Hollow-structured CoSe2/C Anode Materials: Preparation and Sodium Storage Properties for Sodium-ion Batteries

doi:10.15541/jim20220224

Abstract

Abstract:

Transition metal selenides (TMSs) with the merits of their versatile material species, ample abundance and high theoretical specific capacity have been regarded as attractive anode materials for sodium-ion batteries (SIBs). However, the large volume changes during the electrochemical reactions which result in limited cycle performance hinder their commercialization. Herein, the hollow structure composed of CoSe₂ and carbon skeleton (denoted as H-CoSe₂/C), derived from the metal organic framework material ZIF-67 using tannic acid as the etching agent, was used as the anode for SIBs. Owing to the unique hollow structure which can alleviate the volume change of the material, H-CoSe₂/C exhibited excellent sodium ions storage performances in terms of cycling stability. Compared with the solid counterpart, the reversible specific capacity of the H-CoSe₂/C electrode remains 383.4 mAh·g^-1 after 350 cycles at a current density of 50 mA·g^-1 with the capacity retention of 83.6%. Even at 500 mA·g^-1, the capacity retention can still reach 72.2% after 350 cycles. This work manifests that hollow structure can provide enough space to alleviate the problem of volume changes for TMSs during the sodiation/desodiation process, thus the cycle performances can be improved.

Key words: sodium-ion battery, anode material, metal organic framework, CoSe₂, hollow structure

CLC Number:

TQ174

WANG Jing, XU Shoudong, LU Zhonghua, ZHAO Zhuangzhuang, CHEN Liang, ZHANG Ding, GUO Chunli. Hollow-structured CoSe₂/C Anode Materials: Preparation and Sodium Storage Properties for Sodium-ion Batteries[J]. Journal of Inorganic Materials, 2022, 37(12): 1344-1350.

Figures/Tables 13

Fig. 1 Schematic illustrations of preparation of H-CoSe2/C and CoSe2/C

Fig. 2 (a) SEM, (b) TEM, (c) HRTEM images and (d) EDS elemental mappings of Co, Se, and C of H-CoSe2/C

Fig. 3 XRD patterns of (a) ZIF-67, TA-Co and H-Co/C, (b) H-CoSe2/C and CoSe2/C, (c) Raman spectra of H-CoSe2/C and CoSe2/C, (d) C1s, (e) Co2p, and (f) Se3d XPS spectra of H-CoSe2/C

Fig. 4 (a) CV curves of H-CoSe2/C at scan rate of 0.1 mV·s-1, and (b) cycle performance of H-CoSe2/C and CoSe2/C (50 mA·g-1)

Fig. 5 SEM images of (a, c) H-CoSe2/C and (b, d) CoSe2/C after (a, b) 1 and (c, d) 350 cycles

Fig. 6 (a) CV curves at different scan rates, (b) corresponding lgi versus lgv plots at each redox peak (i: peak current, v: scan rate), (c) histogram of pseudo capacitive contribution at different scan rates, and (d) capacitive contribution at scan rate of 1.5 V·s-1 of H-CoSe2/C electrode Colorful figures are available on website

Fig. 7 (a) Schematic diagram of the working mechanism, (b) charge-discharge curves and (c) cycle performance at 500 mA·g-1 of Na0.44MnO2/H-CoSe2/C full cell Colorful figures are available on website

Fig. S1 SEM images of (a) ZIF-67, (b) TA-Co, (c) H-Co/C, and (d) H-CoSe2/C samples

Fig. S2 TEM images of (a) ZIF-67, (b) TA-Co, (c) H-Co/C, and (d)H-CoSe2/C samples

Fig. S3 (a) SEM and (b) TEM images of CoSe2/C

Fig. S4 (a) Charge-discharge curves of H-CoSe2/C electrode at 50 mA·g-1; (b) Rate performances of H-CoSe2/C and CoSe2/C; (c) Cycle performance of H-CoSe2/C and CoSe2/C at 500 mA·g-1

Fig. S5 EIS spectra of H-CoSe2/C and CoSe2/C after (a) 1 cycle, (b) 120 cycles, and (c) 350 cycles and (d) corresponding histogram of R2 with inset showing equivalent circuit model

Fig. S6 (a) Charge-discharge curves and (b) cycle performance of Na0.44MnO2 cathode at 500 mA·g-1

References 26

[1]	USISKIN R, LU Y X, POPOVIC J, et al. Fundamentals, status and promise of sodium-based batteries. Nature Reviews Materials, 2021, 6: 1020-1035. DOI URL
[2]	PERVEEN T, SIDDIQ M, SHAHZAD N, et al. Prospects in anode materials for sodium ion batteries-a review. Renewable and Sustainable Energy Reviews, 2020, 119: 109549. DOI URL
[3]	FANG L, BAHLAWANE N, SUN W, et al. Conversion-alloying anode materials for sodium ion batteries. Small, 2021, 17(37): 2101137. DOI URL
[4]	HU Z, LIU Q N, CHOU S L, et al. Advances and challenges in metal sulfides/selenides for next-generation rechargeable sodium- ion batteries. Advanced Materials, 2017, 29(48): 1700606. DOI URL
[5]	LUO M H, YU H X, HU F Y, et al. Metal selenides for high performance sodium ion batteries. Chemical Engineering Journal, 2020, 380: 122557. DOI URL
[6]	WU C, DOU S X, YU Y, et al. The state and challenges of anode materials based on conversion reactions for sodium storage. Small, 2018, 14(22): 1703671. DOI URL
[7]	ZHANG K, PARK M H, ZHOU L M, et al. Urchin-like CoSe₂ as a high-performance anode material for sodium-ion batteries. Advanced Functional Materials, 2016, 26(37): 6728-6735. DOI URL
[8]	MA X Q, ZOU L, ZHAO W X, et al. Tailoring hollow microflower-shaped CoSe₂anodes in sodium ion batteries with high cycling stability. Chemical Communications, 2018, 54: 10507-10510. DOI URL
[9]	FANG Y J, YU X Y, LOU X W, et al. Formation of hierarchical Cu-doped CoSe₂ microboxes via sequential ion exchange for high- performance sodium-ion batteries. Advanced Materials, 2018, 30(21): 1706668. DOI URL
[10]	WANG B, MIAO X W, DONG H L, et al. In situ construction of active interfaces towards improved high-rate performance of CoSe₂. Journal of Materials Chemistry A, 2021, 9(25): 14582-14592. DOI URL
[11]	XU X, YANG T, ZHANG Q, et al. Ultrahigh capacitive deionization performance by 3D interconnected MOF-derived nitrogen- doped carbon tubes. Chemical Engineering Journal, 2020, 390: 124493. DOI URL
[12]	FU Y, WEI Q, ZHANG G, et al. High-performance reversible aqueous Zn-ion battery based on porous MnO_x nanorods coated by MOF-derived N-doped carbon. Advanced Energy Materials, 2018, 8(26): 1801445. DOI URL
[13]	YANG J, GAO H C, MEN S, et al. CoSe₂ nanoparticles encapsulated by N-doped carbon framework intertwined with carbon nanotubes: high-performance dual-role anode materials for both Li-and Na-ion batteries. Advanced Science, 2018, 5(12): 1800763. DOI URL
[14]	XU X, LIU J, LIU J, et al. A general MOF-derived selenidation strategy for in-situ carbon-encapsulated metal selenides as high- rate anodes for Na-ion batteries. Advanced Functional Materials, 2018, 28(16): 1707573. DOI URL
[15]	HU H, ZHANG J T, GUAN B Y, et al. Unusual formation of CoSe@carbon nanoboxes, which have an inhomogeneous shell, for efficient lithium storage. Angewandte Chemie International Edition, 2016, 55(33): 9514-9518. DOI URL
[16]	TABASSUM H, ZOU R, MAHMOOD A, et al. A universal strategy for hollow metal oxide nanoparticles encapsulated into B/N co-doped graphitic nanotubes as high-performance lithium- ion battery anodes. Advanced Materials, 2018, 30(8): 1705441. DOI URL
[17]	LIU T Z, LI Y P, HOU S, et al. Building hierarchical microcubes composed of one-dimensional CoSe₂ @nitrogen-doped carbon for superior sodium ion batteries. Chemistry, 2020, 26(60): 13716-13724.
[18]	ZHANG Y F, PAN A Q, DING L, et al. Nitrogen-doped yolk-shell structured CoSe/C dodecahedra for high-performance sodium ion batteries. ACS Applied Materials & Interfaces, 2017, 9(4): 3624-3633.
[19]	HUANG Y, FANG Y J, LU X F, et al. Co₃O₄ hollow nanoparticles embedded in mesoporous walls of carbon nanoboxes for efficient lithium storage. Angewandte Chemie International Edition, 2020, 59(45): 19914-19918. DOI URL
[20]	PAN Y L, CHENG X D, GAO M Y, et al. Cagelike CoSe₂@N- doped carbon aerogels with pseudocapacitive properties as advanced materials for sodium-ion batteries with excellent rate performance and cyclic stability. ACS Applied Materials & Interfaces, 2020, 12(30): 33621-33630.
[21]	TANG Y, ZHAO Z, HAO X, et al. Engineering hollow polyhedrons structured from carbon-coated CoSe₂ nanospheres bridged by CNTs with boosted sodium storage performance. Journal of Materials Chemistry A, 2017, 5(26): 13591-13600. DOI URL
[22]	TABASSUM H, ZHI C, HUSSAIN T, et al. Encapsulating trogtalite CoSe₂ nanobuds into BCN nanotubes as high storage capacity sodium ion battery anodes. Advanced Energy Materials, 2019, 9(39): 1901778. DOI URL
[23]	XU S D, ZHUANG Q C, TIAN L L, et al. Impedance spectra of nonhomogeneous, multilayered porous composite graphite electrodes for Li-ion batteries: experimental and theoretical studies. The Journal of Physical Chemistry C, 2011, 115(18): 9210-9219. DOI URL
[24]	SUN X P, ZENG S Y, MAN R X, et al. Yolk-shell structured CoSe₂/C nanospheres as multifunctional anode materials for both full/half sodium-ion and full/half potassium-ion batteries. Nanoscale, 2021, 13(23): 10385-10392. DOI URL
[25]	AGARWAL R R. Phase changes and diffusivity in the carbon- lithium electrode. Journal of Power Sources, 1989, 25(2): 151-158. DOI URL
[26]	ZHAO Z Z, HUANG X B, SHAO Y F, et al. Surface modification of Na_0.44MnO₂ via a nonaqueous solution-assisted coating for ultra- stable and high-rate sodium-ion batteries. Chemical Engineering Journal Advances, 2022, 10: 100292. DOI URL

Hollow-structured CoSe₂/C Anode Materials: Preparation and Sodium Storage Properties for Sodium-ion Batteries

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