亚稳态球霰石相碳酸钙的调控制备进展

doi:10.15541/jim20160484

无机材料学报 ›› 2017, Vol. 32 ›› Issue (7): 681-690.DOI: 10.15541/jim20160484 CSTR: 32189.14.10.15541/jim20160484

亚稳态球霰石相碳酸钙的调控制备进展

蒋久信^1,2, 吴月¹, 何瑶¹, 高松¹, 张晨¹, 沈彤³, 刘嘉宁^3,4

(1. 绿色轻质材料与加工湖北工业大学协同创新中心武汉 430068; 2. 湖北工业大学材料与化学工程学院武汉430068; 3. 南京信息工程大学物理与光电工程学院, 南京210044; 4. TU. Braunschweig, Institut für Pharmazeutische Technologie, Mendelssohnstr. 1, D-38106, Braunschweig, Germany)

收稿日期:2016-08-29 修回日期:2016-10-29 出版日期:2017-07-20 网络出版日期:2017-06-23
作者简介:蒋久信(1974—), 男, 博士, 副教授. E-mail: jiuxinjiang@hotmail.com
基金资助:
国家自然科学基金(11174075);湖北省教育厅科学技术研究计划重点项目(D20151405);绿色轻质材料与加工湖北工业大学协同创新中心开放基金(201611A02);校人才启动基金(S8113127001)

Progress in Tuning of Metastable Vaterite Calcium Carbonate

JIANG Jiu-Xin^1,2, WU Yue¹, HE Yao¹, GAO Song¹, ZHANG Chen¹, SHEN Tong³, LIU Jia-Ning^3,4

(1. Collaborative Innovation Center of Green Light-Weight Materials and Processing, Hubei University of Technology, Wuhan 430068, China; 2. School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China; 3. School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing 210044; 4. Institut fur Pharmazeutische Technologie, Technische Universit?t Braunschweig, Mendelssohnstr. 1, D-38106 Braunschweig, Germany)

Received:2016-08-29 Revised:2016-10-29 Published:2017-07-20 Online:2017-06-23
About author:JIANG Jiu-Xin. E-mail: jiuxinjiang@hotmail.com
Supported by:
National Natural Science Foundation of China (11174075);Science and Technology Research Program of Educational Commission, Hubei Province of China (D20151405);Open Foundation of Collaborative Innovation Center of Green Light-weight Materials and Processing, Hubei Provincial Key Laboratory of Green Materials for Light Industry (201611A02);Initial Funding of Nanjing University of Information Science & Technology (S8113127001)

摘要/Abstract

摘要：

球霰石以其独特的机械、物理和化学性能, 在日用品与生物医学等领域表现出广阔的应用前景。然而在三种无水碳酸钙晶体中, 球霰石的热力学性能最不稳定, 在后续的反应和处理过程中常常转变为更稳定的文石或方解石, 因此如何抑制球霰石向稳定晶型转变一直都是碳酸钙领域研究的热点。本文在概述了球霰石晶体结构、性质、应用及其转化途径的基础上, 以碳酸钙的三种基本制备体系为线索, 综述了碳化法、复分解法、微乳液法和溶剂热法等传统方法以及自组装单分子膜法、仿生合成法和热分解法等一些新型调控制备球霰石相方法的研究进展, 还就利用添加剂促进球霰石形成与稳定的相关机制加以剖析。文章旨在为球霰石相碳酸钙的有效制备提供理论和实践的参考。

关键词: 球霰石, 碳酸钙, 亚稳相, 调控, 综述

Abstract:

Vaterite has broad application prospects in the field of daily necessities and biomedical science because of its unique mechanical, physical and chemical properties. However, vaterite is the thermodynamically least stable phase in the three anhydrous crystalline phases of calcium carbonate, and such thermal metastability often transforms it into more stable aragonite or calcite phases, so how to inhibit the phase transformation of vaterite is always a hot topic in the study of calcium carbonate. In this paper, structure, properties, application, and phase transformation from vaterite to aragonite and/or calcite are briefly introduced. Particularly, based on the three basic routes of synthesis of calcium carbonate, some traditional methods, such as carbonization, double decomposition, microemulsion, solvothermal method, and some latest progress, e.g. self-assembly of monolayer, biomimetic synthesis and thermal decomposition methods of tuning and preparation on vaterite are then summarized. Moreover, some analysis on the mechanism of formation and stabilization of vaterite by some additives are given. The aim of this review is to provide a more systematic theoretical and practical guidance to fabrication vaterite phase of calcium carbonate.

Key words: vaterite, calcium carbonate, metastable, tuning, review

中图分类号:

TQ174

蒋久信, 吴月, 何瑶, 高松, 张晨, 沈彤, 刘嘉宁. 亚稳态球霰石相碳酸钙的调控制备进展[J]. 无机材料学报, 2017, 32(7): 681-690.

JIANG Jiu-Xin, WU Yue, HE Yao, GAO Song, ZHANG Chen, SHEN Tong, LIU Jia-Ning. Progress in Tuning of Metastable Vaterite Calcium Carbonate[J]. Journal of Inorganic Materials, 2017, 32(7): 681-690.

图/表 11

图1 (a)球霰石中碳酸根和钙原子位置的垂直投影[10]; (b)球霰石的晶胞结构[11]

Fig. 1 (a) Vertical projection of vaterite showing orientation of carbonate group relative to calcium atoms[10]; (b) Structure of the vaterite unit cell[11]

图2 CaCO3从非晶相转变为球霰石球晶和典型方解石的形成示意图[25]

Fig. 2 Schematic depiction of the CaCO3 transformation from amorphous phase to vaterite spherulites and typical calcite[25]

图3 无水对氨基苯磺酸与L-赖氨酸不同混合比CaCO3晶体的SEM照片[29]

Fig. 3 SEM images of CaCO3 particles in different concentration ratios between p-aminobenzene sulfonic acid anhydrous and l-Lys solutions [29] (a) 0.1 g/L:0.1 g/L; (b) 0.1 g/L:0.3 g/L; (c) 0.1 g/L:0.5 g/L; (d) 0.5 g/L:0.1 g/L; (e) High magnification of selective area of (d)

图4 添加PEG10000-SDS的SEM和TEM照片[35]

Fig. 4 SEM images of CaCO3 hollow spheres obtained in the presence of PEG10000-SDS[35](a) Low magnification image, (b) high and (c) middle magnification SEM images; and (d) TEM image of CaCO3 hollow spheres obtained in the presence of PEG2000-SDS

图5 不同浓度表面活性剂下制备的CaCO3晶体的SEM照片[38]

Fig. 5 SEM images of CaCO3 prepared at different surfactant concentrations [38](a) 0.1 mol/L; (b) Magnification of (a); (c) 0.07 mol/L; (d) 0.04 mol/L

图6 蒸发水包油饱和微乳液制备海绵状球霰石的扫描电镜照片[41]

Fig. 6 SEM images showing sponge-like vaterite spheroids prepared by evaporation[41] from water-in-oil supersaturated microemulsions with compositions of (a) octane︰SDS︰CaHCO3 =71︰4︰25(wt%); (b) octane︰dodecanol︰SDS︰CaHCO3 = 70.8︰0.7︰3.5︰25(wt%); (c) schematic diagram showing the mechanism for the formation of vaterite microsponges in water-in-oil microemulsions

图7 CaCO3的SEM照片, 其中(a~c)和(d~f)分别为加入10 mL、20 mL的丝素蛋白, 且所加镁离子浓度(mmol/L)分别为(a) 10; (b) 20; (c) 50; (d) 10; (e) 20; (f) 50[42]

Fig. 7 SEM images of CaCO3 where (a-c) and (d-f) with 10 mL and 20 mL of silk fibroin, respectively, affter being added Mg2+ at the concentration of (a) 10; (b) 20; (c) 50; (d) 10; (e) 20; (f) 50 mmol/L[42]

图8 不同水溶液中制备的CaCO3的SEM照片[51]

Fig. 8 SEM images of the CaCO3 prepared in different aqueous solutions [51](a) L-valine; (b) L-arginine; (c) L-serine

图9 不同分解温度下碳酸钙的XRD图谱[58]

Fig. 9 XRD patterns of CaCO3 decomposed under different temperatures[58](a) 70 ℃; (b) 80 ℃; (c) 90 ℃

图10 不同分解温度下CaCO3的SEM照片[58]

Fig. 10 SEM images of CaCO3 decomposed under different temperatures[58](a) 70℃; (b) 80℃; (c) 90℃

图11 (a)和(b)方解石和球霰石的原子结构, (c)球霰石结构中(0001)晶面Ca2+的排列以及在搅拌影响下的移动方向, (d)移动后Ca2+的排列及移动过程[ 59]

Fig. 11 Atomic structure of (a) calcite and (b) vaterite, (c) Ca2+ ions stacking in vaterite and the motion direction in the (0001) faces under agitation, and (d) Ca2+ ions stacking in the (0001) faces after motion[59]

参考文献 66

[1]	CUI Z, CUI C, ZHU Y, et al.Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 nanoparticles via adsorption of fatty acids.Langmuir, 2011, 28(1): 314-320.
[2]	LIU S. Stabilized Vaterite.U.S. Patent Application, US20030717 310. 2003.11.19.
[3]	DEVENNEY M, FERNANDEZ M, MORGAN S.Non-cementitious Compositions Comprising Vaterite and Methods Thereof. U.S. Patent Application, US201313804558. 2013.3.14.
[4]	TAS A.Use of vaterite and calcite in forming calcium phosphate cement scaffolds.Ceram. Eng. Sci. Proc., 2009, 28(9): 135-150.
[5]	OHGUSHI H, OKUMURA M, YOSHIKAWA T, et al.Bone formation processin porous calcium carbonate and hydroxyapatite.J. Biomed. Mater. Res., 1992, 26(7): 885-895.
[6]	BUKREEVA T, MARCHENKO I, BORODINA T, et al.Calcium carbonate and titanium dioxide particles as a basis for container fabrication for brain delivery of compounds.Dokl. Phys. Chem., 2011, 440(1): 165-167.
[7]	LI Q, DING Y, LI F, et al.Solvothermal growth of vaterite in the presence of ethylene glycol, 1, 2-propanediol and glycerin. J. Cryst. Growth, 2002, 236(1): 357-362.
[8]	FLATEN E, SEIERSTEN M, ANDREASSEN J.Polymorphism and morphology of calcium carbonate precipitated in mixed solvents of ethylene glycol and water.J. Cryst. Growth, 2009, 311(13): 3533-3538.
[9]	DUPONT L, PORTEMER F.Synthesis and study of a well crystallized CaCO3 vaterite showing a new habitus.J. Mater. Chem., 1997, 7(5): 797-800.
[10]	KAMHI S.On the structure of vaterite CaCO3.Acta Crystallogr., 1963, 16(8): 770-772.
[11]	MEYER H.Struktur und fehlordnung des vaterits.Z. Kristallogr., 1969, 128(1-6): 183-212.
[12]	DEMICHELIS R, RAITERI P, GALE J, et al.A new structural model for disorder in vaterite from first-principles calculations.CrystEngComm, 2012, 14(1): 44-47.
[13]	DEMICHELIS R, RAITERI P, GALE J, et al.The multiple structures of vaterite.Cryst. Growth Des., 2013, 13(6): 2247-2251.
[14]	NAKA K, TANAKA Y, CHUJO Y.Effect of anionic starburst dendrimers on the crystallization of CaCO3 in aqueous solution: size control of spherical vaterite particles.Langmuir, 2002, 18(9): 3655-3658.
[15]	IMAI H, TOCHIMOTO N, NISHINO Y, et al.Oriented nanocrystal mosaic in monodispersed CaCO3 microspheres with functional organic molecules.Cryst. Growth Des., 2012, 12(2): 876-882.
[16]	YU S, CÖLFEN H, ANTONIETTI M. Polymer-controlled morphosynthesis and mineralization of metal carbonate superstructures.J. Phys. Chem. B, 2003, 107(30): 7396-7405.
[17]	NEHRKE G, VAN CAPPELLEN P.Framboidal vaterite aggregates and their transformation into calcite: a morphological study.J. Cryst. Growth, 2006, 287(2): 528-530.
[18]	CÖLFEN H, QI L. A systematic examination of the morphogenesis of calcium carbonate in the presence of a double-hydrophilic block copolymer.Chem.-Eur. J., 2001, 7(1): 106-116.
[19]	HU Q, ZHANG J, TENG H, et al.Growth process and crystallographic properties of ammonia-induced vaterite.Am. Mineral., 2012, 97(8/9): 1437-1445.
[20]	FRICKE M, VOLKMER D, KRILL C, et al.Vaterite polymorph switching controlled by surface charge density of an amphiphilic dendron-calix [4] arene.Cryst. Growth Des., 2006, 6(5): 1120-1123.
[21]	GEHRKE N, CÖLFEN H, PINNA N, et al. Superstructures of calcium carbonate crystals by oriented attachment.Cryst. Growth Des., 2005, 5(4): 1317-1319.
[22]	QI L, LI J, MA J.Biomimetic morphogenesis of calcium carbonate in mixed solutions of surfactants and double-hydrophilic block copolymers.Adv. Mater., 2002, 14(4): 300-303.
[23]	MUGNAIOLI E, ANDRUSENKO I, SCHÜLER T, et al. Ab initio structure determination of vaterite by automated electron diffraction.Angew. Chem. Int. Ed., 2012, 51(28): 7041-7045.
[24]	WEI H, MA N, SONG B, et al.Formation of multilayered vaterite via phase separation, crystalline transformation, and self-assembly of nanoparticles at the air/water interface.J. Phys. Chem. C, 2007, 111(15): 5628-5632.
[25]	WEI H, SHEN Q, ZHAO Y, et al.Influence of polyvinylpyrrolidone on the precipitation of calcium carbonate and on the transformation of vaterite to calcite.J. Cryst. Growth, 2003, 250(3): 516-524.
[26]	POLITI Y, ARAD T, KLEIN E, et al.Sea urchin spine calcite forms via a transient amorphous calcium carbonate phase.Science, 2004, 306(5699): 1161-1164.
[27]	章峻, 包富荣, 戴冬萍, 等. 马来酸酐 (MAH) 表面改性纳米碳酸钙粉体的制备及表面性能. 无机化学学报, 2007, 23(5): 822-826.
[28]	KONTREC J, KRALJ D, BREČEVIĆ L, et al. Influence of some polysaccharides on the production of calcium carbonate filler particles.J. Cryst. Growth, 2008, 310(21): 4554-4560.
[29]	ZHANG Q, REN L, SHENG Y, et al.Control of morphologies and polymorphs of CaCO3 via multi-additives system.Mater. Chem. Phys., 2010, 122(1): 156-163.
[30]	汪小红, 张群, 董晓庆, 等. 超声辅助的荔枝状球霰石的制备与表征. 人工晶体学报, 2013, 42(10): 2164-2169.
[31]	YANG YA-NAN, ZHU XIAO-LI, KONG XIANG-ZHENG.Controls of crystal morphology, size and structure in spontaneous preparation of calcium carbonate.Journal of Inorganic Materials, 2013, 28(12): 1313-1320.
[32]	RAMESH T, INCHARA S A, PALLAVI K.Para-amino benzoic acid-mediated synthesis of vaterite phase of calcium carbonate.J. Chem. Sci., 2015, 127(5): 843-848.
[33]	夏宏宇, 张群, 王刚, 等. 球形和橄榄形球霰石的简易制备研究. 人工晶体学报, 2015, 44(6): 1701-1706.
[34]	ZOU JIAN-PENG, YANG HONG-ZHI, XIAO-PING, et al.Controllable fabrication of calcium carbonate hollow microspheres with micro-nano hierarchical structure.Journal of Inorganic Materials, 2016, 31(7): 711-718.
[35]	JI X, LI G, HUANG X.The synthesis of hollow CaCO3 microspheres in mixed solutions of surfactant and polymer. Mater. Lett., 2008, 62(4): 751-754.
[36]	徐国峰, 王洁欣, 沈志刚, 等. 单分散纳米碳酸钙的制备和表征. 北京化工大学学报(自然科学版), 2009, 36(5): 27-30.
[37]	KANG S, HIRASAWA I, KIM W, et al.Morphological control of calcium carbonate crystallized in reverse micelle system with anionic surfactants SDS and AOT.J. Colloid. Interf. Sci. 2005, 288(2): 496-502.
[38]	JIANG J, MA Y, ZHANG T, et al.Morphology and size control of calcium carbonate crystallized in a reverse micelle system with switchable surfactants.RSC Adv., 2015, 5: 80216-80219.
[39]	陈银霞, 纪献兵, 赵改青, 等. 低温溶剂热法合成圆饼状球霰石碳酸钙. 材料导报, 2010, 24(12): 99-102.
[40]	陈先勇, 唐琴, 刘代俊. 独特形貌碳酸钙的微波水热合成与表征. 功能材料, 2012, 43(9): 1109-1112.
[41]	WALSH D, LEBEAU B, MANN S.Morphosynthesis of calcium carbonate (vaterite) microsponges.Adv. Mater., 1999, 11(4): 324-328.
[42]	AN X, CAO C.Biomineralization of CaCO3 through the cooperative interactions between multiple additives and self-assembled monolayers.J. Phys. Chem. C, 2008, 112(16): 6526-6530.
[43]	YANG B, NAN Z.Abnormal polymorph conversion of calcium carbonate from calcite to vaterite.Mater. Res. Bull., 2012, 47(3): 521-526.
[44]	YANG D, YU K, AI Y, et al.The mineralization of electrospun chitosan/poly (vinyl alcohol) nanofibrous membranes.Carbohydr. Polym., 2011, 84(3): 990-996.
[45]	RAUTARAY D, AHMAD A, SASTRY M.Biosynthesis of CaCO3 crystals of complex morphology using a fungus and an actinomycete.J. Am. Chem. Soc., 2003, 125(48): 14656-14657.
[46]	BEUVIER T, CALVIGNAC B, DELCROIX G, et al.Synthesis of hollow vaterite CaCO3 microspheres in supercritical carbon dioxide medium. J. Mater. Chem., 2011, 21(26): 9757-9761.
[47]	潘晓芳, 王海水. 乙醇/水混合溶剂体系中碳酸钙晶体晶型和取向的控制. 无机化学学报, 2014, 30(6): 1312-1316.
[48]	韩金鑫, 连宾, 唐源, 等. 恶臭假单胞菌对碳酸钙的诱导矿化作用. 南京大学学报 (自然科学版), 2013, 49(6): 681-688.
[49]	马晓明, 杨媛媛, 张晓婷, 等. 大豆胰岛素指导下具有分级结构碳酸钙的仿生合成. 河南师范大学学报(自然科学版), 2014, 42(2): 64-68.
[50]	黄玉刚, 褚日环, 何明辉, 等. 富含羧基的多肽基双亲水杂化共聚物控制碳酸钙的形成. 中山大学学报(自然科学版), 2014, 53(3): 73-79.
[51]	GUO Y, WANG F, ZHANG J, et al.Biomimetic synthesis of calcium carbonate with different morphologies under the direction of different amino acids.Res. Chem. Intermed., 2013, 39(6): 2407-2415.
[52]	任丽英, 张群, 朱万华, 等. 仿生合成碳酸钙微环. 人工晶体学报, 2015, 44(1): 250-255.
[53]	LIU L, JIANG J, YU S.Polymorph selection and structure evolution of CaCO3 mesocrystals under control of poly (sodium 4-styrenesulfonate): synergetic effect of temperature and mixed solvent.Cryst. Growth Des., 2014, 14(11): 6048-6056.
[54]	陈晓东, 辛梅华, 李明春, 等. N-琥珀酰基-O-羟丙基磺酸壳聚糖仿生合成球霰石碳酸钙. 材料研究学报, 2016, 30(1): 31-37.
[55]	朱文杰, 蔡春华, 林嘉平. 碳酸钙在聚合物胶束控制下的仿生合成. 高分子学报, 2011, 4: 335-339.
[56]	汪玉瑛. 生物成因碳酸钙矿化机制的仿生实验研究. 合肥: 中国科学技术大学博士学位论文, 2015.
[57]	张群, 张清. 不同晶型碳酸钙的仿生矿化研究. 硅酸盐通报, 2014, 33(5): 1236-1240.
[58]	JIANG J, YE J, ZHANG G, et al.Polymorph and morphology control of CaCO3 via temperature and PEG during the decomposition of Ca(HCO3)2.J. Am. Ceram. Soc., 2012, 95(12): 3735-3738.
[59]	JIANG J, ZHANG Y, XU D, et al.Can agitation determine the polymorphs of calcium carbonate during the decomposition of calcium bicarbonate?CrystEngComm, 2014, 16(24): 5221-5226.
[60]	ZENG H, YAN Z, JIAO M, et al.A novel method for preparing calcium carbonate particles: thermal decomposition from calcium hydrogen carbonate solution.Key Eng. Mater., 2016, 697: 113-118.
[61]	TRUSHINA D, BUKREEVA T, KOVALCHUK M, et al.CaCO3 vaterite microparticles for biomedical and personal care applications.Mater. Sci. Eng., C, 2014, 45: 644-658.
[62]	RODRIGUEZ-NAVARRO C, JIMENEZ-LOPEZ C, RODRIGUEZ-NAVARRO A, et al.Bacterially mediated mineralization of vaterite.Geochim. Cosmochim. Acta, 2007, 71(5): 1197-1213.
[63]	WANG X, WU C, TAO K, et al.Influence of ovalbumin on CaCO3 precipitation during in vitro biomineralization.J. Phys. Chem. B, 2010, 114(16): 5301-5308.
[64]	DONNERS J, HEYWOOD B, MEIJER E, et al.Control over calcium carbonate phase formation by dendrimer/surfactant templates.Chem.-Eur. J., 2002, 8(11): 2561-2567.
[65]	PARAKHONSKIY B, HAASE A, ANTOLINI R.Sub-micrometer vaterite containers: synthesis, substance loading, and release.Angew. Chem., Int. Edit., 2012, 51(5): 1195-1197.
[66]	SAND K, RODRIGUEZ-BLANCO J, MAKOVICKY E, et al.Crystallization of CaCO3 in water-alcohol mixtures: spherulitic growth, polymorph stabilization, and morphology change.Cryst. Growth Des., 2012, 12(2): 842-853.

亚稳态球霰石相碳酸钙的调控制备进展

Progress in Tuning of Metastable Vaterite Calcium Carbonate

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