Journal of Inorganic Materials

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Reaction-Sintering Mechanisms of Zirconia-Mullite Multiphase Ceramics Prepared from ZrSiO4/α-AlO3 Mixtures

ZHAO Shi-Ke; HUANG Xiao-Xian; GUO Jing-Kun   

  1. State Key Lab of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:1999-12-06 Revised:2000-01-11 Published:2000-12-20 Online:2000-12-20

Abstract: Mullite-zirconia composites were prepared by reaction-sintering of zircon and α-Al2O3 mixed powders. Densification process as well as formation
mechanism of mullite was studied and discussed, and special attention was paid to the effect of mullite seeding on the reaction-sintering mechanisms. It is
shown that the viscous flow of the non-crystalline may be a dominant densification mechanism prior to the formation of mullite. Mullite seeding has an obvious influence
on the forming way of mullite, and a higher relative density of 97% can be obtained when a small amount of mullite seeds (3wt%) are added.

Key words: reaction-sintering mechanism, mullite, zirconia, composite

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