含钒介孔空心球的合成

doi:10.3724/SP.J.1077.2012.11503

无机材料学报 ›› 2012, Vol. 27 ›› Issue (7): 699-705.DOI: 10.3724/SP.J.1077.2012.11503 CSTR: 32189.14.SP.J.1077.2012.11503

含钒介孔空心球的合成

时晓波, 陈玉, 孔岩, 吴丞, 王军

(南京工业大学化学化工学院, 材料化学工程国家重点实验室, 南京 210009)

收稿日期:2011-08-12 修回日期:2011-11-17 出版日期:2012-07-20 网络出版日期:2012-06-06
作者简介:时晓波(1985-), 男, 硕士研究生.
基金资助:
国家自然科学基金(20876077); 江苏省自然科学基金支撑计划(BE2008142); 江苏省高校自然科学基金重大项目(10KJA530015)

Synthesis of Vanadium-mesoporous Hollow Spheres

SHI Xiao-Bo, CHEN Yu, KONG Yan, WU Cheng, WANG Jun

(State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China)

Received:2011-08-12 Revised:2011-11-17 Published:2012-07-20 Online:2012-06-06
About author:SHI Xiao-Bo
Supported by:
National Natural Science Foundation of China (20876077); Natural Science Foundation of Jiangsu Province R&D Program (BE2008142); University Natural Science Foundation of Jiangsu Province (10KJA530015)

摘要/Abstract

摘要： 以十六烷基三甲基溴化铵、十二烷基硫酸钠和P123三种表面活性剂为共模板剂合成了含钒介孔空心球, 研究了钒含量及反应条件对空心球形成的影响. 结果表明: 当n(V)/n(Si)低于0.05时不能形成空心球, 而n(V)/n(Si)过大时, 大部分钒在材料中以氧化物形式出现, 合适的n(V)/n(Si)为0.1. 最佳反应条件为pH值5.0, 45℃反应2 h. 产物结构规整, 且对苯乙烯过氧化氢选择氧化反应有着良好的催化性能.

关键词: 钒, 介孔材料, 空心球

Abstract: Vanadium-containing mesoporous silica with hollow spherical morphology was successfully synthesized by using CTAB, SDS and P123 as co-template. The influences of vanadium content and reaction conditions on the formation of the materials were also studied. Results indicated that the hollow spheres could not be shaped as molar ratio of V to Si was lower than 0.05 while excess vanadium content led large amount of vanadium oxides existed in the materials. The adequate molar ratio of V to Si was 0.1. The optimal synthesis conditions were reacted at 45℃ for 2 h under pH value of 5. The products with regular structure and morphology exhibited high catalytic activity on the selective oxidation of styrene by hydrogen peroxide.

Key words: vanadium, mesoprous materials, hollow spheres

中图分类号:

O643

时晓波, 陈玉, 孔岩, 吴丞, 王军. 含钒介孔空心球的合成[J]. 无机材料学报, 2012, 27(7): 699-705.

SHI Xiao-Bo, CHEN Yu, KONG Yan, WU Cheng, WANG Jun . Synthesis of Vanadium-mesoporous Hollow Spheres[J]. Journal of Inorganic Materials, 2012, 27(7): 699-705.

参考文献

[1] Wang A J, Lu Y P, Sun R X. Recent progress on the fabrication of hollow microspheres. Mater. Sci. Eng. A,2007, 460-461: 1-6.

[2] 梁志武, 郝广杰, 申小义, 等. 中空结构聚合物微粒的制备方法. 高分子通报, 2003 (5): 36-41.

[3] Hu Y, Ge J, Sun Y, et al. A self-templated approach to TiO2 microcapsules. Nano Lett., 2007, 7(6): 1832-1836.

[4] Chen J F, Ding H M, Wang J X, et al. Preparation and characterization of porous hollow silica nanoparticles for drug delivery application. Biomaterials, 2004, 25(4): 723-727.

[5] Zhang Y, Chu Y, Yang Y, et al. Fabrication of polystyrene-CPbS core-shell and hollow PbS microspheres with sulfonated polystyrene templates. Colloid. Polym. Sci., 2007, 285(9): 1061-1066.

[6] Zheng J, Song X, Zhang Y, et al. Nano-sized aluminum nitride hollow spheres formed through a self-templating solid-gas interface reactionJ. J. Solid State Chem., 2007, 180(1): 276-283.

[7] Banerjee S, Premchandran R, Tata M, et al. Polymer precipitation using a micellar nonsolvent: the role of surfactant polymer interactions and the development of a microencapsulation technique. Ind. Eng. Chem. Res.,1996, 35(9): 3100-3107.

[8] Cha J N, Bartl M H, Wong M S, et al. Microcavity lasing from block peptide hierarchically assembled quantum dot spherical resonators. Nano Lett., 2003, 3(7): 907-911.

[9] 刘桂霞, 洪广言, 王进贤, 等. 无机中空球壳材料的制备方法. 化学通报, 2006(10): 749-754.

[10] 白飞燕, 方仕江. 模板法技术制备中空聚合物微球的进展. 胶体与聚合物, 2004, 23(4): 26-30.

[11] 甘治平, 官建国. 硬模法制备无机空心球的研究进展. 材料导报, 2007, 21(5): 105-108.

[12] 曾文, 徐宏, 古宏晨. 氧化硅空心微球的制备及表面形貌的调控. 动能材料, 2008, 39(6): 975-978.

[13] Yu J, Liu W, Yu H. A one-pot approach to hierarchically nanoporous titania hollow microspheres with high photocatalytic activity. Cryst. Grow. Design, 2008, 8(3): 930-934.

[14] 余承忠, 范杰, 赵东元(YU Cheng-Zhong, et al). 利用嵌段共聚物及无机盐合成高质量的立方相、大孔径介孔氧化硅球. 化学学报(Acta Chim. Sinica), 2002, 60(8): 1357-1360.

[15] Zhu Y, Shi J, Chen H, et al. A facile method to synthesize novel hollow mesoporous silica spheres and advanced storage property. Micro. Meso. Mater., 2005, 84(1): 218-222.

[16] Zhao D Y, Feng J L, Huo Q S, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science, 1998, 279(5350): 548.

[17] Parida K M, Rath D. Structural properties and catalytic oxidation of benzene to phenol over CuO-impregnated mesoporous silica. Applied Catalysis A: General, 2007. 321(2): 101-108.

[18] Uphade B, Akita T, Nakamura T, et al. Vapor-phase epoxidation of propene using H2 and O2 over Au/Ti-MCM-48. J. Catal., 2002, 209(2): 331-340.

[19] Ma Y, Qi L, Ma J, et al. Large-pore mesoporous silica spheres: synthesis and application in HPLC. Colloids Sur A: Physicochem. Eng. Aspects, 2003, 229(1): 1-8.

[20] 格林伍德N N. 元素化学(下册). 北京: 高等教育出版社, 1996: 113.

[21] Kim S S, Karkamkar A, Pinnavaia T J, et al. Synthesis and characterization of ordered, very large pore MSU-H silicas assembled from water-soluble silicates. J. Phys. Chem. B, 2001, 105(32): 7663-7670.

[22] Todorova S, Pārvulescu V, Kadinov G, et al. Metal states in cobalt- and cobalt-vanadium-modified MCM-41 mesoporous silica catalysts and their activity in selective hydrocarbons oxidation. Microporous Mesoporous Mater., 2008, 113(1/2/3): 22-30.

[23] Zhang Q, Wang Y, Itsuki S, et al. Manganese-containing MCM-41 for epoxidation of styrene and stilbene. J. Mol. Catal. A: Chem., 2002, 188(1/2): 189-200.

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含钒介孔空心球的合成

Synthesis of Vanadium-mesoporous Hollow Spheres

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