掺磷四面体非晶碳薄膜电极的电化学伏安特性

doi:10.3724/SP.J.1077.2007.01056

无机材料学报

掺磷四面体非晶碳薄膜电极的电化学伏安特性

刘爱萍, 朱嘉琦, 韩杰才, 韩潇, 吴化平

哈尔滨工业大学复合材料与结构研究所, 哈尔滨 150001

收稿日期:2006-12-17 修回日期:2007-01-31 出版日期:2007-11-20 网络出版日期:2007-11-20

Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode

LIU Ai-Ping, ZHU Jia-Qi, HAN Jie-Cai, HAN Xiao, WU Hua-Ping

Center for Composite Materials, Harbin Institute of Technology, Harbin 150001, China

Received:2006-12-17 Revised:2007-01-31 Published:2007-11-20 Online:2007-11-20

摘要/Abstract

摘要： 采用过滤阴极真空电弧技术, 以高纯磷烷气体为掺杂源制备掺磷四面体非晶碳(ta-C:P)薄膜. 利用X射线光电子能谱和激光拉曼光谱表征薄膜的成分和结构, 采用循环伏安和微分脉冲伏安分析薄膜的电化学行为. 结果表明, 磷的掺入没有引起薄膜非晶结构的明显变化, 只是促进了sp²杂化碳原子的团簇. 经过酸预处理的ta-C:P薄膜在硫酸溶液中有宽的电势窗口和低的背景电流; 对Cl^-有催化活性; 薄膜表面电子传输速度快; 对水溶液中Cu²⁺和Cd²⁺有检测活性. 因此具有良好导电性的ta-C:P薄膜适于作为电极并有望用于污水中重金属离子的分析检测等领域.

关键词: 过滤阴极真空电弧, 掺磷四面体非晶碳, 电极, 伏安行为

Abstract: Phosphorus incorporated tetrahedral amorphous carbon (ta-C:P) film was deposited by a filtered cathodic vacuum arc technology with PH3 as the dopant source. The composition and structural characteristics were investigated by X-ray photoelectron spectroscope and Raman spectroscope, and the electrochemical behaviors of ta-C:P film were examined by cyclic voltammetry and differential pulse voltammetry. Results indicate that phosphorus implantation does not remarkably change the amorphous structure of the film but enhances the clustering of sp² sites dispersed in sp3 skeleton and the evolution of structrual ordering. Ta-C:P film pretreated by acid exhibits a large electrochemical potential window and a low background current in H₂SO₄ solution, a considerable electrochemical activity toward Cl^-, quick electrode response and a high signal for Cu²⁺ and Cd²⁺ analysis. These characteristics greatly demonstrate a potential application of conductive ta-C:P film as electrodes for analysis and treatment of trace metal ions in waste water.

Key words: filtered cathodic vacuum arc, phosphorus incorporated tetrahedral amorphous carbon

中图分类号:

刘爱萍,朱嘉琦,韩杰才,韩潇,吴化平. 掺磷四面体非晶碳薄膜电极的电化学伏安特性[J]. 无机材料学报, DOI: 10.3724/SP.J.1077.2007.01056.

LIU Ai-Ping,ZHU Jia-Qi,HAN Jie-Cai,HAN Xiao,WU Hua-Ping. Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2007.01056.

参考文献

[1] Hupert M, Muck A, Wang R, et al. Diamond and Related Materials, 2003, 12 (10-11): 1940--1949.
[2] Compton R G, Foord J S, Marken F. Electroanalysis, 2003, 15 (17): 1349--1363.
[3] Panizza M, Cerisola G. Electrochimica Acta, 2005, 51 (2): 191--199.
[4] Weng J, Xue J M, Wang J, et al. Adv. Funct. Mater., 2005, 15 (4): 639--647.
[5] Robertson J. Mater. Sci. Eng. R, 2002, 37: 129--281.
[6] 陈弟虎, 等(CHEN Di-Hu, { et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (1): 179--182.
[7] 蒋娜哪, 等(JIANG Na-Na, { et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20 (1): 187--192.
[8] Yoo K S, Miller B, Kalish R, et al. Electrochem. Solid-State Lett., 1999, 2 (5): 233--235.
[9] Cheah L K, Shi X, Tay B K, et al. Diam. Relat. Mater., 1998, 7 (2-5): 640--644.
[10] Ma Z Q, Liu B X. Sol. Energ. Mat. Sol. C, 2001, 69 (4): 339--344.
[11] Rusop M, Soga T, Jimbo T. Diam. Relat. Mater., 2004, 13 (11-12): 2197--2202.
[12] Pleskov Y V, Evstefeeva Y E, Krotova M D, et al. Diam. Relat. Mater., 1999, 8 (1): 64--72.
[13] Zeng A, Liu E, Tan S N, et al. Eletroanalysis, 2002, 14 (18): 1294--1298.
[14] Lagrini A, Deslouis C, Cachet H, et al. Electrochem. Commun., 2004, 6 (3): 245--248.
[15] Fuge G M, May P W, Rosser K N, et al. Diamond and Related Materials, 2004, 13 (4-8): 1442--1448.
[16] Golzan M M, McKenzie D R, Miller D J, et al. J. Diam. Relat. Mater., 1995, 4: 912--916.
[17] Merel P, Tabbal M, Chaker M, et al. Applied Surface Science, 1998, 136 (1-2): 105--110.
[18] Zhao J F, Lemoine P, Liu Z H, et al. J. Phys. Condens. Matter., 2000, 12 (44): 9201--9213.
[19] Messina G, Paoletti A, Santangelo S, et al. J. Appl. Phys., 2001, 89 (2): 1053--1058.
[20] Tabbal M, Christidis T, Isber S, et al. J. Appl. Phys., 2005, 98 (4): 044310. [21] Ferrari A C, Robertson J. Physical Review B, 2000, 61 (20): 14095--14107.
[22] Claeyssens F, Fuge G M, Allan N L, et al. Dalton. Trans., 2004, 4 (19): 3085--3092.
[23] Veerasamy V S, Amaratunga G A J, Davis C A, et al. J. Phys.: Condens. Matter., 1993, 5: Ll69--L174.
[24] Rusop M, Soga T, Jimbo T. Sol. Energ. Mat. Sol. C, 2006, 90: 291--300.
[25] Zeng A, Liu E, Tan S N, et al. Eletroanalysis, 2002, 14 (15-16): 1110--1115.
[26] Salazar-Banda G R, Andrade L S, Nascente P A P, et al. Electrochimica Acta, 2006, 51: 4612--4619.

掺磷四面体非晶碳薄膜电极的电化学伏安特性

Electrochemical Properties of Phosphorus Incorporated Tetrahedral Amorphous Carbon Film Electrode

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