等离子加热反应合成TiB2-B4C-Fe3(C, B)复合材料研究

doi:10.3724/SP.J.1077.2014.13378

无机材料学报 ›› 2014, Vol. 29 ›› Issue (4): 423-428.DOI: 10.3724/SP.J.1077.2014.13378 CSTR: 32189.14.SP.J.1077.2014.13378

等离子加热反应合成TiB₂-B₄C-Fe₃(C, B)复合材料研究

崔洪芝, 张珊珊, 王晓彬, 赫庆坤, 宋强

(山东科技大学材料科学与工程学院, 青岛 266590)

收稿日期:2013-07-25 修回日期:2013-09-07 出版日期:2014-04-20 网络出版日期:2014-03-24
基金资助:
国家自然科学基金(51072104, 51272141); 山东省“泰山学者”计划(ts20110828)

TiB₂-B₄C-Fe₃(C, B) Composite Synthesized by Plasma Heating

CUI Hong-Zhi, ZHANG Shan-Shan, WANG Xiao-Bin, HE Qing-Kun, SONG Qiang

(School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China)

Received:2013-07-25 Revised:2013-09-07 Published:2014-04-20 Online:2014-03-24
Supported by:
National Natural Science Foundation of China (51072104,51272141); Taishan Scholars Project of Shandong Province (ts20110828)

摘要/Abstract

摘要： 以Ti、B₄C和Fe粉为原料, 采用等离子束加热反应合成TiB₂-B₄C-Fe₃(C, B)复合材料, 并研究复合材料的物相、组织结构和显微硬度。结果表明: 反应生成物相主要有TiB₂、B₄C以及Fe₃(C, B)。由于等离子束的快速加热、冷却以及散热具有方向性, 板条状TiB₂晶粒沿散热最快的方向生长, 与白色的Fe₃(C, B)相间分布, 未反应的B₄C被挤压在板条之间; 等离子束电流影响单位时间内输入试样的热量, 电流越大越有利于TiB₂的长大, 但降低复合材料硬度。

关键词: TiB₂-B₄C-Fe₃(C, B)复合材料, 等离子, 显微组织, 反应合成

Abstract: TiB₂-B₄C-Fe₃(C, B) composites were prepared by plasma heating synthesis with Ti, B₄C and Fe powders as raw materials. Effects of plasma current on phase composition, microstructure and hardness of the final composites were studied. The results show that the final composites are composed of TiB₂, B₄C and Fe₃(C, B). Because of fast heating and cooling during the plasma heating synthesis and directional heat releasing, plate-like TiB₂ grains grow along the fastest heat releasing direction. TiB₂ plates and white Fe₃(C, B) are alternating distribution while the unreacted B₄C grains are packed into gaps. Plasma current affects the heat which inputted into the sample in unit time. Hence, increasing current is conducive to the growth of TiB₂, but decrease the hardness of the composites.

Key words: TiB₂-B₄C-Fe₃(C, B) composite, plasma, microstructure, reaction synthesis

中图分类号:

TB333

崔洪芝, 张珊珊, 王晓彬, 赫庆坤, 宋强. 等离子加热反应合成TiB₂-B₄C-Fe₃(C, B)复合材料研究[J]. 无机材料学报, 2014, 29(4): 423-428.

CUI Hong-Zhi, ZHANG Shan-Shan, WANG Xiao-Bin, HE Qing-Kun, SONG Qiang. TiB₂-B₄C-Fe₃(C, B) Composite Synthesized by Plasma Heating[J]. Journal of Inorganic Materials, 2014, 29(4): 423-428.

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等离子加热反应合成TiB₂-B₄C-Fe₃(C, B)复合材料研究

TiB₂-B₄C-Fe₃(C, B) Composite Synthesized by Plasma Heating

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