Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass

doi:10.3724/SP.J.1077.2012.00615

Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (6): 615-619.DOI: 10.3724/SP.J.1077.2012.00615

• Research Paper • Previous Articles Next Articles

Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass

SONG Zhi-Guo^1,2,3, LI Chen¹,YANG Zheng-Wen^1,2,3, YIN Zhao-Yi^1,2,3, ZHOU Da-Cheng^1,2,3, SHANG Ji-Hua¹, YU Xue^1,2,3, QIU Jian-Bei^1,2,3

(1. School of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Key Lab of materials of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China; 3. Key Lab of Advanced Materials in Rare & Precious and Nonferrous Metals (Kunming University of Science and Technology), Ministry of Education, Kunming 650093, China)

Received:2011-07-12 Revised:2011-09-07 Published:2012-06-20 Online:2012-05-07
About author:SONG Zhi-Guo. E-mail: songzg@kmust.edu.cn
Supported by:
973 Program (2011CB211700); Natural Science Foundation of Yunnan Province (2009CC009, 2008027E)

Abstract

Abstract: The effect of optical basicity on near infrared (NIR) luminescence properties of bismuth-doped aluminophosphate glasses was investigated. The result show that with increase in the radius of alkali metal ions in glass host, the intensity of NIR emission band at about 1300 nm from Bi ions increases, while the intensity of NIR emission band at 1100 nm decreases. The dependence of intensity of NIR emission band at 1300 nm on the optical basicity of glass host is found to be opposite to those in previous reports as well as to that of NIR emission band at 1100 nm. The infrared emissions peaked at 1100 and 1300 nm may originate from different valent Bi ion, and the relationship between optical basicity and infrared luminescence of bismuth-doped aluminophosphate glasses can be due to the reduction effect of glass matrix.

Key words: bismuth doped, infrared fluorescence, optical basicity, glass

CLC Number:

TQ174

SONG Zhi-Guo, LI Chen,YANG Zheng-Wen, YIN Zhao-Yi, ZHOU Da-Cheng, SHANG Ji-Hua, YU Xue, QIU Jian-Bei. Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass[J]. Journal of Inorganic Materials, 2012, 27(6): 615-619.

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Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass

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