超声化学结合放电等离子烧结制备In4Se3化合物的热电性能研究

doi:10.3724/SP.J.1077.2012.00201

无机材料学报 ›› 2012, Vol. 27 ›› Issue (2): 201-204.DOI: 10.3724/SP.J.1077.2012.00201 CSTR: 32189.14.SP.J.1077.2012.00201

超声化学结合放电等离子烧结制备In₄Se₃化合物的热电性能研究

刘丹丹, 王善禹, 唐新峰

(武汉理工大学材料复合新技术国家重点实验室, 武汉 430070)

收稿日期:2011-02-28 修回日期:2011-04-07 出版日期:2012-02-10 网络出版日期:2012-01-05
作者简介:刘丹丹(1985-), 女, 硕士研究生. E-mail: liu_dandan@163.com
基金资助:
国家973计划(2007CB607501) 973 Program (2007CB607501)

Thermoelectric Properties of In₄Se₃ Synthesized by Combing Sonochemical and SPS Method

LIU Dan-Dan, WANG Shan-Yu, TANG Xin-Feng

(State Key Laboratory of Advanced Technology for Material Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China)

Received:2011-02-28 Revised:2011-04-07 Published:2012-02-10 Online:2012-01-05
About author:LIU Dan-Dan. E-mail: liu_dandan@163.com

摘要/Abstract

摘要：

采用超声化学和后续还原热处理工艺合成了单相In₄Se₃化合物粉体, 并结合放电等离子烧结技术(SPS)制备了致密的块体材料. 对所得的块体材料的微结构和热电传输性能进行了系统研究. 结果表明, 块体样品的晶粒细小、排列紧密并存在显著的择优取向, 同时样品中存在大量精细的层状结构, 这使得块体样品的电热传输性能也表现出明显的各向异性. 由于具有较高的Seebeck系数和较低的热导率, 沿着SPS压力方向上样品表现出较好的热电性能, 其最大ZT值在700 K可达到0.56, 这与其它物理技术制备的In₄Se₃多晶材料的性能相当.

关键词: In₄Se₃, 超声化学法, 各向异性, 热电性能

Abstract:

Single-phase In₄Se₃ powders were synthesized by a sonochemical method combined with subsequent deoxidizing heat-treatment, and a bulk sample was prepared via a spark plasma sintering (SPS) method. The phase composition, microstructures and thermoelectric transport properties of the as-prepared bulk sample were studied. The bulk sample possesses refined crystalline and obvious anisotropy observed in the different directions, where a large number of fine layered structures exist along the SPS pressing direction. Therefore, the thermoelectric properties of the bulk sample also show significant anisotropy. Owing to higher Seebeck coefficient and lower thermal conductivity, a better ZT is achieved in direction of the SPS pressure compared with the perpendicular direction. As a result, the maximum ZT reaches 0.56 at 700 K, which is comparable with that of the samples synthesized by other physical techniques.

Key words: In₄Se₃, sonochemicial method, anisotropy, thermoelectric properties

中图分类号:

TB34

刘丹丹, 王善禹, 唐新峰. 超声化学结合放电等离子烧结制备In₄Se₃化合物的热电性能研究[J]. 无机材料学报, 2012, 27(2): 201-204.

LIU Dan-Dan, WANG Shan-Yu, TANG Xin-Feng. Thermoelectric Properties of In₄Se₃ Synthesized by Combing Sonochemical and SPS Method[J]. Journal of Inorganic Materials, 2012, 27(2): 201-204.

图/表 5

图1 SPS烧结后样品的XRD图谱

Fig. 1 XRD pattern of the sample sintered by SPS method

图2 (a)(b)AZ方向; (c)(d)PZ方向块体材料的FESEM照片

Fig. 2 FESEM images of bulk sample in (a)(b) AZ direction and (c)(d) PZ direction

图3 样品不同方向(a)电导率、(b)Seebeck系数、(c)功率因子和(d)热导率随温度变化关系

Fig. 3 Temperature dependences of (a) electrical conductivities, (b) seebeck coffecient, (c) power factors and (d) Thermal conductivities of the sample in different directions

Table 1 Values of Hall coefficient RH, electrical resistivity ρ, carrier concentration n, mobility μH and Seebeck coefficient α at room temperature

Direction	R_H/(×10^-6, m³·C^-1)	ρ/(m Ω·m)	n/(×10¹⁸, cm^-3)	μ_H/(cm²·V^-1·s^-1)	α?(μV·K^-1)
AZ	-1.61	1.837	-3.9	8.8	-209.4
PZ	-1.27	0.796	-4.9	16.0	-52.4

图4 样品的不同方向ZT值随温度的变化

Fig. 4 Temperature dependences of ZT value of the sample in different directions

参考文献 13

[1]	Loffe A F. Semiconductors Thermoelements and Thermoelectric Cooling. Interscince Publishers, New York-London, 1961.
[2]	Snyder G J, Toberer E S. Complex thermoelectric materials. Nature Materials, 2008, 7: 105-114.
[3]	Tritt T M. Thermoelectric materials: holey and unholey semiconductors. Science, 1999, 283(5403): 804-805.
[4]	Bell L E. Cooling, heating, generating power, and recovering waste heat with thermoelectric systems. Science, 2008, 321(5895): 1457-1461.
[5]	Dresselhaus M S, Chen G, Tang M Y, et al. New directions for low-dimensional thermoelectric materials. Advanced Materials, 2007, 19(8): 1043-1053.
[6]	Minnich A J, Dresselhaus M S, Ren Z F, et al. Bulk nanostructured thermoelectric materials: current research and future prospects. Energy & Environmental Science, 2009, 2(5): 466-479.
[7]	Rhyee J S, Lee K H, Lee S M, et al. Peierls distortion as a route to high thermoelectric performance in In4Se3-delta crystals. Nature, 2009, 459(7249): 965-968.
[8]	Bercha D M, Rushchanskii K Z, Sznajder M. Phonon spectrum of the layered In4Se3 crystal. Physica Status Solidi (b), 1999, 212(2): 247-261.
[9]	Scherrer H,Scherrer S. Bismuth Telluride, Antimony Telluride, and Their Solid Solutions. CRC Handbook of Thermoelectrics; Rowe, DM, Ed.; CRC Press: Boca Raton, FL, 1995.
[10]	Drabble J R, Goodman C. Chemical bonding in bismuth telluride. Journal of Physics and Chemistry of Solids, 1958, 5(1/2): 142-144.
[11]	Rhyee J S, Cho E, Lee K H, et al. Thermoelectric properties and anisotropic electronic band structure in the InSe compounds. Applied Physics Letters, 2009, 95(21): 212106-1-3.
[12]	Shi X, Cho J Y, Salvador J R, et al. Thermoelectric properties of polycrystalline InSe and InTe. Applied Physics Letters, 2010, 96(16): 162108-1-3.
[13]	Yan X, Poudel B, Ma Y, et al. Experimental studies on anisotropic thermoelectric properties and structures of n-Type Bi2Te2.7Se0.3. Nano Letters, 2010, 10(9): 3373-3378.

[1]	胡宇晨, 徐子硕, 胡悦娟, 陈立东, 姚琴. 单壁碳纳米管复合增强二维平面聚酞菁铜的热电性能[J]. 无机材料学报, 2026, 41(1): 63-69.
[2]	吴华鑫, 张骐昊, YAN Haixue, 王连军, 江莞. 纳米复合MgAgSb基合金的热电输运性能优化[J]. 无机材料学报, 2025, 40(9): 997-1004.
[3]	缪鹏程, 王丽君, 沈紫怡, 黄莉, 袁宁一, 丁建宁. 微球状Ag₂Se的溶剂热合成及其热电性能研究[J]. 无机材料学报, 2025, 40(12): 1373-1378.
[4]	郑元顺, 余健, 叶先峰, 梁栋, 朱婉婷, 聂晓蕾, 魏平, 赵文俞, 张清杰. V取代Al位提升全赫斯勒合金Fe₂VAl的热电性能[J]. 无机材料学报, 2025, 40(12): 1425-1432.
[5]	吴明轩, 李珺杰, 陈硕, 鄢永高, 苏贤礼, 张清杰, 唐新峰. 区熔n型Bi_1.96Sb_0.04Te_2.70Se_0.30热电材料均匀性研究[J]. 无机材料学报, 2025, 40(11): 1252-1260.
[6]	汪波, 余健, 李存成, 聂晓蕾, 朱婉婷, 魏平, 赵文俞, 张清杰. Gd/Bi_0.5Sb_1.5Te₃热电磁梯度复合材料的服役稳定性[J]. 无机材料学报, 2023, 38(6): 663-670.
[7]	贺丹琪, 魏明旭, 刘蕤之, 汤志鑫, 翟鹏程, 赵文俞. 一步法制备重费米子YbAl₃热电材料及其性能提升[J]. 无机材料学报, 2023, 38(5): 577-582.
[8]	林思琪, 李艾燃, 付晨光, 李荣斌, 金敏. Zintl相Mg₃X₂(X=Sb, Bi)基晶体生长及热电性能研究进展[J]. 无机材料学报, 2023, 38(3): 270-279.
[9]	鲁志强, 刘可可, 李强, 胡芹, 冯利萍, 张清杰, 吴劲松, 苏贤礼, 唐新峰. p型多晶Bi_0.5Sb_1.5Te₃合金类施主效应与热电性能[J]. 无机材料学报, 2023, 38(11): 1331-1337.
[10]	江润璐, 吴鑫, 郭昊骋, 郑琦, 王连军, 江莞. UiO-67基导电复合材料的制备及其热电性能研究[J]. 无机材料学报, 2023, 38(11): 1338-1344.
[11]	程成, 李建波, 田震, 王鹏将, 康慧君, 王同敏. In₂O₃/InNbO₄复合材料的热电性能研究[J]. 无机材料学报, 2022, 37(7): 724-730.
[12]	刘丹, 赵亚欣, 郭锐, 刘艳涛, 张志东, 张增星, 薛晨阳. 退火条件对磁控溅射MgO-Ag₃Sb-Sb₂O₄柔性薄膜热电性能的影响[J]. 无机材料学报, 2022, 37(12): 1302-1310.
[13]	任培安, 汪聪, 訾鹏, 陶奇睿, 苏贤礼, 唐新峰. Te与In共掺杂对Cu₂SnSe₃热电性能的影响[J]. 无机材料学报, 2022, 37(10): 1079-1086.
[14]	逯旭, 侯绩翀, 张强, 樊建锋, 陈少平, 王晓敏. Mg含量对Mg₃₍₁₊_z₎Sb₂化合物热电传输性能的影响[J]. 无机材料学报, 2021, 36(8): 835-840.
[15]	董康佳, 姜晨, 任绍彬, 郎小虎, 高睿, 叶卉. 砷化镓晶体力学特性的各向异性计算[J]. 无机材料学报, 2021, 36(6): 645-651.

超声化学结合放电等离子烧结制备In₄Se₃化合物的热电性能研究

Thermoelectric Properties of In₄Se₃ Synthesized by Combing Sonochemical and SPS Method

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 13

相关文章 15

编辑推荐

Metrics

本文评价