Bi4Si3O12基玻璃陶瓷的制备及热处理对其光学性能的影响

doi:10.3724/SP.J.1077.2014.13249

无机材料学报 ›› 2014, Vol. 29 ›› Issue (2): 167-171.DOI: 10.3724/SP.J.1077.2014.13249 CSTR: 32189.14.SP.J.1077.2014.13249

Bi₄Si₃O₁₂基玻璃陶瓷的制备及热处理对其光学性能的影响

王晨阳^1,2, 胡关钦¹, 王红¹, 赵景泰¹

(1. 中国科学院上海硅酸盐研究所, 中国科学院透明光功能无机材料重点实验室, 上海200050; 2. 中国科学院大学, 北京100039)

收稿日期:2013-05-06 修回日期:2013-07-28 出版日期:2014-02-20 网络出版日期:2014-01-17
作者简介:王晨阳(1989–), 女, 博士研究生. E-mail:wangcy@student.sic.ac.cn
基金资助:
国家自然科学基金(50990304)

Preparation of Bi₄Si₃O₁₂-based Glass-ceramics and Effect of Heat Treatments on Optical Properties

WANG Chen-Yang^1,2, HU Guan-Qin², WANG Hong², ZHAO Jing-Tai²

(1. Key Laboratory of Transparent Opto-Functional Inorganic Materials of Chinese Academy of Sciences, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100039, China)

Received:2013-05-06 Revised:2013-07-28 Published:2014-02-20 Online:2014-01-17
About author:WANG Chen-Yang. E-mail:wangcy@student.sic.ac.cn
Supported by:
National Natural Science Foundation of China (50990304)

摘要/Abstract

摘要： 采用阶梯热处理的方式对Bi₂O₃-SiO₂基玻璃进行析晶处理, 得到了具有不同结晶率和透明度的Bi₄Si₃O₁₂(BSO)基玻璃陶瓷。实验表明, 分段热处理有利于控制BSO基玻璃陶瓷中晶粒的数量和尺寸, 从而影响玻璃陶瓷的透明度和发光性质。分段热处理后样品的透射谱显示, BSO基玻璃陶瓷(在600℃保温1 h, 然后升温至800℃保温1 h)的透过率可达73.1%(λ > 500 nm)。制备出的BSO基玻璃陶瓷具有和BSO单晶相似的发光性质, 在可见光波段(380~680 nm)有发光, 且发光强度与结晶率成正比。低温(14 K)下, 该BSO基玻璃陶瓷的发光强度较室温下提高了约12倍。

关键词: Bi₄Si₃O₁₂, 玻璃陶瓷, 热处理, 发光性质

Abstract: Bi₄Si₃O₁₂-based glass-ceramics with different crystalline volume fractions and transparency were prepared by the two-step heat-treatment of Bi₂O₃-SiO₂ based glass. The experimental results show that the two-step heat-treatment is favorable to control the amount and size of crystallized grains in BSO-based glass-ceramics, which correspondingly affects the transparency and optical properties of the obtained glass-ceramics. The transmission spectra of these samples indicate that the transparency of BSO-based glass-ceramic (annealed at 600℃ for 1 h, then heated to 800℃ and held for 1 h) can reach 73.1% (> 500 nm). The BSO-based glass-ceramics maintain similar optical property as that of BSO single crystal, that is, the emission of such glass-ceramics is located in visible light wavelength of 380–680 nm, and their optical intensities are almost proportional to the crystalline volume fraction. The optical intensity of BSO-based glass-ceramic at low temperature (14 K) is increased by 12 times as against that at room temperature.

Key words: Bi₄Si₃O₁₂, glass-ceramic, heat treatment, optical properties

中图分类号:

TB34

王晨阳, 胡关钦, 王红, 赵景泰. Bi₄Si₃O₁₂基玻璃陶瓷的制备及热处理对其光学性能的影响[J]. 无机材料学报, 2014, 29(2): 167-171.

WANG Chen-Yang, HU Guan-Qin, WANG Hong, ZHAO Jing-Tai. Preparation of Bi₄Si₃O₁₂-based Glass-ceramics and Effect of Heat Treatments on Optical Properties[J]. Journal of Inorganic Materials, 2014, 29(2): 167-171.

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Bi₄Si₃O₁₂基玻璃陶瓷的制备及热处理对其光学性能的影响

Preparation of Bi₄Si₃O₁₂-based Glass-ceramics and Effect of Heat Treatments on Optical Properties

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