NBT-BNT陶瓷的光致形变性能

doi:10.15541/jim20200254

无机材料学报 ›› 2021, Vol. 36 ›› Issue (3): 277-282.DOI: 10.15541/jim20200254 CSTR: 32189.14.10.15541/jim20200254

所属专题：【虚拟专辑】钙钛矿材料(2020~2021)

NBT-BNT陶瓷的光致形变性能

董正明¹^,²(), 李修²^,³, 陈晨²(), 曹明贺¹(), 易志国²

1. 武汉理工大学材料科学与工程学院, 武汉 430070
2. 中国科学院上海硅酸盐研究所, 高性能陶瓷和超微结构国家重点实验室, 上海 200050
3. 华中师范大学物理科学与技术学院, 武汉 430079

收稿日期:2020-05-13 修回日期:2020-09-04 出版日期:2021-03-20 网络出版日期:2020-10-10
通讯作者: 曹明贺, 教授. E-mail: caominghe@whut.edu.cn
陈晨, 助理研究员. E-mail: chen.chen@mail.sic.ac.cn
作者简介:董正明(1996-), 男, 硕士研究生. E-mail: dongzhengming_yzu@163.com
基金资助:
国家自然科学基金(51872311);国家自然科学基金(51902331);中国科学院前沿科学重点研究计划项目(QYZDB-SSW-JSC027);上海市自然科学基金(19ZR1464900)

Photostriction of NBT-BNT Ceramics

DONG Zhengming¹^,²(), LI Xiu²^,³, CHEN Chen²(), CAO Minghe¹(), YI Zhiguo²

1. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
3. College of Physical Science and Technology, Central China Normal University, Wuhan 430079, China

Received:2020-05-13 Revised:2020-09-04 Published:2021-03-20 Online:2020-10-10
Contact: CAO Minghe, professor. E-mail: caominghe@whut.edu.cn
CHEN Chen, assistant professor. E-mail: chen.chen@mail.sic.ac.cn
About author:DONG Zhengming(1996-), male, Master candidate. E-mail: dongzhengming_yzu@163.com
Supported by:
National Natural Science Foundation of China(51872311);National Natural Science Foundation of China(51902331);Frontier Science Key Project of the Chinese Academy of Sciences(QYZDB-SSW-JSC027);Natural Science Foundation of Shanghai(19ZR1464900)

摘要/Abstract

摘要：

光致形变材料在光致驱动器和传感器等光机电领域有重要的应用前景。本研究采用放电等离子体烧结法制备了Ni掺杂Na_0.5Bi_0.5TiO₃-BaTiO₃(NBT-BT)陶瓷材料Na_0.5Bi_0.5TiO₃-Ba(Ti_0.5Ni_0.5)O₃(NBT-BNT)。进一步研究发现样品在405、520及655 nm波长激光照射下均表现出10 ^-3数量级的光致形变响应, 其光致形变系数达到10 ^-11 m ³/W。通过研究NBT-BNT陶瓷在外加光源照射下的原位X射线衍射图谱, 发现所有衍射峰在可见光照射下均发生小角度的偏移, 说明光照引起的材料晶格畸变是NBT-BNT材料光致形变效应的主要原因。

关键词: 铁电材料, 光致形变, 可见光响应, 钙钛矿

Abstract:

Photostrictive materials exhibit great potential in the light-driven microactuators/sensors, light-controlled microrobots, and other optomechanical applications. In this study, we present the photostrictive performance of Ni-modified Na_0.5Bi_0.5TiO₃-BaTiO₃ (NBT-BT) ceramics prepared by using spark plasma sintering. Under visible light illumination (405, 520 and 655 nm, respectively), the Na_0.5Bi_0.5TiO₃-Ba(Ti_0.5Ni_0.5)O₃ (NBT-BNT) ceramics exhibits large photostriction of the order of 10 ^-3 and photostriction coefficient around 10 ^-11 m ³/W. The XRD peaks of the sample under external illumination show low angle shift, indicating the light-induced lattice distortion, which contributes to the large photostrictive response of NBT-BNT ceramics.

Key words: ferroelectric material, photostriction, visible light response, perovskite

中图分类号:

TQ174

董正明, 李修, 陈晨, 曹明贺, 易志国. NBT-BNT陶瓷的光致形变性能[J]. 无机材料学报, 2021, 36(3): 277-282.

DONG Zhengming, LI Xiu, CHEN Chen, CAO Minghe, YI Zhiguo. Photostriction of NBT-BNT Ceramics[J]. Journal of Inorganic Materials, 2021, 36(3): 277-282.

图/表 9

图1 NBT-BNT与NBT-BT样品的XRD图谱(a~b)和NBT- BNT(c)和NBT-BT(d)陶瓷断面的SEM照片

Fig. 1 XRD patterns (a-b) of NBT-BNT and NBT-BT samples, cross sectional SEM images of NBT-BNT (c) and NBT-BT (d) ceramic

图2 NBT-BNT与NBT-BT样品的吸收光谱(a)及带隙大小(b)

Fig. 2 Absorption spectra (a) and bandgaps (b) of NBT-BNT and NBT-BT samples

图3 NBT-BNT样品在不同光照条件下的光致形变性能(阴影部代表光照区间)(a), NBT-BNT样品分别在5 kW/cm2(b)和15 kW/cm2 (c)光强下的光致形变稳定性, NBT-BNT样品在不同光照条件下的光致形变系数(d), NBT-BNT样品在不同光照条件下(与(a)图相对应)的温度变化(e)和NBT-BNT样品的热膨胀曲线(f)

Fig. 3 Photostrictive performance of the NBT-BNT sample under different light conditions (shaded part indicates laser on state) (a), Stability of the photostrictive properties of the NBT-BNT sample under 5 kW/cm2 (b) and 15 kW/cm2 (c), photostriction coefficient of NBT-BNT sample under different light conditions (d), temperature change of the NBT-BNT sample (e) corresponding to Fig.(a), and thermal expansion curve of the NBT-BNT sample (f)

表1 部分光致形变形材料的性能对比

Table 1 Comparison of the photostrictive performances of the materials in literature and this work

Compounds	Sample thickness	Illumination wavelength/nm	Light irradiance	λ_max/%	η/(m³·W^-1)
PLZT ceramics^[26]	0.5 mm	365	150 W/m²	0.01	3.3×10^-10
BiFeO₃ crystal^[9]	90 µm	365	326 W/m²	0.003	8.2×10^-12
BiFeO₃ film^[8]	35 nm	400	2 mJ/cm²	0.46	4×10^-25
Silicon crystal^[11]	0.5 mm	248	127 mJ/cm²	-6.4×10^-4	-3.7×10^-20
Nematic elastomers^[30]	-	365	-	20	-
SrRuO₃ film^[6]	40 nm	532	62.5 W/cm²	1.12	7×10^-16
CH₃NH₃PbBr₃crystal^[5]	2.7 mm	532	60 W/cm²	-1.25	-5.6×10^-11
NBT-BNT	0.2 mm	405	25 kW/m²	0.21	1.68×10^-11
	0.2 mm	520	25 kW/m²	0.13	1.10×10^-11
	0.2 mm	655	25 kW/m²	0.11	9.12×10^-12

图4 NBT-BNT样品极化前(a)后(b)的I-V曲线

Fig. 4 I-V curves of the NBT-BNT sample before (a) and after (b) electric polarization

图5 NBT-BNT陶瓷样品在不同波长外加光源照射下的XRD图谱(a)和部分衍射峰局部放大图(b)

Fig. 5 XRD patterns of NBT-BNT sample under different external laser irradiations (a) and enlarged images of partial diffraction peaks (b)

表2 激光照射下NBT-BNT的样品XRD衍射面位移 Δd/d

Table 2 The displacement Δd/d of crystal planes of NBT- BNT samples under laser irradiation

Wavelength /nm	Δd/d
Wavelength /nm	(100)	(110)	(111)	(200)	(211)	(220)
405	0.0008	0.0003	0.0001	0.0003	0.0001	0.0005
520	0.0015	0.0005	0.0002	0.0002	0.0001	0.0003
655	0.0016	0.0004	0.0003	0.0002	0.0002	0.0003

图6 NBT-BNT样品的变温XRD图谱(a)及局部放大图(b)

Fig. 6 XRD patterns (a) and enlarged patterns of partial peaks (b) of NBT-BNT sample at different temperatures

表3 不同温度下NBT-BNT样品晶面位移Δd/d

Table 3 The displacement Δd/d of crystal planes of NBT- BNT samples at different temperatures

Temperature /℃	Δd/d
Temperature /℃	(100)	(110)	(111)	(200)	(211)	(220)
50	0.0004	0.0001	0.0003	0.0001	0.0005	0.0009
100	0.0008	0.0004	0.0004	0.0004	0.001	0.0008
150	0.0009	0.0006	0.0006	0.0005	0.0012	0.0011

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NBT-BNT陶瓷的光致形变性能

Photostriction of NBT-BNT Ceramics

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