Oxidation Behavior of Glucose on Platinized Diamond-like Carbon Film Electrode

doi:10.3724/SP.J.1077.2010.01325

Journal of Inorganic Materials ›› 2010, Vol. 25 ›› Issue (12): 1325-1329.DOI: 10.3724/SP.J.1077.2010.01325

• Research Paper • Previous Articles Next Articles

Oxidation Behavior of Glucose on Platinized Diamond-like Carbon Film Electrode

ZHAO Hai-Xin ^1,2, LIU Ai-Ping ^1,2, QIU Xu ^1,2, SHEN Guo-Xian²

(1. Department of Physics, Center for Optoelectronics Materials and Devices, Zhejiang Sci-Tech University; Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-tech University), Ministry of Education, Hangzhou 310018, China; 2. Zhejiang Province New Textile Research & Development Emphasised Laboratory, Zhejiang Textile & Garment Science & Technology Co., Ltd., Hangzhou 310009,China)

Received:2010-03-22 Revised:2010-06-07 Published:2010-12-20 Online:2010-11-24
Supported by:
National Natural Science Foundation of China (50902123); The Scientific Research Fund of Zhejiang Provincial Education Department (Y200806012); The Open Foundation of Zhejiang Province New Textile Research & Development Emphasised Laboratory (2009FZD003); The Excellent Young Talents Foundation of Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-tech University) (2009QN02)

Abstract

Abstract: In order to improve the electrochemical activity of conductive diamond-like carbon(DLC) film, platinized DLC (DLC-Pt) film was prepared by magnetron co-sputtering of graphite and platinum targets. The compositions and microstructures of DLC-Pt film were investigated by X-ray photoelectron spectroscope and Raman spectroscope, and the oxidation behaviors of glucose at the DLC-Pt film surface were examined by cyclic voltammetry. The results indicate that DLC-Pt film has more sp² carbon atoms compared with DLC film, and the redox reaction of K₃Fe(CN)₆on the DLC-Pt film electrode is controlled by diffusion. The glucose oxidation starts at about -0.8 V on the DLC-Pt film surface without interference from urea and ascorbic acid. A linear detection range of glucose obtained on the DLC-Pt electrode is identified from 2 mmol/L to 22 mmol/L (covering blood glucose levels in diabetic patients). So the DLC-Pt film has potential application to be a glucose sensor for blood glucose defection.

Key words: magnetron sputtering, platinized diamond-like carbon (DLC-Pt), glucose sensor, catalytic activity

CLC Number:

O646

ZHAO Hai-Xin, LIU Ai-Ping, QIU Xu, SHEN Guo-Xian. Oxidation Behavior of Glucose on Platinized Diamond-like Carbon Film Electrode[J]. Journal of Inorganic Materials, 2010, 25(12): 1325-1329.

References

[1] Gavin J R, Alberti K G M M, Davidson M B, et al. Report of the expert committee on the diagnosis and classification of diabetes mellitus. Diabetes Care, 1997, 20(7): 1183-1197. [2] Larew L A, Johnson D C. Concentration-dependence of the mechanism of glucose-oxidation at gold electrodes in alkaline media. J. Electroanal. Chem., 1989, 262(1/2): 167-182. [3] Lei H W, Wu B L, Cha C S, et al. Electrooxidation of glucose on platinum in alkaline-solution and selective oxidation in the presence of additives. J. Electroanal. Chem., 1995, 382(1/2): 103-110. [4] Parpot P, Pires S G, Bettencourt A P. Electrocatalytic oxidation of D-galactose in alkaline medium. J. Electroanal. Chem., 2004, 566(2): 401-408. [5] Ben Aoun S, Dursun Z, Koga T, et al. Effect of metal ad-layers on Au(111) electrodes on electrocatalytic oxidation of glucose in an alkaline solution. J. Electroanal. Chem., 2004, 567(2): 175-183. [6] Gilman S. Electroanalytical Chemistry. New York: Marcel Dekker, 1967: 111-192. [7] McCreery R L. Advanced carbon electrode materials for molecular electrochemistry. Chem. Rev., 2008, 108(7): 2646-2687. [8] Tatsuma T, Mori H, Fujishima A. Electron transfer from diamond electrodes to heme peptide and peroxidase. Anal. Chem., 2000, 72(13): 2919-2924. [9] Liu A P, Zhu J Q, Han J C, et al. Influence of phosphorus doping level and acid pretreatment on the voltammetric behavior of phosphorus incorporated tetrahedral amorphous carbon film electrodes. Electroanalysis, 2007, 19(17): 1773-1778. [10] Zhang Z E, Liu H Y, Deng J Q. A glucose biosensor based on immobilization of glucose oxidase in electropolymerized o-aminophenol film on platinized glassy carbon electrode. Anal. Chem., 1996, 68(9): 1632-1638. [11] Wang J, Carlisle J A. Covalent immobilization of glucose oxidase on conducting ultrananocrystalline diamond thin films. Diamond Relat. Mater., 2006, 15(2/3): 279-284. [12] Maalouf R, Soldatkin A, Vittori O, et al. Study of different carbon materials for amperometric enzyme biosensor development. Mater. Sci. Eng. C, 2006, 26(2/3): 564-567. [13] Park S, Boo H, Chung T D. Electrochemical non-enzymatic glucose sensors. Anal. Chim. Acta, 2006, 556(1): 46-57. [14] Ye J S, Wen Y, Zhang W D, et al. Nonenzymatic glucose detection using multi-walled carbon nanotube electrodes. Electrochem. Commun., 2004, 6(1): 66-70. [15] Robertson J. Diamond-like amorphous carbon. Mater. Sci. Eng. R, 2002, 37(4/5/6): 129-281. [16] 刘爱萍, 朱嘉琦, 韩杰才, 等(LIU Ai-Ping, et al). 掺磷四面体非晶碳薄膜电极的电化学伏安特性. 无机材料学报(Journal of Inorganic Materials), 2007, 22(6): 1056-1060. [17] Maalouf R, Chebib H, Saikali Y, et al. Characterization of different diamond-like carbon electrodes for biosensor design. Talanta, 2007, 72(1): 310-314. [18] Pocard N L, Alsmeyer D C, McCreery R L, et al. Nanoscale platinum(0) clusters in glassy-carbon: synthesis, characterization, and uncommon catalytic activity. J. Am. Chem. Soc., 1992, 114(2): 769-771. [19] Joo S H, Choi S J, Oh I, et al. Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature, 2001, 412(6843): 169-172. [20] You T Y, Niwa O, Tomita M, et al. Characterization of platinum nanoparticle- embedded carbon film electrode and its detection of hydrogen peroxide. Anal. Chem., 2003, 75(9): 2080-2085. [21] Ivandini T A, Sato R, Makide Y, et al. Pt-implanted boron-doped diamond electrodes and the application for electrochemical detection of hydrogen peroxide. Diamond Relat. Mater., 2005, 14(11/12): 2133-2138. [22] Menegazzo N, Jin C M, Narayan R J, et al. Compositional and electrochemical characterization of noble metal-diamondlike carbon nanocomposite thin films. Langmuir, 2007, 23(12): 6812-6818. [23] Ferrari A C, Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review B, 2000, 61(20): 14095-14107. [24] Belgsir E M, Bouhier E, Essis Yei H, et al. Electrosynthesis in aqueous- medium: a kinetic-study of the electrocatalytic oxidation of oxygented organic-molecules. Electrochim. Acta, 1991, 36(7): 1157-1164. [25] Tominaga M, Shimazoe T, Nagashima M, et al. Electrocatalytic oxidation of glucose at gold nanoparticle-modified carbon electrodes in alkaline and neutral solutions. Electrochem. Commun., 2005, 7(2): 189-193.

Oxidation Behavior of Glucose on Platinized Diamond-like Carbon Film Electrode

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Peng, JIN Zunlong, CHEN Ningguang, LIU Yonghao. Theoretical Investigation of Mo Doped α-MnO₂ Electrocatalytic Oxygen Evolution Reaction [J]. Journal of Inorganic Materials, 2022, 37(5): 541-546.
[2]	WANG Ying, ZHANG Wenlong, XING Yanfeng, CAO suqun, DAI Xinyi, LI Jingze. Performance of Amorphous Lithium Phosphate Coated Lithium Titanate Electrodes in Extended Working Range of 0.01-3.00 V [J]. Journal of Inorganic Materials, 2021, 36(9): 999-1005.
[3]	ZHAO Changjiang,MA Chao,LIU Juncheng,LIU Zhigang,CHEN Yan. Sputtering Power on the Microstructure and Properties of MgF₂ Thin Films Prepared with Magnetron Sputtering [J]. Journal of Inorganic Materials, 2020, 35(9): 1064-1070.
[4]	LI Yuan-Yang, JIANG Bo. λ/4-λ/2 Double-layer Broadband Antireflective Coatings with Superhydrophilicity and Photocatalysis [J]. Journal of Inorganic Materials, 2019, 34(2): 159-163.
[5]	WANG Mei-Han, WEN Jia-Xing, CHEN Yun, LEI Hao. Nano-structured WO₃ Thin Films Deposited by Glancing Angle Magnetron Sputtering [J]. Journal of Inorganic Materials, 2018, 33(12): 1303-1308.
[6]	CHENG Dan, HUANG Bin, CHEN Tao, JING Feng-Juan, XIE Dong, LENG Yong-Xiang, HUANG Nan. Microstructure of TiCuO Films on Copper Ion Release and Endothelial Cell Behavior [J]. Journal of Inorganic Materials, 2018, 33(10): 1089-1096.
[7]	WANG Hong-Yan, ZHANG Hao, JIANG Hong, WANG Guo-Qing, XIONG Chun-Rong. Preparation of Coating Glass with High Visible Transmittance and High UV Cut-off [J]. Journal of Inorganic Materials, 2017, 32(7): 758-764.
[8]	WANG Fo-Gen, CHEN Yun-Lu, REN Sheng-Qiang, ZHANG Jia-Yuan, WU Li-Li, FENG Liang-Huan. Properties of CdS:Al Films Deposited by Magnetron Sputtering [J]. Journal of Inorganic Materials, 2017, 32(4): 413-417.
[9]	CAI Wei-Wei, LI Jiao, HE Jing, WANG Wei-Wei. Controlled Synthesis and Photocatalytic Activity Evaluation of Nanostructured Ag₃PO₄ [J]. Journal of Inorganic Materials, 2017, 32(3): 263-268.
[10]	SONG Jia, XU Ying, MO Yan-Ping, LI Yong-An. Enhanced Photocatalytic Activity of Bi₂WO₆ by the Synergistic Action of Ti(IV) and Graphene Bi-cocatalysts [J]. Journal of Inorganic Materials, 2017, 32(3): 269-274.
[11]	TIAN Xiao, DUAN Ru-Xia, ZHAO Li-Juan, NAREN Ge-Ri-Le. Anode Catalyst for the Direct Borohydride Fuel Cell [J]. Journal of Inorganic Materials, 2017, 32(12): 1233-1242.
[12]	LI Miao-Lei, WANG En-Qing, YUE Jian-Ling, HUANG Xiao-Zhong. Microstructure, Mechanical and Tribological Property of TiAlN/VN Nano-multilayer Films [J]. Journal of Inorganic Materials, 2017, 32(12): 1280-1284.
[13]	CUI Lei, YANG Li-Juan, WANG Fan, XIA Wei-Wei. Fabrication of Flower-like Sn₃O₄Hollow Microspheres and Their Photocatalytic Activity [J]. Journal of Inorganic Materials, 2016, 31(5): 461-465.
[14]	ZHU Yu-Chan, YUAN Min, ZHANG Huan, WANG Le, QUAN Shan-Shan, CHAI Bo, REN Zhan-Dong. Preparation of Pt/Ti Electrodes Preferred Growth along the [111] Direction and Its Electrocatalytic Activity for Chlorine Evolution [J]. Journal of Inorganic Materials, 2016, 31(5): 510-516.
[15]	ZHAO Dan-Dan, YU Yan-Long, GAO Dong-Zi, CAO Ya-An. Properties and Photocatalytic Activity of Rutile TiO₂ Nanosheets [J]. Journal of Inorganic Materials, 2016, 31(1): 1-6.