钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

doi:10.15541/jim20240333

无机材料学报

• 综述 •

钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

朱文杰^1,2,3, 唐璐^1,2,3, 陆继长^1,2,3, 刘江平^1,2,3, 罗永明^2,3,4

1.昆明理工大学环境科学与工程学院,昆明 650500;
2.云南省挥发性有机物污染物控制与资源化利用创新团队,昆明 650500;
3.云南省高校恶臭挥发性有机物控制重点实验室,昆明 650500;
4.昆明理工大学化学工程学院,昆明 650500

收稿日期:2024-07-16 修回日期:2024-09-13
作者简介:朱文杰(1979-), 男, 教授. E-mail: zhuwenjie17@163.com
基金资助:
国家自然科学基金项目(22166021); 云南省科技厅科技计划项目(202302AG050002-1); 云南省中青年学术与技术带头人后备人才项目(202405AC350026)

Research Progress in Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides

ZHU Wenjie^1,2,3, TANG Lu^1,2,3, LU Jichang^1,2,3, LIU Jiangping^1,2,3, LUO Yongming^2,3,4

1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China;
2. Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, Kunming 650500, China;
3. Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province, Kunming 650500, China;
4.Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

Received:2024-07-16 Revised:2024-09-13
About author:ZHU Wenjie (1979-), male, professor. E-mail: zhuwenjie17@163.com
Supported by:
National Natural Science Foundation of China (22166021); Science and Technology Plan Project of Yunnan Provincial Science and Technology Department (202302AG050002-1); Yunnan Province Reserve Talent Project for Young and Middle-aged Academic and Technical Leaders (202405AC350026)

摘要/Abstract

摘要： 挥发性有机化合物(VOCs)的控制与去除一直是环境领域的热点问题,催化氧化法因其低温、高效以及副产物无毒害等特点成为去除VOCs最有前景的技术之一。钙钛矿型氧化物(ABO₃)是催化氧化VOCs的高效稳定催化剂。为了提高钙钛矿型催化剂的催化效率,有必要针对性地解剖钙钛矿型氧化物的设计,以满足对不同类型VOCs的去除。系统总结了近年来钙钛矿型氧化物催化氧化VOCs的研究进展。首先介绍了钙钛矿型氧化物在VOCs催化氧化中不同的设计策略,包括形貌调控、A位和B位取代、缺陷工程和负载型钙钛矿催化剂,阐明了钙钛矿型氧化物的催化性能与其材料组成、形貌、表面性质(氧物种、缺陷)和本身性质(氧空位浓度、晶格结构)之间的关系;然后介绍了VOCs催化氧化的反应机制和降解途径,并展望了钙钛矿型氧化物催化剂的合理设计和反应机制研究的前景和挑战。

关键词: 挥发性有机化合物, 钙钛矿型氧化物, 结构设计, 催化氧化, 综述

Abstract: The control and removal of volatile organic compounds (VOCs) have always been critical issues in the environmental field. Catalytic oxidation has emerged as one of the most promising technologies for VOCs removal due to its low operational temperature, high efficiency, and non-toxic by-products. Perovskite oxides (ABO₃) are recognized as efficient and stable catalysts for the catalytic oxidation of VOCs. To enhance the catalytic efficiency of perovskite-based catalysts, it is necessary to systematically analyze and optimize the design of perovskite oxides to meet the specific requirements for the removal of different VOCs. This paper comprehensively reviews recent advances in the catalytic oxidation of VOCs using perovskite oxides. Firstly, various design strategies for perovskite oxides in VOCs catalytic oxidation, including morphology control, A-site and B-site substitution, defect engineering, and supported perovskite catalysts are introduced, giving a close link between the catalytic performance of perovskite oxides and their material composition, morphology, surface properties (oxygen species, defects), and intrinsic properties (oxygen vacancy concentration, lattice structure). The reaction mechanisms and degradation pathways involved in the catalytic oxidation of VOCs are discussed, and the prospects and challenges in the rational design of perovskite oxide catalysts and the exploration of reaction mechanisms are outlined.

Key words: volatile organic compound, perovskite oxide, structure design, catalytic oxidation, review

中图分类号:

O643

朱文杰, 唐璐, 陆继长, 刘江平, 罗永明. 钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展[J]. 无机材料学报, DOI: 10.15541/jim20240333.

ZHU Wenjie, TANG Lu, LU Jichang, LIU Jiangping, LUO Yongming. Research Progress in Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20240333.

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钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

Research Progress in Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides

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