新型La2Mo2O9基氧离子导体的研究进展

摘要/Abstract

摘要： 自2000年Lacorre等人报道La₂Mo₂O₉具有较高的氧离子电导率以来,La₂Mo₂O₉ 基氧离子导体由于具有优异的性能而受到人们的关注．本文综述了新型氧离子导体La₂Mo₂O₉ 的研究现状．重点介绍了纯La₂Mo₂O₉及其掺杂体系的结构与相变、氧离子电导率、氧空位扩散机理、化学稳定性和热膨胀系数等性能．已有的研究结果表明,基于La₂Mo₂O₉的氧离子导体可望在固体氧化物燃料电池、氧传感器、透氧膜等方面得到应用．

关键词: 氧离子导体, La₂Mo₂O₉, 固体氧化物燃料电池

Abstract:

La₂Mo₂O₉-based oxide-ion conductors have attracted more and more attention since they were reported having high ionic conductivity in 2000 by Lacorre et. al. In this paper the recent investigation
on the novel La₂Mo₂O₉-based oxide-ion conductors is reviewed. It is focused on the structure and phase transition, oxide-ion conductivity, mechanism of oxygen vacancy diffusion, chemical stability,
and thermal expansion coefficient in the pure and doped La₂Mo₂O₉ samples. It is pointed out that the La₂Mo₂O₉-based oxide-ion conductors could be possibly applied in the field
such as solid oxide fuel cells, oxygen sensors, oxygen permeable membrane.

Key words: oxide-ion conductor, La₂Mo₂O₉, SOFC

中图分类号:

TM911

方前锋,王先平,程帜军,张国光. 新型La₂Mo₂O₉基氧离子导体的研究进展[J]. 无机材料学报.

FANG Qian-Feng,WANG Xian-Ping,Cheng Zhi-Jun,ZHANG Guo-Guang. Research Status of the Novel La₂Mo₂O₉-based Oxide-ion Conductors[J]. Journal of Inorganic Materials.

参考文献

[1] Kendall K R, Navas C, Thomas J K, et al. Solid State Ionics, 1995, 82: 215-223.
[2] Minh N Q. J. Am. Ceram. Soc., 1993, 76: 563-588.
[3] Lane J A, Benson S J, Waller D, et al. Solid State Ionics, 1999, 121: 201-208.
[4] Pimenov A, Ullrich J, Lunkenheimer P, et al. Solid State Ionics, 1998, 109: 111-118.
[5] Hibino T, Hashimoto A, Inoue T, et al. Science, 2000, 288: 2031-2033.
[6] Kilner J A. Solid State Ionics, 2000, 129: 13-23.
[7] Huang K, Tichy R S, Goodenough J B. J. Am. Ceram. Soc., 1998, 81: 2565-2575.
[8] Ishihara T, Kilner J A, Honda M, et al. Solid State Ionics, 1998, 113-115: 593-600.
[9] Lacorre P, Goutenoire F, Bohnke O, et al. Nature, 2000, 404: 856-858.
[10] Goutenoire F, Isnard O, Lacorre P. Chem. Matter., 2000, 12: 2575-2580.
[11] Lacorre P. Solid State Science, 2000, 2: 755-758.
[12] Wang X P, Fang Q F. Phys. Rev. B, 2002, 65: 064304-064309.
[13] Georges S, Goutenoire F, Altorfer F, et al. Solid State Ionics, 2003, 161: 231-241.
[14] Marozau I P, Marrero-Lopez D, Shaula A L, et al. Electrochimica Acta, 2004, 49: 3517-3524.
[15] Subasri R, Nafe H, Aldinger F. Mater. Res. Bull., 2003, 38: 1965-1977.
[16] Wang X P, Fang Q F. J. Phys. Condensed Matt., 2001, 13: 1641-1651.
[17] Wang X P, Fang Q F. Solid State Ionics, 2002, 146: 185-193.
[18] Wang X P, Fang Q F, Li Z S, et al. Appl. Phys. Lett., 2002, 81: 3434-3436.
[19] Wang X P, Fang Q F, Li Z S, et al. Mater. Sci. Eng. A, 2004, 370: 365-369.
[20] Yi Z G, Fang Q F, Wang X P. Solid State Ionics, 2003, 160: 117-124.
[21] Hayward S A, Redfern S A T. J. Phys. Condensed Matt., 2004, 16: 3571-3583.
[22] Arulraj A, Goutenoire F, Tabellout M, et al. Chem. Mater., 2002, 14: 2492-2498.
[23] Bo Q B, Feng J, Wang H Y, et al. Chinese Chem. Lett., 2003, 14: 197-200.
[24] Fang Q F, Wang X P, Zhang G G, et al. J. Alloy & Comp., 2003, 355: 177-182.
[25] 方前锋, 王先平, 张国光, 等. 金属学报, 2003, 39: 1133-1138.
[26] Wang X P, Cheng Z J, Fang Q F. Solid State ionics, 2005, 176: 761-765.
[27] Goutenoire F, Isnard O, Suard E, et al. J. Mater. Chem., 2001, 11: 119-124.
[28] Subasri R, Matusch D, Nafe H, et al. J. Eur. Ceram. Soc., 2004, 24: 129-137.
[29] Basu S, Devi P S, Maiti H S. Appl. Phys. Lett., 2004, 85: 3486-3488.
[30] Zhang G G, Fang Q F, Wang X P, et al. phys. stat. sol. (a), 2003, 199: 329-334.
[31] Georges S, Goutenoire F, Laligant Y, et al. J. Mater. Chem., 2003, 13: 2317-2321.
[32] Georges S, Goutenoire F, Bohnke O, et al. J. New Mater. Eletrochem. System., 2004, 7: 51-57.
[33] Yang J, Gu Z, Wen Z, et al. Solid State ionics, 2005, 176: 523-530.
[34] Tsai D S, Hsieh M J, Tseng J C, et al. J. Eur. Ceram. Soc., 2005, 25: 481-487.
[35] Khadasheva Z S, Venskovskii N U, Safronenko M G, et al. Inorg. Mater., 2002, 38: 1168-1171.
[36] Collado J A, Aranda M A G, Cabeza A, et al. J. Solid State Chem., 2002, 167: 80-85.
[37] Marrero-Lopez D, Ruiz-Morales J C, Nunez P, et al. J. Solid State Chem., 2004, 177: 2378-2386.
[38] Rocha R A, Muccillo E N S. Chem. Mater., 2003, 15: 4268-4272.
[39] Marrero-Lopez D, Ruiz-Morales J C, Perez-Coll D, et al. J. Solid State Electrochem., 2004, 8: 638-643.
[40] Lacorre P, Retoux R. J. Solid State Chem., 1997, 132: 443-446.
[41] Kuang W X, Fan Y I, Yao K W, et al. J. Solid State Chem., 1998, 140: 354-360.
[42] Tarancon A, Dezanneau G, Arbiol J, et al. J. Power Sources, 2003, 118: 256-264.
[43] Yang J, Wen Z, Gu Z, et al. J. Eur. Ceram. Soc., 2005, 25: 3315-3321.
[44] Georges S, Skinner S J, Lacorre P, et al. Dalton Trans., 2004, 19: 3101-3105.
[45] Fang Q F, Wang X P. Solid State Phenomenon, 2003, 89: 293-298.
[46] 袁立曦, 方前锋. 金属学报, 1998, 34: 1016-1020.
[47] Fang Q F, Wang X P, Zhang G G, et al. phys. Stat. Sol. (a), 2005, 202: 1041-1047.
[48] Goutenoire F, Retoux R, Suard E, et al. J. Solid State Chem., 1999, 142: 228-235.
[49] Tarancon A, Norby T, Dezanneau G, et al. Electrochem. & Solid State Lett., 2004, 7: A373-A375.
[50] Zhu B, Yang X T, Xu J, et al. J. Power Sources, 2003, 118: 47-53.
[51] Kosacki I, Suzuki T, Petrovsky V, et al. Solid State Ionics, 2000, 136-137: 1225-1233.
[52] Jiang S, Schulze W A, Amarakoon V R W, et al. J. Mater. Res., 1997, 12: 2374-2380.

新型La₂Mo₂O₉基氧离子导体的研究进展

Research Status of the Novel La₂Mo₂O₉-based Oxide-ion Conductors

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	潘建隆, 马官军, 宋乐美, 郇宇, 魏涛. 燃料还原法原位制备高稳定性/催化活性SOFC钴基钙钛矿阳极[J]. 无机材料学报, 2024, 39(8): 911-919.
[2]	叶梓滨, 邹高昌, 吴琪雯, 颜晓敏, 周明扬, 刘江. 阳极支撑型锥管串接式直接碳固体氧化物燃料电池组的制备及性能[J]. 无机材料学报, 2024, 39(7): 819-827.
[3]	张琨, 王宇, 朱腾龙, 孙凯华, 韩敏芳, 钟秦. LaNi_0.6Fe_0.4O₃阴极接触材料导电特性调控及其对SOFC电化学性能的影响[J]. 无机材料学报, 2024, 39(4): 367-373.
[4]	陈正鹏, 金芳军, 李明飞, 董江波, 许仁辞, 徐韩昭, 熊凯, 饶睦敏, 陈创庭, 李晓伟, 凌意瀚. 双钙钛矿Sr₂CoFeO₅₊_δ阴极材料的制备及其中温固体氧化物燃料电池性能研究[J]. 无机材料学报, 2024, 39(3): 337-344.
[5]	薛顶喜, 伊炳尧, 李国君, 马帅, 刘克勤. 功能梯度阳极固体氧化物燃料电池热应力数值模拟研究[J]. 无机材料学报, 2024, 39(11): 1189-1196.
[6]	郭天民, 董江波, 陈正鹏, 饶睦敏, 李明飞, 李田, 凌意瀚. 中温固体氧化物燃料电池的高熵双钙钛矿阴极材料: 兼容性与活性研究[J]. 无机材料学报, 2023, 38(6): 693-700.
[7]	樊帅, 金天, 张山林, 雒晓涛, 李成新, 李长久. Li₂O烧结助剂对固体氧化物燃料电池LSGM电解质烧结特性及离子电导率的影响[J]. 无机材料学报, 2022, 37(10): 1087-1092.
[8]	曹丹,周明扬,刘志军,颜晓敏,刘江. 阳极支撑质子导体电解质固体氧化物燃料电池的制备及其性能研究[J]. 无机材料学报, 2020, 35(9): 1047-1052.
[9]	夏天, 孟燮, 骆婷, 占忠亮. 固体氧化物燃料电池La_xSr_2-3_x_/2Fe_1.5Ni_0.1Mo_0.4O_6-_δ阳极性能研究[J]. 无机材料学报, 2020, 35(5): 617-622.
[10]	李凯, 李霄, 李箭, 谢佳苗. 基于应力分析Ni-Fe合金支撑固体氧化物燃料电池结构稳定性研究[J]. 无机材料学报, 2019, 34(6): 611-617.
[11]	汪维, 苑莉莉, 丘倩媛, 周明扬, 刘美林, 刘江. 流延法制备单片式直接碳固体氧化物燃料电池组及其性能研究[J]. 无机材料学报, 2019, 34(5): 509-514.
[12]	夏天, 孟燮, 骆婷, 占忠亮. Ca掺杂Sr₂Fe_1.5Mo_0.5O_6-_δ材料的合成与作为对称固体氧化物燃料电池电极催化剂的性能研究[J]. 无机材料学报, 2019, 34(10): 1109-1114.
[13]	李斯琳, 屠恒勇, 于立军. 中温固体氧化物燃料电池Nd₂NiO₄₊_δ-Ce_0.8Gd_0.2O_2-_δ复合阴极性能研究[J]. 无机材料学报, 2017, 32(5): 469-475.
[14]	徐红梅, 张华, 李恒, 简耀永, 谢武, 王一平, 徐铭泽. 纳米结构LSCF-SDC复合阴极的制备及其氧还原机理研究[J]. 无机材料学报, 2017, 32(4): 379-385.
[15]	谢佳苗, 王峰会. 基于热应力分析的固体氧化物燃料电池阳极功能层优化设计[J]. 无机材料学报, 2017, 32(4): 400-406.