Journal of Inorganic Materials

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Preparation and Investigation on Extreme-pressure Performance of PyDDP Surface Modified Borate-molybdenum Agent

TIAN Yan1,2, LIU Jun-Feng2, REN Nan-Qi2, HUANG Yu-Dong1   

  1. (1. School of Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China; 2. State Key Laboratory of Urban Water Resource & Environment, Harbin Institute of Technology, Harbin 150090, China)
  • Received:2009-04-07 Revised:2009-06-06 Published:2009-11-20 Online:2010-04-22

Abstract: Using pyridinium dialkyl dithiophosphate (PyDDP) as the surface modifying agent, PyDDP surface modified nanolanthanum borate and nano-molybdenum disulfide were prepared respectively, and borate-molybdenum agent was formed based on the two components. Infrared spectrum (IR), Xray diffraction (XRD) and transmission electron microscope (TEM) were employed to analyze the structure of nano-particles. The results showed that borate-molybdenum agent was consisted of nano-lanthanum borate and nano-molybdenum disulfide particles, and the particle size was around 30nm to 50nm. The tribological properties of PyDDP surface modified borate molybdenum agent were evaluated with four-ball test methods. The surface micrograph and the elements compositions for the scar of experimental ball were tested with scanning electron Microscope (SEM), electron diffraction Xray analysis (EDXA) and X-ray photoelectron spectroscope (XPS). The results show that borate-molybdenum agent possesses better extreme-pressure properties, and the property improvement of borate-molybdenum agent is due to the formation of inorganic reaction membrane.

Key words: surface modification, borate-molybdenum agent, anti-wear reagent at extreme pressure, modification with tribological chemistry

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