无机材料学报 ›› 2015, Vol. 30 ›› Issue (3): 225-232.DOI: 10.15541/jim20140346 CSTR: 32189.14.10.15541/jim20140346
• • 下一篇
樊 龙, 黎宇坤, 陈 韬, 李 晋, 杨志文, 袁 铮, 邓 博, 曹柱荣, 胡 昕
收稿日期:
2014-07-02
修回日期:
2014-09-03
出版日期:
2015-03-20
网络出版日期:
2015-03-06
基金资助:
FAN Long, LI Yu-Kun, CHEN Tao, LI Jin, YANG Zhi-Wen, YUAN Zheng, DENG Bo, CAO Zhu-Rong, HU Xin
Received:
2014-07-02
Revised:
2014-09-03
Published:
2015-03-20
Online:
2015-03-06
Supported by:
摘要:
碘化铯(CsI)薄膜因对X射线及紫外光具有高的光电转换效率而倍受关注。在核物理、高能物理以及天体物理研究的推动下, 研制高量子效率(QE)、性能稳定的CsI薄膜光阴极成为了近年来研究的热点。然而, 目前人们对某些影响其性能的因素还不完全清楚或确定。本文综述了CsI薄膜光阴极的最新研究进展, 总结了影响QE的因素和光阴极的老化机理, 重点关注了一些存在争议的问题, 并对其研究发展方向进行了探讨。
中图分类号:
樊 龙, 黎宇坤, 陈 韬, 李 晋, 杨志文, 袁 铮, 邓 博, 曹柱荣, 胡 昕. 碘化铯薄膜光阴极的研究进展[J]. 无机材料学报, 2015, 30(3): 225-232.
FAN Long, LI Yu-Kun, CHEN Tao, LI Jin, YANG Zhi-Wen, YUAN Zheng, DENG Bo, CAO Zhu-Rong, HU Xin. Recent Progress in Research on CsI Thin Film Photocathodes[J]. Journal of Inorganic Materials, 2015, 30(3): 225-232.
图1 (a) Parylene-N /Au /CsI透射式光阴极; (b) MCP表面反射式CsI光阴极
Fig. 1 (a) Parylene-N /Au /CsI semitransparence photocathode; (b) Refective CsI photocathode coated on the surface of microchannel plate (MCP)
图2 (a) CsI/ MgO/ MWCNTs/ Si结构光阴极的SEM照片[45]; (b)等离子体刻蚀过的Si基底的SEM照片; (c)Si基底上CsI薄膜暴露于空气前的AFM照片; (d) Si基底上CsI薄膜暴露于空气24 h的AFM照片[41]
Fig. 2 (a) SEM image of the CsI/ MgO/ MWCNTs/ Si photocathode[45]; (b) SEM image of the Si substrate patterned by colloidal lithography after lift-off process; (c)AFM image of the fresh CsI film evaporated on the Si patterned substrate; (d) AFM image of the CsI film on the Si patterned substrate exposed to ambient air for 24 h[41]
图3 (a)刚制备、(b)在空气中暴露后、(c)在极端潮湿环境中暴露后CsI薄膜的SEM照片[49]; (d)NIF采用的X射线条纹相机上200 nm厚的CsI透射式光阴极信号下降与空气暴露时间的关系[47]
Fig. 3 SEM images of as-deposited (a), aged in ambient air (b) and extreme moisture exposed CsI films (c)[49]; Percent degradation in the yield signal of streak camera used at NIF from a 200 nm thick CsI cathode as a function of air exposure time[47]
图4 (a)5 d UV辐照后CsI薄膜的AFM照片[11]; (b) 5 d UV辐照后的PEEM照片[11]; (c)UV辐照后的TEM照片[48]
Fig. 4 (a) AFM image of the 5 d UV-irradiated CsI photocathode[11]; (b) PEEM image of the 5 d UV-irradiated CsI photocathode[11]; (c) TEM image of the UV-irradiated CsI film[48]
[1] | FENG J, SHIN H J, NASIATKA J R, et al. An x-ray streak camera with high spatio-temporal resolution. Appl. Phys. Lett., 2007, 91(13): 134102-1-3. |
[2] | MOLNAR L.The ALICE HMPID detector ready for collisions at the LHC.Nucl. Instrum. Methods Phys. Res., Sect. A, 2008, 595(1): 27-30. |
[3] | NAPPI E.Trends in the development of large area photon detectors for Cherenkov light imaging applications.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 504(1/2/3): 70-87. |
[4] | WANG W, FANG Z H, JIA G, et al. Multispectral X-ray imaging with a multichannel Kirkpatrick-Baez microscope for imploded core temperature observation. The European Physical Journal D, 2014,68(5):129-1-5. |
[5] | XIE W Q, LI Y L, LI J, et al.Study of VUV Detector Based on Thinner THGEM for CDEX. Nuclear Science Symposium and Medical Imaging Conference (NSS/MIC), Anaheim, CA, 2012: 1127-1130. |
[6] | XIE Y G, ZHANG A W, LIU Y B, et al.Influence of air exposure on CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2012, 689: 79-86. |
[7] | TREMSIN A S, SIEGMUND O H. The Quantum Efficiency and Stability of UV and Soft X-ray Photocathodes. Proc. SPIE5920, Ultrafast X-Ray Detectors, High-Speed Imaging, and Applications, San Diego, USA, 2005: 592001-1-13. |
[8] | HOEDLMOSER H, BRAEM A, De CATALDO G, et al.Long term performance and ageing of CsI photocathodes for the ALICE/HMPID detector.Nucl. Instrum. Methods Phys. Res., Sect. A, 2007, 574(1): 28-38. |
[9] | SINGH B K, TRILOKI, GARG P, et al.VUV-induced radiation ageing processes in CsI photocathodes studied by microscopy and spectroscopy techniques.Nucl. Instrum. Methods Phys. Res., Sect. A, 2009, 610(1): 350-353. |
[10] | SINGH B K, SHEFER E, BRESKIN A, et al.CsBr and CsI UV photocathodes: new results on quantum efficiency and aging.Nucl. Instrum. Methods Phys. Res., Sect. A, 2000, 454(2/3): 364-378. |
[11] | SINGH B K, NITTI M A, VALENTINI A, et al.Ageing of CsI thin film photocathodes induced by UV photons.Nucl. Instrum. Methods Phys. Res., Sect. A, 2007, 581(3): 651-655. |
[12] | BUZULUTSKOV A F.Gaseous photodetectors with solid photocathodes.Phys. Part. Nuclei, 2008, 39(3): 424-453. |
[13] | BRAEM A, DAVENPORT M, Di MAURO A, et al.Aging of large-area CsI photocathodes for the ALICE HMPID prototypes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 515(1): 307-312. |
[14] | PIUZ F.Ring Imaging CHerenkov systems based on gaseous photo-detectors: trends and limits around particle accelerators.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 502(1): 76-90. |
[15] | NAPPI E.CsI RICH detectors in high energy physics experiments.Nucl. Instrum. Methods Phys. Res., Sect. A, 2001, 471(1): 18-24. |
[16] | SCHYNS E.Status of large area CsI photocathode developments.Nucl. Instrum. Methods Phys. Res., Sect. A, 2002, 494(1/2/3): 441-446. |
[17] | XIE Y G, LIU H B, ZHANG A W, et al.Quantum efficiency measurement of CsI photocathodes using synchrotron radiation at BSRF.Nucl. Instrum. Methods Phys. Res., Sect. A, 2012, 664(1): 310-316. |
[18] | NITTI M A, NAPPI E, VALENTINI A, et al.Progress in the production of CsI and diamond thin film photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2005, 553(1/2): 157-164. |
[19] | NITTI M A, VALENTINI A, SENESI G S, et al.Ion-beam sputtering deposition of CsI thin films.Applied Physics A, 2005, 80(8): 1789-1791. |
[20] | FAIRCHILD S B, BACK T C, MURRAY P T, et al. Low work function CsI coatings for enhanced field emission properties. J. Vac. Sci. Technol. A, 2011, 29(3): 031402-1-6. |
[21] | BRENDEL' V M, BUKIN V V, GARNOV S V, et al. Fabrication of alkali halide UV photocathodes by pulsed laser deposition.Quantum Electron., 2012, 42(12): 1128-1132. |
[22] | BUZULUTSKOV A, BRESKIN A, CHECHIK R.Heat enhancement of the photoyield from CsI, NaI and CuI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 1995, 366(2/3): 410-412. |
[23] | HOEDLMOSER H, BRAEM A, De CATALDO G, et al.Production technique and quality evaluation of CsI photocathodes for the ALICE/HMPID detector.Nucl. Instrum. Methods Phys. Res., Sect. A, 2006, 566(2): 338-350. |
[24] | BRESKIN A.CsI UV photocathodes: history and mystery.Nucl. Instrum. Methods Phys. Res., Sect. A, 1996, 371(1/2): 116-136. |
[25] | FRIESE J, GERNHÄUSER R, HOMOLKA J, et al. Enhanced quantum efficiency for CsI grown on a graphite-based substrate coating.Nucl. Instrum. Methods Phys. Res., Sect. A, 1999, 438(1): 86-93. |
[26] | VALENTINI A, NAPPI E, NITTI M A.Influence of the substrate reflectance on the quantum efficiency of thin CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2002, 482(1/2): 238-243. |
[27] | LU C, MCDONALD K T.Properties of reflective and semitransparent CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 1994, 343(1): 135-151. |
[28] | BOUTBOUL T, BRESKIN A, CHECHIK R, et al.On the surface morphology of thin alkali halide photocathode films.Nucl. Instrum. Methods Phys. Res., Sect. A, 1999, 438(2/3): 409-414. |
[29] | LI Y K, CHEN T, DENG B, et al. Energy spectral response of photocathode for soft X-ray streak camera. High Power Laser and Particle Beams, 2014, 26(02): 02202-1-4. |
[30] | YUAN Z, ZENG P, DENG B, et al. Spectral Sensitivity Calibration of Au and CsI Photocathodes of High Speed X-ray Scanning Camera. Proc. SPIE8419, 6th International Symposium on Advanced Optical Manufacturing and Testing Technologies: Optoelectronic Materials and Devices for Sensing, Imaging, and Solar Energy, Xiamen, China, 2012: 841921-1-6. |
[31] | ZENG P, YUAN Z, DENG B, et al.Spectral response calibration of Au and CsI transmission photocathodes of X-ray streak camera in a 60-5500 eV photon energy region. Acta Phys. Sin. 2012, 61(15): 379-385. |
[32] | BRAEM A, JORAM C, PIUZ F, et al.Technology of photocathode production.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 502(1): 205-210. |
[33] | LI M, NI Q L, CHEN B.Calculation of quantum efficiency of alkali halide photocathode materials in the extreme ultraviolet region.Acta Phys. Sin., 2009, 58(10): 6894-6901. |
[34] | LARRUQUERT J I, MENDEZ J A, AZNAREZ J A, et al.Optical properties and quantum efficiency of thin-film alkali halides in the far ultraviolet.Appl. Optics, 2002, 41(13): 2532-2540. |
[35] | GARAI B, RADHAKRISHNA V, RAJANNA K.Effect of vacuum treatment on CsI photocathode performance in UV photon detectors.Optical Materials Express, 2013, 3(7): 948-953. |
[36] | MAURO A D, MARTINENGO P, PIUZ F, et al.Study of the quantum efficiency of CsI photocathodes exposed to oxygen and water vapour.Nucl. Instrum. Methods Phys. Res., Sect. A, 2001, 461(1/2/3): 584-586. |
[37] | NITTI M A, CIOFFI N, NAPPI E, et al.Influence of bias voltage on the stability of CsI photocathodes exposed to air.Nucl. Instrum. Methods Phys. Res., Sect. A, 2002, 493(1/2): 16-24. |
[38] | KUMAR K, ARUN P, KANT C R, et al.The effect of cesium metal clusters on the optical properties of cesium iodide thin films.Applied Physics A, 2010, 99(1): 305-310. |
[39] | KUMAR K, ARUN P, KANT C R, et al. Metal cluster’s effect on the optical properties of cesium bromide thin films. Appl. Phys. Lett., 2012, 100(24): 243106-1-7. |
[40] | TIAN J Q, JIANG D L, SUN X P, et al.Study on new MCP reflection X-ray sensitive film of variable density halide.Chinese Journal of Luminescence, 2002, 23(5): 513-517. |
[41] | NITTI M A, TINTI A, VALENTINI A, et al.Influence of the substrate surface texture on the photon-sensitivity stability of CsI thin film photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2009, 610(1): 234-237. |
[42] | SHEFER E, BRESKIN A, BOUTBOUL T, et al.Photoelectron transport in CsI and CsBr coating films of alkali antimonide and CsI photocathodes.J. Appl. Phys., 2002, 92(8): 4758-4771. |
[43] | SINGH B K, NAPPI E, NITTI M A, et al.Role of the substrate reflectance and surface-bulk treatments in CsI quantum efficiency.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 502(1): 108-111. |
[44] | HALVORSON C, HOUCK T, MACPHEE A, et al. High energy photocathodes for laser fusion diagnostics. Rev. Sci. Instrum., 2010, 81(10): 10E309-1-3. |
[45] | LEE J, PARK T, LEE W, et al. Evaluation of a cesium iodide photocathode assisted with MgO-coated multiwall carbon nanotubes. Appl. Phys. Lett., 2010, 96(14): 141109-1-3. |
[46] | QIAN W J, LAI H W, PEI X Z, et al.Improving field emission by constructing CsI-AlN hybrid nanostructures.J. Mater. Chem., 2012, 22(35): 18578-18582. |
[47] | OPACHICH Y P, KALANTAR D H, MACPHEE A G, et al. High performance imaging streak camera for the National Ignition Facility. Rev. Sci. Instrum., 2012, 83(12): 125105-1-6. |
[48] | TREMSIN A S, RUVIMOV S, SIEGMUND O H W. Structural transformation of CsI thin film photocathodes under exposure to air and UV irradiation.Nucl. Instrum. Methods Phys. Res., Sect. A, 2000, 447(3): 614-618. |
[49] | FAN L, YANG Z W, CHEN T, et al. Influence of air exposure on the structure and properties of cesium iodide film. Acta Phys. Sin.2014, 14(63):146801-1-7. |
[50] | TRILOKI, DUTTA B, SINGH B K.Influence of humidity on the photoemission properties and surface morphology of cesium iodide photocathode.Nucl. Instrum. Methods Phys. Res., Sect. A, 2012, 695: 279-282. |
[51] | KUMAR K, ARUN P, KANT C R, et al.The effect of cesium metal clusters on the optical properties of cesium iodide thin films.Applied Physics A, 2010, 99(1): 305-310. |
[52] | ALMEIDA J, BRAEM A, BRESKIN A, et al.Microanalysis surface studies and photoemission properties of CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 1995, 367(1/2/3): 337-341. |
[53] | BOUTBOUL T, AKKERMAN A, BRESKIN A, et al.Escape length of ultraviolet induced photoelectrons in alkali iodide and CsBr evaporated films: Measurements and modeling.J. Appl. Phys., 1998, 84(5): 2890-2896. |
[54] | TREMSIN A S, SIEGMUND O H.The Dependence of Quantum Efficiency of Alkali Halide Photocathodes on the Radiation Incidence angle. Proc. SPIE 3765, EUV, X-Ray, and Gamma-Ray Instrumentation for Astronomy X, Denver, 1999: 441-451. |
[55] | BUZULUTSKOV A, BRESKIN A, CHECHIK R.Photoemission from CsI/LiF and CsI/NaF films, enhanced by exposure to water vapour.Nucl. Instrum. Methods Phys. Res., Sect. A, 1996, 372(3): 572-574. |
[56] | SENESI G S, NITTI M A, VALENTINI A.A scanning electron and atomic force microscopy study of the surface morphology and composition of CsI films as affected by evaporation rate and humid-air exposure.Microsc. Microanal., 2005, 11(2): 124-132. |
[57] | NITTI M A, SENESI G S, LIOTINO A, et al.Influence of the film deposition rate and humidity on the properties of thin CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2004, 523(3): 323-333. |
[58] | TREMSIN A S, SIEGMUND O H W. UV radiation resistance and solar blindness of CsI and KBr photocathodes.IEEE Transactions on Nuclear Science, 2001, 48(3): 421-425. |
[59] | TREMSIN A S, PEARSON J F, NICHOLS A P, et al.X-ray-induced radiation damage in CsI, Gadox, Y2O2S and Y2O3 thin films.Nucl. Instrum. Methods Phys. Res., Sect. A, 2001, 459(3): 543-551. |
[60] | TREMSIN A S, SIEGMUND O H W. Quantum efficiency and stability of alkali halide UV photocathodes in the presence of electric field.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 504(1): 4-8. |
[61] | VA’VRA J. Physics and chemistry of aging-early developments.Nucl. Instrum. Methods Phys. Res., Sect. A, 2003, 515(1): 1-14. |
[62] | RUDOLF P, MARCHAL F, SPORKEN R, et al.Laterally resolved measurements of polycrystalline cesium iodide surfaces.Nucl. Instrum. Methods Phys. Res., Sect. A, 1997, 387(1/2): 163-170. |
[63] | TREMSIN A S, SIEGMUND O H W. Heat enhancement of radiation resistivity of evaporated CsI, KI and KBr photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 2000, 442(1/2/3): 337-341. |
[64] | LU C, MCDONALD K T.Properties of reflective and semitransparent CsI photocathodes.Nucl. Instrum. Methods Phys. Res., Sect. A, 1994, 343(1): 135-151. |
[65] | KAN T, MATSUMOTO K, SHIMOYAMA I.Nano-pattern Replication Using Parylene Thin Film for Optical Applications. Micro Electro Mechanical Systems, IEEE 20th International Conference on, Hyogo, 2007: 819-822. |
[66] | FEDOROV A, LEBEDINSKY A, MATEYCHENKO P.Dewetting behavior of CsI layers on LiF substrate.J. Cryst. Growth, 2011, 318(1): 595-598. |
[67] | THOMPSON C V.Solid-state dewetting of thin films.Ann. Rev. Mater. Res., 2012, 42: 399-434. |
[68] | YAO D L, GU M, LIU X L, et al.Performance of columnar CsI(Tl) scintillation films prepared on special pre-deposited layers.Appl. Surf. Sci., 2013, 276: 776-781. |
[69] | LIU J, ZHANG X S, DONG G Q, et al.The performances of silicon solar cell with core-shell pn junctions of micro-nano pillars fabricated by cesium chloride self-assembly and dry etching.Applied Physics A, 2014, 114(4): 1175-1179. |
[70] | WANG Y Y, GAO Y, WANG X M, et al.Fabrication and ultraviolet photoemission characteristics of novel Au photocathodes.High Power Laser and Particle Beams, 2013, 25(10): 2627-2630. |
[71] | GUO L, LI S W, ZHENG J, et al. A compact flat-response x-ray detector for the radiation flux in the range from 1.6 keV to 4.4 keV. Meas. Sci. Technol., 2012, 23(6): 065902-1-6. |
[1] | 魏相霞, 张晓飞, 徐凯龙, 陈张伟. 增材制造柔性压电材料的现状与展望[J]. 无机材料学报, 2024, 39(9): 965-978. |
[2] | 杨鑫, 韩春秋, 曹玥晗, 贺桢, 周莹. 金属氧化物电催化硝酸盐还原合成氨研究进展[J]. 无机材料学报, 2024, 39(9): 979-991. |
[3] | 刘鹏东, 王桢, 刘永锋, 温广武. 硅泥在锂离子电池中的应用研究进展[J]. 无机材料学报, 2024, 39(9): 992-1004. |
[4] | 黄洁, 汪刘应, 王滨, 刘顾, 王伟超, 葛超群. 基于微纳结构设计的电磁性能调控研究进展[J]. 无机材料学报, 2024, 39(8): 853-870. |
[5] | 陈乾, 苏海军, 姜浩, 申仲琳, 余明辉, 张卓. 超高温氧化物陶瓷激光增材制造及组织性能调控研究进展[J]. 无机材料学报, 2024, 39(7): 741-753. |
[6] | 王伟明, 王为得, 粟毅, 马青松, 姚冬旭, 曾宇平. 以非氧化物为烧结助剂制备高导热氮化硅陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 634-646. |
[7] | 蔡飞燕, 倪德伟, 董绍明. 高熵碳化物超高温陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 591-608. |
[8] | 吴晓晨, 郑瑞晓, 李露, 马浩林, 赵培航, 马朝利. SiCf/SiC陶瓷基复合材料高温环境损伤原位监测研究进展[J]. 无机材料学报, 2024, 39(6): 609-622. |
[9] | 赵日达, 汤素芳. 多孔碳陶瓷化改进反应熔渗法制备陶瓷基复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 623-633. |
[10] | 方光武, 谢浩元, 张华军, 高希光, 宋迎东. CMC-EBC损伤耦合机理及一体化设计研究进展[J]. 无机材料学报, 2024, 39(6): 647-661. |
[11] | 张幸红, 王义铭, 程源, 董顺, 胡平. 超高温陶瓷复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 571-590. |
[12] | 张慧, 许志鹏, 朱从潭, 郭学益, 杨英. 大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展[J]. 无机材料学报, 2024, 39(5): 457-466. |
[13] | 李宗晓, 胡令祥, 王敬蕊, 诸葛飞. 氧化物神经元器件及其神经网络应用[J]. 无机材料学报, 2024, 39(4): 345-358. |
[14] | 鲍可, 李西军. 化学气相沉积法制备智能窗用热致变色VO2薄膜的研究进展[J]. 无机材料学报, 2024, 39(3): 233-258. |
[15] | 胡梦菲, 黄丽萍, 李贺, 张国军, 吴厚政. 锂/钠离子电池硬碳负极材料的研究进展[J]. 无机材料学报, 2024, 39(1): 32-44. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||