 收稿日期:1997-07-04 修回日期:1997-09-17 出版日期:1998-08-10 网络出版日期:1998-08-10

Process and Properties of Fine-grained (Y/Ce, M)-PSZ/MgAl2O4Ceramics

MA YA-Lu+; YUAN Qi-Ming; TAN Jia-Qi; ZHU Xuan-Hui   

  1. +Department of Materials Science and Engineering; Tiawtn University Tianjin 300072 China; Depatrnent of Chemistry; Tiawtn University Tiaaiin 300072 China
  • Received:1997-07-04 Revised:1997-09-17 Published:1998-08-10 Online:1998-08-10

摘要: 在化学共沉淀法制备细晶PSZ陶瓷的基础上,用工业ZrO2作原料,以MgO、Y2O3、CeO2及α-Al2O3作为复合稳定剂及添加剂,采用机械球磨混合法,并在制备过程中部分用去离子水代替乙醇作为球磨介质,探讨了水磨混合法制备粉料的可行性.实验结果表明:在较低的固溶烧结温度(1550℃)下,经1100℃适当时间热处理,亦可制备出具有较好力学性能的细晶PSZ陶瓷材料,其室温强度约700MPa,断裂韧性在15MPa·m1/2左右;在(180℃,1MPa)水热条件下,采用CeO2作复合稳定剂的PSZ陶瓷材料要比Y2O3复合稳定的PSZ材料更具良好的抗水化性.

关键词: 细晶(Y/Ce, Mg)-PSZ/MgAl2O4陶瓷, 工业ZrO2, 机械球磨混合法, 力学性能, 抗水化性

Abstract: Compared to fine-grained PSZ ceramics prepared by coprecipitation, the costabilized (Y, Mg)-PSZ and (Ce, Mg)-PSZ wigh MgAl2O4 spinel additions were developed, in
which industrial zirconia was used as the main starting material. Powders were prepared by mechanical milling-mixing process. During mixing process, distilled water was partially used as
ball-milling medium instead of ethanol. Feasibility for milling-mixing in distilled water was studied. The experimental results showed that fine-grained PSZ ceramics sintered at low solid
solution temperature (≤1550℃) could be achieved by mechanical mixing process, as well as coprecipitation. These materials had good mechanical properties: the flexural strength and
fracture toughness at room temperature were about 700MPa and 15MPa·m1/2, respectively. After hydrothermal treatment (180℃, 1MPa, in distilled water) up to 20h, (Ce, Mg)-PSZ materials
exhibited much better thermal stability than (Y, Mg)-PSZ ceramics.

Key words: fine-grained (Y/Ce, Mg)-PSZ/MgAl2O4 ceramics, industrial zirconia, mechanical milling-mixing process, mechanical properties, thermal stability

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