无机材料学报

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ZrSiO4/Al2O3制备氧化锆-莫来石复相陶瓷的反应烧结机制

赵世柯; 黄校先; 郭景坤   

  1. 中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室, 上海 200050
  • 收稿日期:1999-12-06 修回日期:2000-01-11 出版日期:2000-12-20 网络出版日期:2000-12-20

Reaction-Sintering Mechanisms of Zirconia-Mullite Multiphase Ceramics Prepared from ZrSiO4/α-AlO3 Mixtures

ZHAO Shi-Ke; HUANG Xiao-Xian; GUO Jing-Kun   

  1. State Key Lab of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:1999-12-06 Revised:2000-01-11 Published:2000-12-20 Online:2000-12-20

摘要: 以ZrSiO和α-Al为原料,采用反应烧结方法制备了氧化锆-莫来石复相陶瓷 材料.研究了反应烧结过程中致密化和莫来石的形成机制,重点讨论了莫来石晶种的引入对莫 来石形成机制的影响.结果表明,在莫来石形成之前,非晶态的粘滞性流动是主要的致密化机 制.晶种的添加使莫来石的形成方式发生了变化,对反应烧结有一定促进作用.添加 3wt%晶 种的试样在1600℃保温8h相对密度可达97%左右.

关键词: 反应烧结机制, 莫来石, 氧化锆, 复合材料

Abstract: Mullite-zirconia composites were prepared by reaction-sintering of zircon and α-Al2O3 mixed powders. Densification process as well as formation
mechanism of mullite was studied and discussed, and special attention was paid to the effect of mullite seeding on the reaction-sintering mechanisms. It is
shown that the viscous flow of the non-crystalline may be a dominant densification mechanism prior to the formation of mullite. Mullite seeding has an obvious influence
on the forming way of mullite, and a higher relative density of 97% can be obtained when a small amount of mullite seeds (3wt%) are added.

Key words: reaction-sintering mechanism, mullite, zirconia, composite

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