掺磷四面体非晶碳薄膜电极的电化学伏安特性

doi:10.3724/SP.J.1077.2007.01056

无机材料学报

掺磷四面体非晶碳薄膜电极的电化学伏安特性

刘爱萍, 朱嘉琦, 韩杰才, 韩潇, 吴化平

哈尔滨工业大学复合材料与结构研究所, 哈尔滨 150001

收稿日期:2006-12-17 修回日期:2007-01-31 出版日期:2007-11-20 网络出版日期:2007-11-20

Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode

LIU Ai-Ping, ZHU Jia-Qi, HAN Jie-Cai, HAN Xiao, WU Hua-Ping

Center for Composite Materials, Harbin Institute of Technology, Harbin 150001, China

Received:2006-12-17 Revised:2007-01-31 Published:2007-11-20 Online:2007-11-20

摘要/Abstract

摘要： 采用过滤阴极真空电弧技术, 以高纯磷烷气体为掺杂源制备掺磷四面体非晶碳(ta-C:P)薄膜. 利用X射线光电子能谱和激光拉曼光谱表征薄膜的成分和结构, 采用循环伏安和微分脉冲伏安分析薄膜的电化学行为. 结果表明, 磷的掺入没有引起薄膜非晶结构的明显变化, 只是促进了sp²杂化碳原子的团簇. 经过酸预处理的ta-C:P薄膜在硫酸溶液中有宽的电势窗口和低的背景电流; 对Cl^-有催化活性; 薄膜表面电子传输速度快; 对水溶液中Cu²⁺和Cd²⁺有检测活性. 因此具有良好导电性的ta-C:P薄膜适于作为电极并有望用于污水中重金属离子的分析检测等领域.

关键词: 过滤阴极真空电弧, 掺磷四面体非晶碳, 电极, 伏安行为

Abstract: Phosphorus incorporated tetrahedral amorphous carbon (ta-C:P) film was deposited by a filtered cathodic vacuum arc technology with PH3 as the dopant source. The composition and structural characteristics were investigated by X-ray photoelectron spectroscope and Raman spectroscope, and the electrochemical behaviors of ta-C:P film were examined by cyclic voltammetry and differential pulse voltammetry. Results indicate that phosphorus implantation does not remarkably change the amorphous structure of the film but enhances the clustering of sp² sites dispersed in sp3 skeleton and the evolution of structrual ordering. Ta-C:P film pretreated by acid exhibits a large electrochemical potential window and a low background current in H₂SO₄ solution, a considerable electrochemical activity toward Cl^-, quick electrode response and a high signal for Cu²⁺ and Cd²⁺ analysis. These characteristics greatly demonstrate a potential application of conductive ta-C:P film as electrodes for analysis and treatment of trace metal ions in waste water.

Key words: filtered cathodic vacuum arc, phosphorus incorporated tetrahedral amorphous carbon

中图分类号:

刘爱萍,朱嘉琦,韩杰才,韩潇,吴化平. 掺磷四面体非晶碳薄膜电极的电化学伏安特性[J]. 无机材料学报, DOI: 10.3724/SP.J.1077.2007.01056.

LIU Ai-Ping,ZHU Jia-Qi,HAN Jie-Cai,HAN Xiao,WU Hua-Ping. Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2007.01056.

参考文献

[1] Hupert M, Muck A, Wang R, et al. Diamond and Related Materials, 2003, 12 (10-11): 1940--1949.
[2] Compton R G, Foord J S, Marken F. Electroanalysis, 2003, 15 (17): 1349--1363.
[3] Panizza M, Cerisola G. Electrochimica Acta, 2005, 51 (2): 191--199.
[4] Weng J, Xue J M, Wang J, et al. Adv. Funct. Mater., 2005, 15 (4): 639--647.
[5] Robertson J. Mater. Sci. Eng. R, 2002, 37: 129--281.
[6] 陈弟虎, 等(CHEN Di-Hu, { et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (1): 179--182.
[7] 蒋娜哪, 等(JIANG Na-Na, { et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20 (1): 187--192.
[8] Yoo K S, Miller B, Kalish R, et al. Electrochem. Solid-State Lett., 1999, 2 (5): 233--235.
[9] Cheah L K, Shi X, Tay B K, et al. Diam. Relat. Mater., 1998, 7 (2-5): 640--644.
[10] Ma Z Q, Liu B X. Sol. Energ. Mat. Sol. C, 2001, 69 (4): 339--344.
[11] Rusop M, Soga T, Jimbo T. Diam. Relat. Mater., 2004, 13 (11-12): 2197--2202.
[12] Pleskov Y V, Evstefeeva Y E, Krotova M D, et al. Diam. Relat. Mater., 1999, 8 (1): 64--72.
[13] Zeng A, Liu E, Tan S N, et al. Eletroanalysis, 2002, 14 (18): 1294--1298.
[14] Lagrini A, Deslouis C, Cachet H, et al. Electrochem. Commun., 2004, 6 (3): 245--248.
[15] Fuge G M, May P W, Rosser K N, et al. Diamond and Related Materials, 2004, 13 (4-8): 1442--1448.
[16] Golzan M M, McKenzie D R, Miller D J, et al. J. Diam. Relat. Mater., 1995, 4: 912--916.
[17] Merel P, Tabbal M, Chaker M, et al. Applied Surface Science, 1998, 136 (1-2): 105--110.
[18] Zhao J F, Lemoine P, Liu Z H, et al. J. Phys. Condens. Matter., 2000, 12 (44): 9201--9213.
[19] Messina G, Paoletti A, Santangelo S, et al. J. Appl. Phys., 2001, 89 (2): 1053--1058.
[20] Tabbal M, Christidis T, Isber S, et al. J. Appl. Phys., 2005, 98 (4): 044310. [21] Ferrari A C, Robertson J. Physical Review B, 2000, 61 (20): 14095--14107.
[22] Claeyssens F, Fuge G M, Allan N L, et al. Dalton. Trans., 2004, 4 (19): 3085--3092.
[23] Veerasamy V S, Amaratunga G A J, Davis C A, et al. J. Phys.: Condens. Matter., 1993, 5: Ll69--L174.
[24] Rusop M, Soga T, Jimbo T. Sol. Energ. Mat. Sol. C, 2006, 90: 291--300.
[25] Zeng A, Liu E, Tan S N, et al. Eletroanalysis, 2002, 14 (15-16): 1110--1115.
[26] Salazar-Banda G R, Andrade L S, Nascente P A P, et al. Electrochimica Acta, 2006, 51: 4612--4619.

掺磷四面体非晶碳薄膜电极的电化学伏安特性

Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	施桐, 甘乔炜, 刘东, 张莹, 冯浩, 李强. 自支撑Bi@Cu纳米树电极高效电化学还原CO₂制甲酸[J]. 无机材料学报, 2024, 39(7): 810-818.
[2]	程节, 周月, 罗薪涛, 高美婷, 骆思妃, 蔡丹敏, 吴雪垠, 朱立才, 袁中直. 蛋黄壳结构FeF₃·0.33H₂O@N掺杂碳纳米笼正极材料的构筑及其电化学性能[J]. 无机材料学报, 2024, 39(3): 299-305.
[3]	陈正鹏, 金芳军, 李明飞, 董江波, 许仁辞, 徐韩昭, 熊凯, 饶睦敏, 陈创庭, 李晓伟, 凌意瀚. 双钙钛矿Sr₂CoFeO₅₊_δ阴极材料的制备及其中温固体氧化物燃料电池性能研究[J]. 无机材料学报, 2024, 39(3): 337-344.
[4]	方万丽, 沈黎丽, 李海艳, 陈薪羽, 陈宗琦, 寿春晖, 赵斌, 杨松旺. NiO_x介孔层的成膜过程对碳电极钙钛矿太阳能电池性能的影响[J]. 无机材料学报, 2023, 38(9): 1103-1109.
[5]	杜剑宇, 葛琛. 光电人工突触研究进展[J]. 无机材料学报, 2023, 38(4): 378-386.
[6]	王烨, 焦忆楠, 郭军霞, 刘欢, 李睿, 尚子璇, 张士东, 王永浩, 耿海川, 侯登录, 赵晋津. 钙钛矿太阳能电池界面工程优化研究[J]. 无机材料学报, 2023, 38(11): 1323-1330.
[7]	李成金, 薛怡, 周晓霞, 陈航榕. BiZn_x/Si光电阴极的制备及其CO₂还原性能研究[J]. 无机材料学报, 2022, 37(10): 1093-1101.
[8]	王玥, 崔常松, 王士维, 占忠亮. La_xSr_2-_xFe_1.5Ni_0.1Mo_0.4O_6-_δ对称电池电解CO₂研究[J]. 无机材料学报, 2021, 36(12): 1323-1329.
[9]	李泽晖,谭美娟,郑元昊,骆雨阳,经求是,蒋靖坤,李明杰. 导电金属有机骨架材料在超级电容器中的应用[J]. 无机材料学报, 2020, 35(7): 769-780.
[10]	王金敏, 于红玉, 马董云. 纳米二氧化锰的制备及其应用研究进展[J]. 无机材料学报, 2020, 35(12): 1307-1314.
[11]	邓敏,江奇,段志虹,刘青青,蒋理,卢晓英. 米粒状氧化铜化学修饰电极的制备及其对葡萄糖的检测[J]. 无机材料学报, 2019, 34(2): 152-158.
[12]	夏天, 孟燮, 骆婷, 占忠亮. Ca掺杂Sr₂Fe_1.5Mo_0.5O_6-_δ材料的合成与作为对称固体氧化物燃料电池电极催化剂的性能研究[J]. 无机材料学报, 2019, 34(10): 1109-1114.
[13]	王晓, 王冉冉, 施良晶, 孙静. 铜纳米线的合成、优化及其透明电极的应用[J]. 无机材料学报, 2019, 34(1): 49-59.
[14]	要美娜, 杨贤金, 崔振铎, 朱胜利, 李朝阳, 梁砚琴. 铋膜电极阳极溶出伏安法检测痕量Cd金属[J]. 无机材料学报, 2019, 34(1): 91-95.
[15]	蒋青松, 陈若婷, 李文波, 程文杰, 黄业晓, 胡光. 透明硫化钴对电极在染料敏化太阳能电池中的应用[J]. 无机材料学报, 2018, 33(8): 832-838.