Preparation of Zinc Oxide Nano-hollow Spheres in Mercury Medium

doi:10.3724/SP.J.1077.2008.00039

Abstract

Abstract: Zinc oxide nano-hollow spheres were prepared by oxidation of zinc in mercury medium with template of surfactant micelles. SEM, EDX, TG, DTA, XRD and IR were used to characterize the as-grown products. The effect of surfactant on the growth of zinc oxide was discussed. The results show that zinc oxide hollow spheres, amorphous, with nanometer-sized thickness are assembled by zinc oxide nanometer particles. After calcinated, they transform to wurtzite structure. With suitable concentration of PEG or CTAB adding, ZnO hollow spheres can be fabricated on the surface of Zn plate. If no surfactant, excessive concentration of PEG or SDBS is added, ZnO hollow spheres can’t be fabricated.

Key words: zinc oxide, nano-hollow sphere, mercury, medium

CLC Number:

TB383

YANG Qi,LIU Lei,SHEN Bin,DENG Yi-Da,HU Wen-Bin. Preparation of Zinc Oxide Nano-hollow Spheres in Mercury Medium[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2008.00039.

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Preparation of Zinc Oxide Nano-hollow Spheres in Mercury Medium

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