Progress in Synthetic Methods of Cathode Material LiMxMn2-xO4 for Lithium Ion Batteries

Abstract

Abstract: Spinel LiMn₂O₄ is a promising candidate for substitution of LiCoO₂ as the cathode
material for Lithium ion batteries, of which the crystal structure was described in detail. The synthetic methods for the preparation
of LiM_xMn_2-xO₄ developed in recent years were reviewed, including “solid-state reaction methods”such as high temperature
solid-state reaction, microwave sintering, and solid-state coordination reaction, etc., and “soft-chemistry synthetic methods”such as pechini
synthesis, sol-gel method and micro-emulsion method etc. The advantages & drawbacks of each method were compared and analyzed. Of all the methods
described herein, the solid-state coordination reaction method developed by the author is quite a new one for preparing LiM_xMn_2-xO₄, which has
wide application prospects. Compared to the traditional high temperature solid-state reaction method, this new one not only maintains all the former’s
merits such as simple to operate and easy to manufacture in large-scale, but also has many advantages such as low calcination temperature, short
calcination time, and good morphology & small particulate as well as easy control of stoichiometry, etc.

Key words: spinel LiM_^xMn_2-xO₄, crystal structure, solid-state synthesis, soft-chemistry synthesis, Li-ion battery

CLC Number:

TM911

KANG Kai,DAI Shou-Hui,WAN Yu-Hua. Progress in Synthetic Methods of Cathode Material LiM_xMn_2-xO₄ for Lithium Ion Batteries[J]. Journal of Inorganic Materials.

References

[1] 康慨, 戴受惠, 万玉华. 核科技报告, 2000, CNIC－01466: 1--9.
[2] 周恒辉, 慈云祥, 刘昌炎. 化学进展, 1998, 10 (1): 85--94.
[3] 尹大川, 王~~猛, 黄卫东. 功能材料, 1999, 30 (6): 591--594.
[4] Haringer D, Novak P, Haas O, et al. Proc Electrochem Soc., 1998, 16: 296--305.
[5] Kanno R. Mater. Integ., 1999, 12 (3): 13--16 (Japanese).
[6] 康慨, 戴受惠, 万玉华. 功能材料, 2000, 31 (3): 283--286.
[7] Hayashi N, Ikuta H, Wakihara M. J. Electrochem Soc., 1999, 146 (4): 1351--1354.
[8] Ammundsen B, Uchiyama T, Itoh T, et al. Langmuir, 1999, 15 (15): 4949--4951.
[9] Frison J C, Hwang S J, Song S W, et al. J. Phys. Chem. B, 1999, 103 (2): 2100--2106.
[10] Hong S J, Chang S H, Yo C H. Bull. Korean. Chem. Soc., 1999, 20 (1): 53--58.
[11] 崔万秋, 杨丽芬. 功能材料, 1998, 29 (1): 378--380, 428.
[12] 王要武, 阴晓东, 徐仲榆. 电池, 1999, 29 (2): 51--53.
[13] Hasezaki K, Kamada M. Funtai Oyobi Funmatsu Yakin, 1999, 46 (3): 317--320 (Japanese).
[14] Kachibaya E, Japaridze L, Akhvlediani R, et al. Bull. Georgian Acad. Sci., 1998, 157 (3): 428--431.
[15] Saravanan T, Stephan A M, Thirunakaran R, et al. Bull. Electrochem, 1998, 14 (8-9): 286--288.
[16] Hu X H, Ai X P, Yang H X, et al. J. Power Sources, 1998, 74 (2): 240--243.
[17] Siapkas D I, Mitsas C, Samaras I, et al. J. Power Sources, 1998, 72 (1): 22--26.
[18] 卢集政, 赖琼钰. 化学研究与应用, 1998, 10 (6): 620--623.
[19] 严宏伟, 陈立泉, 黄学杰, 等. 发明专利公开说明书, 1997, CN1143267A, 7pp.
[20] Liu W, Kowal K, Farrington G C. J. Electrochem Soc., 1998, 145 (2): 459--465.
[21] Wang G X, Bradhurst D H, Liu H K, et al. Solid State Ionics, 1999, 120 (4): 95--101.
[22] Huang H, Bruce P G. J. Power Sources, 1995, 54: 52--56.
[23] Tsumura T, Inagaki M. Solid State Ionics, 1997, 104 (1,2): 35--43.
[24] Vogler C, Dittrich H, Arnold G, et al. Ionics, 1998, 4 (3\&4): 285--298.
[25] Ikuhara Y H, Iwamoto Y, Kikuta K, et al. J. Mater. Res., 1999, 14 (7): 3102--3110.
[26] Hong Y S, Park H B, Yi J E, et al. Bull. Korean Chem. Soc., 1997, 18 (11): 1153--1158.
[27] Yang W S, Liu Q G, Qiu W H, et al. Solid State Ionics, 1999, 121 (1-4): 79--84.
[28] 刘培松, 刘兴泉, 陈召勇, 等. 应用化学, 2000, 17 (1): 60--62.
[29] Choy J H, Kim D H, Kwon C W, et al. J. Power Sources, 1999, 77 (1): 1--11.
[30] Sun Y K, Kim D W, Jin S H, et al. Korean J. Chem. Eng., 1998, 15 (1): 64--70.
[31] Sun Y K, Kim D W, Choi Y M. J. Power Sources, 1999, 79 (2): 231--237.
[32] Sun Y K, Oh I H, Choi J W. J. New Mater. Electrochem Syst, 1999, 2 (1): 51--57.
[33] Kweon H J, Kim S S, Kim G B, et al. J. Mater. Sci. Lett., 1998, 17 (20): 1697--1701.
[34] Lee Y S, Sun Y K, Nahm K S. Solid State Ionics, 1998, 109 (3,4): 285--294.
[35] Prabaharan S R, Saparil N B, Michael S S, et al. Solid State Ionics, 1998, 112 (1,2): 25--34.
[36] Noguchi Xia Y, H. et al. J. Solid State Chem., 1995, 119: 216.
[37] Takada I, Enoki H, Hayakawa H, et al. Key Eng. Mater., 1999, 157-158: 297--302.
[38] Tsang C, Manthiram A. Solid State Ionics, 1996, 89 (3,4): 305--312.
[39] Peramunage D, Abraham K M. J. Electrochem Soc., 1998, 145 (4): 1131--1136.
[40] Hwang K T, Um W S, Lee H S, et al. J. Power Sources, 1998, 74 (2): 169--174.
[41] Kim M K, Chung H T, Um W S, et al. Mater. Lett., 1999, 39 (3): 133--137.
[42] 杨书廷, 张焰峰, 吕庆章, 等(YANG Shu-Thing, et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (2): 309--314.

Progress in Synthetic Methods of Cathode Material LiM_xMn_2-xO₄ for Lithium Ion Batteries

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	HUANG Jianfeng, LIANG Ruihong, ZHOU Zhiyong. Effects of W/Cr Co-doping on the Crystal Structure and Electric Properties of CaBi₂Nb₂O₉ Piezoceramics [J]. Journal of Inorganic Materials, 2024, 39(8): 887-894.
[2]	SU Nan, QIU Jieshan, WANG Zhiyu. F-doped Carbon Coated Nano-Si Anode with High Capacity: Preparation by Gaseous Fluorination and Performance for Lithium Storage [J]. Journal of Inorganic Materials, 2023, 38(8): 947-953.
[3]	SONG Yunxia, HAN Yinglei, YAN Tao, LUO Min. New Ultraviolet Nonlinear Optical Crystal Rb₃Hg₂(SO₄)₃Cl [J]. Journal of Inorganic Materials, 2023, 38(7): 778-784.
[4]	XIAO Meixia, LI Miaomiao, SONG Erhong, SONG Haiyang, LI Zhao, BI Jiaying. Halogenated Ti₃C₂ MXene as High Capacity Electrode Material for Li-ion Batteries [J]. Journal of Inorganic Materials, 2022, 37(6): 660-668.
[5]	ZHAO Wei, XU Yang, WAN Yingjie, CAI Tianxun, MU Jinxiao, HUANG Fuqiang. Metal Cyanamides/Carbodiimides: Structure, Synthesis and Electrochemical Energy Storage Performance [J]. Journal of Inorganic Materials, 2022, 37(2): 140-151.
[6]	PENG Fan, ZENG Yi. Method of Crystal Structure Identification by Using Kikuchi Diffraction Patterns [J]. Journal of Inorganic Materials, 2021, 36(11): 1193-1198.
[7]	LI Shufang,ZHAO Shuang,ZHOU Xiao,LI Manrong. Crystal Structures, Optical, and Magnetic Properties of Zn_3-_xMn_xTeO₆ [J]. Journal of Inorganic Materials, 2020, 35(8): 895-901.
[8]	LI Shufang, ZHAO Shuang, LI Manrong. Flux Growth of Tungsten Oxychloride Li₂₃CuW₁₀O₄₀Cl₅ [J]. Journal of Inorganic Materials, 2020, 35(7): 834-838.
[9]	HUANG Chong,ZHAO Wei,WANG Dong,BU Kejun,WANG Sishun,HUANG Fuqiang. Synthesis, Crystal Structure, and Electrical Conductivity of Pd-intercalated NbSe₂ [J]. Journal of Inorganic Materials, 2020, 35(4): 505-510.
[10]	Xiang-Xiong ZENG, Jin-Chao YANG, Lian ZUO, Ben-Ben YANG, Jun QIN, Zhi-Hang PENG. Li/Ce/La Multidoping on Crystal Structure and Electric Properties of CaBi₂Nb₂O₉ Piezoceramics [J]. Journal of Inorganic Materials, 2019, 34(4): 379-386.
[11]	HUANG Long, DING Shi-Hua, ZHANG Xiao-Yun, YAN Xin-Kan, LI Chao, ZHU Hui. Structure and Microwave Dielectric Property of BaAl₂Si₂O₈with Li₂O-B₂O₃-SiO₂ Glass Addition [J]. Journal of Inorganic Materials, 2019, 34(10): 1091-1096.
[12]	ZHOU Xin, MA Lei, LIU Tao, GUO Yong-Bin, WANG Dao, DONG Pei-Lin. Crystal Structure and Magnetic Property of Si₃N₄/FePd/Si₃N₄ Thin Films [J]. Journal of Inorganic Materials, 2018, 33(8): 909-913.
[13]	WANG Jing, CHENG Zhi-Ning, GUO Yu-Zhong, HUANG Rui-An, WANG Jian-Hua. Preparation and Electrochemical Performance of Ordered Mesoporous Si/C Composite for Anode Material [J]. Journal of Inorganic Materials, 2018, 33(3): 313-319.
[14]	MENG Fan-Bin, MA Xiao-Fan, ZHANG Wei, WU Guang-Heng, ZHANG Yu-Jie. Structure and Magnetic Property of Fe and Mn Doped Spinel Co₂MnO₄ [J]. Journal of Inorganic Materials, 2017, 32(6): 609-614.
[15]	WANG Qing-Qing, SHI Jian, LI Huan-Ying, CHEN Xiao-Feng, PAN Shang-Ke, BIAN Jian-Jiang, REN Guo-Hao. Optical and Scintillation Properties of Cs₂LiYCl₆:Ce Crystal [J]. Journal of Inorganic Materials, 2017, 32(2): 175-179.