RuFe纳米粒子修饰片状BiVO4协同催化氨硼烷水解产氢

doi:10.15541/jim20190502

无机材料学报 ›› 2020, Vol. 35 ›› Issue (7): 809-816.DOI: 10.15541/jim20190502 CSTR: 32189.14.10.15541/jim20190502

所属专题：能源材料论文精选(四)：光催化与电催化(2020)

RuFe纳米粒子修饰片状BiVO₄协同催化氨硼烷水解产氢

张翊青,张淑娟,万正睿,莫晗,王念贵(),周立群()

湖北大学化学化工学院, 有机化工新材料湖北省协同创新中心, 有机功能分子合成与应用教育部重点实验室, 武汉 430062

收稿日期:2019-09-30 修回日期:2019-12-28 出版日期:2020-07-20 网络出版日期:2020-03-03
作者简介:张翊青(1995-), 女, 硕士研究生. E-mail: zhangyq95@163.com
ZHANG Yiqing (1995-), female, Master candidate. E-mail: zhangyq95@163.com
基金资助:
湖北省自然科学基金(2010CDB04701);有机功能分子合成与应用教育部重点实验室项目(KLSAOFM1913)

RuFe Nanoparticles Modified Sheet-like BiVO₄ : High-efficient Synergistic Catalyst for Ammonia Borane Hydrolytic Dehydrogenation

ZHANG Yiqing,ZHANG Shujuan,WAN Zhengrui,MO Han,WANG Niangui(),ZHOU Liqun()

Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China

Received:2019-09-30 Revised:2019-12-28 Published:2020-07-20 Online:2020-03-03
Supported by:
Hubei Provincial Natural Science Foundation(2010CDB04701);Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules of China(KLSAOFM1913)

摘要/Abstract

摘要：

开发高效廉价的催化剂对于清洁能源经济至关重要, 将氨硼烷的催化水解用于氢能源开发前景广阔。本工作首先采用简单回流法制备BiVO₄纳米片, 再通过浸渍还原法制备出Ru/Fe不同摩尔比的RuFe@BiVO₄催化剂, 并在室温下用于催化氨硼烷水解产氢。通过比较载体BiVO₄、Ru@BiVO₄、Fe@BiVO₄、RuFe@BiVO₄以及无载体的RuFe纳米粒子的催化产氢速率发现, 在所有的催化剂中, Ru₁Fe_0.1@BiVO₄具有最高的催化活性, 非贵金属Fe能显著增强Ru的催化性能, 这与RuFe之间强的电子效应以及RuFe纳米粒子与载体BiVO₄间的双功能效应密切相关, 其活化能(E_a)为43.7 kJ·mol^-1, 转化频率(TOF)为205.4 mol_H2·mol_Ru·min^-1。

关键词: 钒酸铋, RuFe纳米粒子, 协同催化, 氨硼烷, 产氢

Abstract:

Developing highly efficient and low-cost catalysts is crucial in the field of clean energy economy, in which ammonia borane (AB) has attracted great attention due to its high hydrogen production through the catalytic hydrolysis. In this work, BiVO₄ nanosheet was firstly synthesized by a facile reflux method. And then bimetallic RuFe@BiVO₄ catalysts with different molar ratios of Ru/Fe were prepared via in situ impregnation-reduction techniques and their catalytic activities were also tested in the hydrogen generation from aqueous solution of AB at room temperature. Compared with the releasing hydrogen rates of catalysts of BiVO₄, Ru@BiVO₄, Fe@BiVO₄, RuFe NPs and RuFe@BiVO₄, respectively, Ru₁Fe_0.1@BiVO₄ exhibits the highest catalytic activity for the dehydrogenation of AB among all catalysts, the activation energy (E_a) and turnover frequency (TOF) are 43.7 kJ·mol^-1 and 205.4 mol_H2·mol_Ru·min^-1, respectively. The addition of non-noble Fe can significantly enhance the catalytic activity of Ru counterparts, which is closely related to the strong electronic effect between Ru and Fe NPs, bi-functional effect generated between the RuFe NPs and the support BiVO₄.

Key words: BiVO₄, RuFe nanoparticles, synergistic catalysis, ammonia borane, releasing hydrogen

中图分类号:

O643

张翊青,张淑娟,万正睿,莫晗,王念贵,周立群. RuFe纳米粒子修饰片状BiVO₄协同催化氨硼烷水解产氢[J]. 无机材料学报, 2020, 35(7): 809-816.

ZHANG Yiqing,ZHANG Shujuan,WAN Zhengrui,MO Han,WANG Niangui,ZHOU Liqun. RuFe Nanoparticles Modified Sheet-like BiVO₄ : High-efficient Synergistic Catalyst for Ammonia Borane Hydrolytic Dehydrogenation[J]. Journal of Inorganic Materials, 2020, 35(7): 809-816.

图/表 10

图1 BiVO4、Ru@BiVO4、Fe@BiVO4、Ru1Fe0.1@BiVO4和五次循环后Ru1Fe0.1@BiVO4的XRD图谱

Fig. 1 XRD patterns of BiVO4, Ru@BiVO4, Fe@BiVO4, Ru1Fe0.1@BiVO4 and Ru1Fe0.1@BiVO4 after five cycles

图2 BiVO4(A, B)、Ru1Fe0.1@BiVO4(C)和RuFe纳米粒子(E)的TEM照片; Ru1Fe0.1@BiVO4(D)、RuFe纳米粒子(F)的粒径分布图

Fig. 2 TEM images of BiVO4 (A, B), Ru1Fe0.1@BiVO4 (C) and RuFe NPs (E); particle size distributions of Ru1Fe0.1@BiVO4 (D) and RuFe NPs (F)

图3 Ru1Fe0.1@BiVO4(A)的FESEM照片及其相应的元素分布图(B)和EDS图谱(C)

Fig. 3 FESEM image (A); elemental mappings of Ru and Fe (B) and EDS pattern of Ru1Fe0.1@BiVO4 (C)

图4 Ru1Fe0.1@BiVO4催化剂的XPS图谱

Fig. 4 XPS spectra of the Ru1Fe0.1@BiVO4 catalysts (A) Survey; (B) Ru3p; (C) Fe2p; (D) Bi4f; (E) V2p; (F) O1s

图5 BiVO4、Ru1Fe0.1@BiVO4和五次循环后Ru1Fe0.1@BiVO4的红外光谱图

Fig. 5 FT-IR spectra of BiVO4, Ru1Fe0.1@BiVO4 and Ru1Fe0.1@BiVO4 after five cycles

表1 RuFe@BiVO4催化剂中元素的ICP-AES分析结果

Table 1 ICP-AES analyses results of RuFe@BiVO4 catalyst

Catalyst	Initial ratio of Ru : Fe	Actual ratio of Ru : Fe	Actual Ru loading/wt%
RuFe@BiVO₄	1 : 0.10	1 : 0.12	4.21

图6 不同催化剂对AB水解产氢速率图

Fig. 6 Plots of n(H2)/n(AB) vs. time from the hydrolysis of AB (18.5 mg) (A) Catalysts with the same nanoparticles loadings; (B) Ru1Fex NPs; (C) Ru1Fex@BiVO4 ; (D) Catalysts with different supporters

图7 Ru1Fe0.1@BiVO4催化AB水解机理示意图

Fig. 7 Mechanism of AB hydrolysis catalyzed by the Ru1Fe0.1@BiVO4 catalyst

图8 温度对Ru1Fe0.1@BiVO4催化水解氨硼烷的影响曲线(A)及其相应的阿伦尼乌斯图(B), 催化剂五次循环稳定性(C)

Fig. 8 Plots of n(H2)/n(AB) vs. time for the hydrolysis of AB catalyzed by Ru1Fe0.1@BiVO4 at different temperatures(A) and corresponding Arrhenius plots (B), and cycling test for the Ru1Fe0.1@BiVO4 within five cycles (C)

表2 不同钌基催化剂用于AB水解脱氢的催化活性

Table 2 Catalytic activities of different Ru-based catalysts used for the hydrolytic dehydrogenation of AB

Catalyst	TOF/(mol_H2?mol_Ru?min^-1)	E_a/(kJ?mol^-1)	Ref.
Ru NPs	26.7	66.5	[30]
RuCu(1 : 1)/γ-Al₂O₃	16.4	52	[31]
RuCo(1 : 11)/γ-Al₂O₃	32.9	47.0	[31]
RuCuCo@MIL-101	241.2	48.0	[32]
Ru@g-C₃N₄	313.0	37.4	[33]
RuCu/graphene	135.0	30.6	[34]
Ru₁Fe_0.1@BiVO₄	205.4	43.7	This study

参考文献 34

[1]	EDWARDS P P, KUZNETSOV V L, DAVID W I F, et al. Hydrogen and fuel cells: towards a sustainable energy future. Energy Policy, 2008,36(12):4356-4362. DOI URL
[2]	EBERLE U, FELDERHOFF M, SCHUETH F. ChemInform abstract: chemical and physical solutions for hydrogen storage. Angewandte Chemie International Edition, 2009,40(48):6608-6630.
[3]	CHANDRA M, XU Q. A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia-borane. Journal of Power Sources, 2006,156(2):190-194. DOI URL
[4]	YANG J, SUDIK A, WOLVERTON C, et al. High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery. Chemical Society Review, 2010,39(2):656-675. DOI URL
[5]	GROCHALA W, EDWARDS P P. Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen. Chemical Reviews, 2004,104(3):1283-1316. DOI URL PMID
[6]	SUN D, MAZUMDER V, ÖNDER METIN, et al. Catalytic hydrolysis of ammonia borane via cobalt palladium nanoparticles. ACS Nano, 2011,5(8):6458-6464. DOI URL PMID
[7]	CHEN G, DESINAN S, RENZO R, et al. Synthesis of Ni-Ru alloy nanoparticles and their high catalytic activity in dehydrogenation of ammonia borane. Chemistry - A European Journal, 2012,18(25):7925-7930. DOI URL
[8]	QU XIAO-PENG, YU ZHI-QIANG, LI ZE-PING, et al. CoRh nanoparticles supported on ZIF-67 as highly efficient catalysts for hydrolytic dehydrogenation of ammonia boranes for chemical hydrogen storage. International Journal of Hydrogen Energy, 2017, 42(51), 30037-30047. DOI URL
[9]	ZHANG L, ZHOU LI-QUN, YANG KUN-ZHOU, et al. Pd-Ni nanoparticles supported on MIL-101 as high-performance catalysts for hydrogen generation from ammonia borane. Journal of Alloys & Compounds, 2016,677:87-95.
[10]	CHEN MENG-HUAN, ZHOU LI-QUN, LU DI, et al. RuCo bimetallic alloy nanoparticles immobilized on multi-porous MIL-53(Al) as a highly efficient catalyst for the hydrolytic reaction of ammonia borane. International Journal of Hydrogen Energy, 2018,43(3):1439-1450. DOI URL
[11]	LI JUN, ZHU QI-LONG, XU QIANG. Non-noble bimetallic CuCo nanoparticles encapsulated in the pores of metal-organic frameworks: synergetic catalysis in the hydrolysis of ammonia borane for hydrogen generation. Catal. Sci. Technol., 2015,5(1):525-530. DOI URL
[12]	ZHANG XIN-BO, YAN JUN-MIN, HAN SONG, et al. Magnetically recyclable Fe@Pt core-shell nanoparticles and their use as electrocatalysts for ammonia borane oxidation: the role of crystallinity of the core. Journal of the American Chemical Society, 2009,131(8):2778-2779. DOI URL PMID
[13]	WETCHAKUN N, CHAIWICHAIN S, INCEESUNGVORN B, et al. BiVO₄/CeO₂ nanocomposites with high visible-light-induced photocatalytic activity. ACS Applied Materials & Interfaces, 2012,4(7):3718-3723. DOI URL PMID
[14]	ABDI F F, SAVENIJE T J, MAY M M, et al. The origin of slow carrier transport in BiVO₄ thin film photoanodes: a time-resolved microwave conductivity study. The Journal of Physical Chemistry Letters, 2013,4(16):2752-2757. DOI URL
[15]	DAVID W I F, WOOD I G. Ferroelastic phase transition in BiVO₄ : VI. Some comments on the relationship between spontaneous deformation and domain walls in ferroelastics. Journal of Physics C: Solid State Physics, 1983,16(26):5149-5166. DOI URL
[16]	WANG S, CHEN P, BAI Y., et al. New BiVO₄ dual photoanodes with enriched oxygen vacancies for efficient solar-driven water splitting. Advanced Materials, 2018,30(20):8500-8504.
[17]	XI G, YE J. Synthesis of bismuth vanadate nanoplates with exposed {001} facets and enhanced visible-light photocatalytic properties. Chemical Communications, 2010,46(11):1893-1895. DOI URL PMID
[18]	ZHOU L, WANG W Z, ZHANG L S, et al. Single-crystalline BiVO₄ microtubes with square cross-sections: microstructure, growth mechanism, and photocatalytic property. J. Phys. Chem. C, 2007,111(37):13659-13664. DOI URL
[19]	YANG K, ZHOU L, YU G, et al. Ru nanoparticles supported on MIL-53(Cr, Al) as efficient catalysts for hydrogen generation from hydrolysis of ammonia borane. Internal Journal of Hydrogen Energy, 2016,41(15):6300-6309.
[20]	CAO N, SU J, LUO W, et al. Ni-Pt nanoparticles supported on MIL-101 as highly efficient catalysts for hydrogen generation from aqueous alkaline solution of hydrazine for chemical hydrogen storage. International Journal of Hydrogen Energy, 2014,39(18):9726-9734. DOI URL
[21]	DAI Z R, PAN Z W, WANG Z L. Gallium oxide nanoribbons and nanosheets. The Journal of Physical Chemistry B, 2002,106(5):902-904. DOI URL
[22]	RAKAP M. PVP-stabilized Ru-Rh nanoparticles as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane. Journal of Alloys & Compounds, 2015,649:1025-1030.
[23]	TAN PING-LIAN. Active phase, catalytic activity, and induction period of Fe/zeolite material in nonoxidative aromatization of methane. Journal of Catalysis, 2016,338:21-29. DOI URL
[24]	ZHANG L, CHEN D, JIAO X. Monoclinic structured BiVO₄ nanosheets: hydrothermal preparation, formation mechanism, and coloristic and photocatalytic properties. The Journal of Physical Chemistry B, 2006,110(6):2668-2673. DOI URL PMID
[25]	WANG Y, TAN G, LIU T, et al. Photocatalytic properties of the g-C₃N₄/{010} facets BiVO₄, interface Z-Scheme photocatalysts induced by BiVO₄, surface heterojunction. Applied Catalysis B: Environmental, 2018,234:37-49. DOI URL
[26]	NING HONG-HUI LU DI ZHOU LI-QUN, et al. Bimetallic RuM(M=Co, Ni) alloy NPs supported on MIL-110(Al): synergetic catalysis in hydrolytic dehydrogenation of ammonia borane. Chinese Journal of Chemical Physics, 2018,31(1):99-109. DOI URL
[27]	LI Y, DAI Y, TIAN X K. Controlled synthesis of monodisperse Pd_xSn₁₀₀-_x nanoparticles and their catalytic activity for hydrogen generation from the hydrolysis of ammonia-borane. International Journal of Hydrogen Energy, 2015,40(30):9235-9243.
[28]	WANG QI, FU FANG-YU, YANG SHA, et al. Dramatic synergy in CoPt nanocatalysts stabilized by “click” dendrimers for hydrogen evolution from hydrolysis of ammonia borane. ACS Catalysis, 2019,9(2):1110-1119. DOI URL
[29]	CAO N, LIU T, SU J, et al. Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes. New Journal of Chemistry, 2014,38(9):4032-4035. DOI URL
[30]	ZHOU Q, YANG H, XU C. Nanoporous Ru as highly efficient catalyst for hydrolysis of ammonia borane. International Journal of Hydrogen Energy, 2016,41(30):12714-12721. DOI URL
[31]	RACHIERO G P, DEMIRCI U B, MIELE P. Bimetallic RuCo and RuCu catalysts supported on γ-Al₂O₃. A comparative study of their activity in hydrolysis of ammonia-borane. International Journal of Hydrogen Energy, 2011,36(12):7051-7065. DOI URL
[32]	YANG K, ZHOU L, XING X, et al. RuCuCo nanoparticles supported on MIL-101 as a novel highly efficient catalysts for the hydrolysis of ammonia borane. Microporous & Mesoporous Materials, 2016,225:1-8.
[33]	FAN YAN-RU, LI XIAO-JING, HE XIAO-CHUN, et al. Effective hydrolysis of ammonia borane catalyzed by ruthenium nanoparticles immobilized on graphic carbon nitride. International Journal of Hydrogen Energy, 2014,39(35):19982-19989. DOI URL
[34]	CAO N, KAI H U, LUO W, et al. RuCu nanoparticles supported on graphene: a highly efficient catalyst for hydrolysis of ammonia borane. Journal of Alloys & Compounds, 2014,590(27):241-246.

RuFe纳米粒子修饰片状BiVO₄协同催化氨硼烷水解产氢

RuFe Nanoparticles Modified Sheet-like BiVO₄ : High-efficient Synergistic Catalyst for Ammonia Borane Hydrolytic Dehydrogenation

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 34

相关文章 13

编辑推荐

Metrics

本文评价

[1]	吐尔洪·木尼热, 赵红刚, 马玉花, 齐献慧, 李钰宸, 闫沉香, 李佳文, 陈平. 单晶WO₃/红磷S型异质结的构建及光催化活性研究[J]. 无机材料学报, 2023, 38(6): 701-707.
[2]	陈瀚翔, 周敏, 莫曌, 宜坚坚, 李华明, 许晖. CoN/g-C₃N₄ 0D/2D复合结构及其光催化制氢性能研究[J]. 无机材料学报, 2022, 37(9): 1001-1008.
[3]	胡越, 安琳, 韩鑫, 侯成义, 王宏志, 李耀刚, 张青红. RhO₂修饰BiVO₄薄膜光阳极的制备及其光电催化分解水性能[J]. 无机材料学报, 2022, 37(8): 873-882.
[4]	徐晶威,李政,王泽普,于涵,何祺,付念,丁帮福,郑树凯,闫小兵. 交错能带结构钕掺杂钒酸铋形貌与光催化性能调控[J]. 无机材料学报, 2020, 35(7): 789-795.
[5]	张翊青, 刘梨, 张淑娟, 万正睿, 刘红英, 周立群. NH₂-UIO-66负载RuCuMo纳米催化剂的制备及其催化产氢[J]. 无机材料学报, 2019, 34(12): 1316-1324.
[6]	周民杰, 张娜, 侯朝辉. 石墨烯-ZnIn₂S₄纳米复合微球的制备及光催化产氢活性[J]. 无机材料学报, 2015, 30(7): 713-718.
[7]	王敏, 刘琼, 孙亚杰, 车寅生, 姜承志. 溶胶-凝胶法制备Eu³⁺掺杂BiVO₄及其可见光光催化性能[J]. 无机材料学报, 2013, 28(2): 153-158.
[8]	郭佳, 朱毅, 张渊明, 李明玉, 杨骏. 不同结构形貌BiVO₄的水热制备及可见光催化性能[J]. 无机材料学报, 2012, 27(1): 26-32.
[9]	阎建辉,张丽,朱裔荣,唐有根,杨海华. NiO(CoO)/N-SrTiO₃异质结型复合光催化剂的制备及模拟太阳光催化产氢[J]. 无机材料学报, 2009, 24(4): 666-670.
[10]	戈磊,张宪华. 微乳液法合成新型可见光催化剂BiVO₄及光催化性能研究[J]. 无机材料学报, 2009, 24(3): 453-456.
[11]	戈磊. 新型Pt/BiVO₄可见光活性光催化剂的制备和表征[J]. 无机材料学报, 2008, 23(3): 449-453.
[12]	朱裔荣,唐有根,阎建辉,刘强. 氮掺杂SrTiO₃的制备及其可见光催化产氢活性研究[J]. 无机材料学报, 2008, 23(3): 443-448.
[13]	张林森,王为,李振亚. Ni/AC膜电极-铝合金储氢电池的研究[J]. 无机材料学报, 2006, 21(5): 1103-1108.