Ball-milling Synthesis and Electrochemical Study of Lithium (Transition) Metal Nitrides

Abstract

Abstract: Lithium (transition) metal nitrides were synthesized by high-energy ball-milling technique. The obtained samples exhibit high electrochemical activity and reversibility.
The average capacity of Li_2.6Co_0.4N samples is ca. 880mAh·g^-1 within the first 10 cycles. Li_2.6Co_0.2Cu_0.2N sample has a capacity about
750mAh·g^-1 after the first several cycles. 80% of its second cycle capacity can be retained at the 45th cycle. Li_2.6Co_0.2Fe_0.2N sample
is a mixture of two or more phases including Li_2.6Co_0.4N. It has a capacity about 560 mAh·g^-1 at the 40th cycle, 82% of its second cycle
capacity. Good cycling performance suggests that these compounds could be promising anode materials for lithium ion batteries.

Key words: ball-milling, lithium metal nitride, anode material, lithium-ion batteries

CLC Number:

TM911
O646

WANG Ke,YANG Jun,XIE Jing-Ying,LIU Yu,WANG Bao-Feng. Ball-milling Synthesis and Electrochemical Study of Lithium (Transition) Metal Nitrides[J]. Journal of Inorganic Materials.

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Ball-milling Synthesis and Electrochemical Study of Lithium (Transition) Metal Nitrides

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