基于花状MoS2微米材料的葡萄糖生物传感器的制备及其性能研究

doi:10.15541/jim20150352

无机材料学报 ›› 2016, Vol. 31 ›› Issue (2): 153-158.DOI: 10.15541/jim20150352 CSTR: 32189.14.10.15541/jim20150352

基于花状MoS₂微米材料的葡萄糖生物传感器的制备及其性能研究

赵得瑞¹, 翟英娇¹, 李金华¹, 楚学影¹, 徐铭泽¹,李雪², 方铉³, 魏志鹏³, 王晓华³

(1. 长春理工大学理学院, 国际纳米光子学与生物光子学联合研究中心, 长春130022; 2. 吉林农业大学信息技术学院, 长春 130118; 3. 长春理工大学高功率半导体激光国家重点实验室, 长春130022)

收稿日期:2015-07-25 修回日期:2015-09-21 出版日期:2016-02-20 网络出版日期:2016-01-15
作者简介:赵得瑞(1988–), 女, 硕士研究生. E-mail:1173632619@qq.com
基金资助:
国家自然科学基金(61204065, 61205193, 61307045, 61404009);吉林省科技发展计划(20140520107JH, 20140204025GX)

Preparation and Properties of Glucose Biosensor Based on Flower-like MoS₂Micrometer Material

ZHAO De-Rui¹, ZHAI Ying-Jiao¹, LI Jin-Hua¹, CHU Xue-Ying¹, XU Ming-Ze¹, LI Xue², FANG Xuan³, WEI Zhi-Peng³, WANG Xiao-Hua³

(1. School of Science, International Joint Research Center for Nanophotonics and Biophotonics, Changchun University of Science and Technology, Changchun 130022, China; 2. College of Information Technology, Jilin Agriculture University, Changchun 130118, China; 3. State key laboratory of high power semiconductor laser, Changchun University of Science and Technology, Changchun 130022, China)

Received:2015-07-25 Revised:2015-09-21 Published:2016-02-20 Online:2016-01-15
About author:ZHAO De-Rui. E-mail:1173632619@qq.com
Supported by:
National Natural Science Foundation of China (61204065, 61205193, 61307045, 61404009);Developing Project of Science and Technology of Jilin Province (20140520107JH, 20140204025GX)

摘要/Abstract

摘要：

本研究采用水热法制备了花状MoS₂微米材料, 将其作为电极构建葡萄糖生物传感器, 并研究了相关性能。结果表明: 水热法制备的MoS₂呈花状, 具有较好的结晶质量, 尺寸约为3.6 μm, 比表面积约为9.646 m²/g; MoS₂电极具有优良的电催化活性, 且电阻抗较小, 使得传感器对葡萄糖具有较好的响应。葡萄糖检测结果表明, 该传感器在0~20 mmol/L范围内, 氧化峰电流与葡萄糖浓度呈良好的线性关系, 相关系数(R)为0.9653, 灵敏度为262 μA•L/mmol。

关键词: MoS2, 水热法, 微米花, 生物传感器

Abstract:

Flower-like MoS₂ micrometer material was successfully synthesized by hydrothermal reaction, which was then used to prepare the glucose biosensor. The performance of the prepared glucose biosensor was examined. Results indicated that as-synthesized MoS₂ is flower-like structure in good crystallinity at ~3.6 μm in length with specific surface area 9.646 m²/g. The biosensor with MoS₂ electrode has a high responsivity of glucose, due to good electrocatalytic activity and small electrical impedance of MoS₂. Glucose detection revealed that oxidation peak current showed a good linear relationship with glucose concentration in the range of 0~20 mmol/L with a correlation coefficient (R) 0.9653. The sensitivity is 262 μA•L/mmol.

Key words: MoS2, hydrothermal method, micron flower, biosensor

中图分类号:

O469

赵得瑞, 翟英娇, 李金华, 楚学影, 徐铭泽,李雪, 方铉, 魏志鹏, 王晓华. 基于花状MoS₂微米材料的葡萄糖生物传感器的制备及其性能研究[J]. 无机材料学报, 2016, 31(2): 153-158.

ZHAO De-Rui, ZHAI Ying-Jiao, LI Jin-Hua, CHU Xue-Ying, XU Ming-Ze, LI Xue, FANG Xuan, WEI Zhi-Peng, WANG Xiao-Hua. Preparation and Properties of Glucose Biosensor Based on Flower-like MoS₂Micrometer Material[J]. Journal of Inorganic Materials, 2016, 31(2): 153-158.

图/表 7

图1 MoS2样品的XRD图谱

Fig. 1 XRD pattern of MoS2 sample

图2 不同倍率下MoS2的SEM照片及EDS能谱

Fig. 2 Different magnification SEM images of MoS2 at5000 times (a), 10000 times (b), 20000 times (c), and EDS spectrum (d) of MoS2

图3 MoS2 样品的(a) BJH孔径分布图及其(b) N2等温吸附-脱附曲线

Fig. 3 (a) BJH pore size distributiona and (b) nitrogen adsorption-desorption isotherms of MoS2

图4 MoS2电极的(a)循环伏安曲线(扫描速率范围10~100 mV/s) 和(b)氧化还原峰电流与扫描速率平方根的线性拟合曲线图

Fig. 4 Cyclic voltammetry curves (scan rate range 10-100 mV/s) (a) and redox peak current and scan rate of the square root of the linear fitting curve of MoS2 electrode (b)

图5 电极NF和MoS2-NF的交流阻抗谱(插图为等效电路)

Fig. 5 AC impedance spectrum of NF electrodes and MoS2-NF electrodes (Inset with its equivalent circuit)

图6 电解液中加入葡萄糖前后MoS2电极的循环伏安曲线

Fig. 6 Cyclic voltammetry curves of MoS2 electrodes in the electrolyte before (a) and after (b) the addition of glucose

图7 MoS2电极检测葡萄糖

Fig. 7 MoS2 electrode for glucose detection (a) MoS2 electrode detecting cyclic voltammetry curves of different concentrations of glucose solution; (b) Linear relationship diagram of glucose concentration and oxidation peak current

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基于花状MoS₂微米材料的葡萄糖生物传感器的制备及其性能研究

Preparation and Properties of Glucose Biosensor Based on Flower-like MoS₂Micrometer Material

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