提锂用锰氧化物离子筛的研究进展

doi:10.3724/SP.J.1077.2012.12020

无机材料学报 ›› 2012, Vol. 27 ›› Issue (10): 1009-1016.DOI: 10.3724/SP.J.1077.2012.12020 CSTR: 32189.14.SP.J.1077.2012.12020

• 综述 • 下一篇

提锂用锰氧化物离子筛的研究进展

李丽^1,2, 刘芳¹, 吴锋^1,2, 陈人杰^1,2

(1. 北京理工大学化工与环境学院, 环境科学与工程北京市重点实验室, 北京100081; 2. 国家高技术绿色材料发展中心, 北京 100081)

收稿日期:2012-01-07 修回日期:2012-02-29 出版日期:2012-10-20 网络出版日期:2012-09-17
作者简介:李丽(1977–), 女, 博士. E-mail: lily863@bit.edu.cn
基金资助:
国家重点973计划项目(2009CB220106); 北京理工大学优秀青年教师资助计划(2011CX04052); 北京理工大学基础研究基金(20101042009)

Progress of Research on the Manganese Oxide Ion-sieve for Extracting Lithium

LI Li^1,2, LIU Fang¹, WU Feng^1,2, CHEN Ren-Jie^1,2

(1. School of Chemical Engineering and Environment, Beijing Municipal Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China; 2. National Development Center of Hi-tech Green Materials, Beijing 100081, China)

Received:2012-01-07 Revised:2012-02-29 Published:2012-10-20 Online:2012-09-17
About author:LI Li. lily863@bit.edu.cn
Supported by:
973 Program (2009CB220106); Excellent Young Teacher Funding of Beijing Institute of Technology (2011CX04052); Basic Research Funding of Beijing Institute of Technology (20101042009)

摘要/Abstract

摘要： 金属锂逐渐在人们生活的各个领域扮演越来越重要的作用并占有战略地位, 从液态锂源如海水、盐湖卤水中提取锂资源具有十分重要的意义, 研究者对液态提锂的方法和工艺也进行了积极的探索研究. 尖晶石锰氧化物由于其特殊的结构而对Li离子具有高度选择性, 被称为“离子筛”吸附剂. 离子筛吸附法以其绿色而高效的优势, 引起了众多学者的关注, 成为最有发展潜力的液态提锂方法之一. 本文以尖晶石锰氧化物为代表, 综述了锂离子筛的研究进展, 对其结构、锂嵌入/脱出机理、制备方法、掺杂改性、成型及应用进行了详细的阐述, 提出了锂离子筛目前存在的问题与技术瓶颈, 并对今后的研究方向进行了展望.

关键词: 提锂, 锰氧化物, 离子筛, 吸附剂, 海水, 盐湖卤水, 综述

Abstract: Metallic lithium plays an important role in the national economy and national defense construction. With the growing demand and exhausted lithium mineral resources, it is of great significance to extract lithium from abundant liquid lithium resources such as seawater and brines. Active exploration of lithium extraction methods and technologies have been carried out. Spinel-type manganese oxide has attracted much attention because of its remarkably high selectivity for lithium ions in the aqueous phase, and it is called ion-sieve adsorbent. Being environmentally friendly and efficient, the ion-sieve adsorption method is regarded as the most promising one for extracting lithium from seawater and brines. In this revieal, the structure of LiMn2O4 is presented, and the development of lithium-ion insertion/extraction mechanisms is introduced as well. The synthesis method and modification of the ion-sieve precursor are also summarized in details. Moreover, the granule/membrane formation and application of lithium ion-sieves are discussed. Finally, the existing problems and the prospects of the lithium ion-sieve are put forward.

Key words: lithium extraction, manganese oxide, ion-sieve, adsorbent, seawater, brine, review

中图分类号:

O647

李丽, 刘芳, 吴锋, 陈人杰. 提锂用锰氧化物离子筛的研究进展[J]. 无机材料学报, 2012, 27(10): 1009-1016.

LI Li, LIU Fang, WU Feng, CHEN Ren-Jie. Progress of Research on the Manganese Oxide Ion-sieve for Extracting Lithium[J]. Journal of Inorganic Materials, 2012, 27(10): 1009-1016.

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提锂用锰氧化物离子筛的研究进展

Progress of Research on the Manganese Oxide Ion-sieve for Extracting Lithium

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