镨掺杂钛酸钙/云母钛荧光效果珠光颜料的制备及其性能研究

doi:10.15541/jim20140149

无机材料学报 ›› 2014, Vol. 29 ›› Issue (12): 1275-1280.DOI: 10.15541/jim20140149 CSTR: 32189.14.10.15541/jim20140149

镨掺杂钛酸钙/云母钛荧光效果珠光颜料的制备及其性能研究

周为明^1,3, 陈庆华^{2, 3}, 柯梅珍¹, 吴楠², 罗永晋^{2, 3}, 张华集¹, 钱庆荣^{2, 3}

(1. 福建师范大学材料科学与工程学院, 福州 350007; 2. 福建师范大学环境科学与工程学院, 福州 350007; 3. 福建省污染控制与资源循环利用重点实验室, 福州 350007)

收稿日期:2014-03-26 修回日期:2014-05-22 出版日期:2014-12-20 网络出版日期:2014-11-20
作者简介:周为明(1988–), 男, 硕士研究生. E-mail: zhouweiming721@126.com
基金资助:
福建省科技厅高校产学研重大项目(2011H6005,2013H6007);福建科技厅重点项目(2012H0018, 2013H0017);福建省自然科学基金(2011J01287)

Preparation and Properties of CaTiO₃:Pr³⁺/TiO₂-mica Fluorescent Pearlescent Pigments

ZHOU Wei-Ming^1,3, CHEN Qing-Hua^{2, 3}, KE Mei-Zhen¹, WU Nan², LUO Yong-Jin^{2, 3}, ZHANG Hua-Ji¹, QIAN Qing-Rong^{2, 3}

(1. College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007, China; 2. College of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, China; 3. Fujian Key Laboratory of Pollution Control & Resource Reuse, Fuzhou 350007, China)

Received:2014-03-26 Revised:2014-05-22 Published:2014-12-20 Online:2014-11-20
About author:ZHOU Wei-Ming. E-mail: zhouweiming721@126.com
Supported by:
Fujian Key Project of Industry-University-Research Collaboration (2011H6005, 2013H6007);Key Project of Fujian Science and Technology Agency (2012H0018, 2013H0017);Natural Science Fund of Fujian Province (2011J01287)

摘要/Abstract

摘要：

采用液相沉积法在云母基材表面双层包覆二氧化钛和镨掺杂氢氧化钙, 经高温煅烧在两层之间生成镨掺杂钛酸钙(CaTiO₃:Pr³⁺)荧光层。通过荧光分光光度计、全自动色差计、X射线粉末衍射仪和冷场扫描电子显微镜测试样品的性能。结果表明, 当氧化钙理论包覆率为5.3%、镨浓度相对硝酸钙为0.2mol%、煅烧温度为900℃时, 样品表面均匀、致密, 具有较好的珠光性能和荧光强度, 样品的激发光谱由264、304和380 nm三个激发峰组成, 最大发射波长主峰位于613 nm, 呈红光发射, 对应于Pr³⁺的¹D₂→³H₄跃迁。

关键词: 荧光, 珠光颜料, CaTiO3:Pr3+

Abstract:

Double-layer of titanium dioxide and Pr-doped calcium hydroxide were coated on the surface of mica by liquid phase deposition, and followed by calcination to form the Pr-doped calcium titanates fluorescent layer. The resultant CaTiO₃:Pr³⁺/TiO₂-mica fluorescent pearlescent pigments were characterized by photoluminescence excitation (PLE) and emission (PL), automatic colorimeter (AC), X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM), respectively. The fluorescent pearlescent pigments obtained at the calcium oxide cladding ratios of 5.3%, the praseodymium/calcium nitrate molar concentration of 0.2%, and the calcinations temperature of 900 ℃, show good pearl property with homogeneous, dense and smooth surface, and relatively high fluorescence intensity. The excitation spectrum of these fluorescent pearlescent pigments consists of three bands at 264, 304 and 380 nm. The maximum emission wavelength is found to be a red light of 613 nm, corresponding to the transition for ¹D₂→³H₄.

Key words: fluorescent, pearlescent pigments, CaTiO3:Pr3+

中图分类号:

TQ626

周为明, 陈庆华, 柯梅珍, 吴楠, 罗永晋, 张华集, 钱庆荣. 镨掺杂钛酸钙/云母钛荧光效果珠光颜料的制备及其性能研究[J]. 无机材料学报, 2014, 29(12): 1275-1280.

ZHOU Wei-Ming, CHEN Qing-Hua, KE Mei-Zhen, WU Nan, LUO Yong-Jin, ZHANG Hua-Ji, QIAN Qing-Rong. Preparation and Properties of CaTiO₃:Pr³⁺/TiO₂-mica Fluorescent Pearlescent Pigments[J]. Journal of Inorganic Materials, 2014, 29(12): 1275-1280.

图/表 8

图1 不同理论包覆率样品的发射光谱及其相对荧光强度(插图)

Fig. 1 PL spectra and relative fluorescence intensity of samples with various cladding ratios (inset)

图2 不同理论包覆率样品的明度和饱和度

Fig. 2 The brightness and degree of saturation of samples with various cladding ratio

图3 不同煅烧温度样品的XRD图谱

Fig. 3 XRD patterns of samples calcined at various temperatures

图4 不同煅烧温度所制样品的发射光谱和相对荧光强度 (插图)

Fig. 4 PL spectra and relative fluorescence intensity (inset) of samples calcined at various temperatures

图5 不同镨浓度样品的激发光谱(a)和发射光谱(b)

Fig. 5 PLE (a) and PL (b) spectra of samples with various praseodymium molar concentrations of calcium nitrate

图6 荧光效果珠光颜料SEM照片

Fig. 6 SEM images of fluorescent pearlescent pigments (a) mica, (b) TiO2-mica pearlescent pigments, (c) fluorescent pearlescent pigments, (d) fracture surface of fluorescent pearlescent pigments

图7 云母钛珠光颜料和样品的激光粒径分布图

Fig. 7 Laser particle size distribution of TiO2-mica pearlescent pigments and sample

图8 样品在自然光(a)和254 nm紫外光(b)下的照片

Fig. 8 Images of samples under bright light (a) and 254 nm UV (b)

参考文献 26

[1]	WANG XIAN-XIANG, ZHANG XIAN-JUN. Advances in the research of mica pearlescent pigment. Journal of Southwest China Normal University (Natural Science), 2002, 27(3): 368-371.
[2]	ZHONG SHENG-WEN, KUANG JING-ZHONG, YUE XUE-JIN, et al. New progress and preparation methods for pearlescent pigment. China Tungsten Industry, 2001, 16(4): 33-36.
[3]	EDWIN B F, RUSSELL I S. High Performance Pigments. Wiley-VCH, 2009: 75-101.
[4]	ZHANG QING-XUN, JIN ZHEN-XING, ZHAO MIN, et al. Preparation of colour lustroes pigments by TiO2-coated mica flakes with other metal oxides filling. Journal of Jinzhou Teachers College, 2000, 21(4): 18-19.
[5]	LI ZHEN-RONG, KONG YU-XIA, SHAO JUN-JIE, et al. preparation of coloring mica nacreous pigment by double-covering method. Chemical Industry and Engineering, 2011, 28(1): 43-47.
[6]	LI YUN-TAO, LI RAN. Preparation of the nacreous pigment of mica titanium was prepared by liquid phase deposition (LPD). Journal of Shanxi University of Science & Technology, 2010, 28(4): 16-20.
[7]	PFAFF GERHARD, DIETZ JOHANN, SCHOEN SABINE, et al. Effect pigments. US: 7691196, 2010-4-6.
[8]	荣建丰.云母钛珠光颜料的荧光修饰. 唐山: 河北理工大学硕士论文, 2009.
[9]	高惠民.云母颜料制备及其机理研究. 武汉: 武汉理工大学博士论文, 2010.
[10]	LI XIU-YING, LIAN SHI-XUN, ZHU AI-LING, et al. Comparation study on the red long-lasting phosphorescence of titanates doped with Pr3+. Journal of Natural Sxience of Hunan Normal University, 2005, 28(1): 48-51.
[11]	CHEN RUI, SONG FENG-LAN, CHEN DONG-HUA, et al. Improvement of the luminescence properties of CaTiO3: Pr obtained by modified solid-state reaction. Powder Technology, 2009, 194(3): 252-255.
[12]	PINEL ERIC, BOUTINAUD PHILIPPE, BERTRAND GENEVIÈVE, et al. Preparation and characterization of luminescent films of Pr3+-doped CaTiO3 processed by Sol-Gel technique. Journal of Alloys and Compounds, 2004, 374(1): 202-206.
[13]	TAN SHU-YUAN, YANG PIAOO-PING, LI CHUN-XIA, et al. Preparation, characterization and luminescent properties of spherical CaTiO3: Pr3+ phosphors by spray pyrolysis. Solid State Sciences., 2010, 12(4): 624-629.
[14]	SARAKHA LUDOVIC, BEGOU THOMAS, GOULLET ANTOINE, et al. Influence of synthesis conditions on optical and electrical properties of CaTiO3:Pr3+ thin films deposited by radiofrequency sputtering for electroluminescent device. Surface and Coatings Technology, 2011, 205: S250-S253.
[15]	XU YING, QIAO HUI, WU LI-FENG. Comparison of dispersion and heat tolerance of several fluorescent pigments in plastic. Engineering Plastics Application, 2008, 36(1): 51-54.
[16]	PARVAIZ M RAHAIL, MOHANTY SMITA, NAYAK SANJAY K, et al. Polyetheretherketone composites reinforced with surface modified mica. Polymer Composites, 2010, 31(12): 2121-2128.
[17]	徐扬群.珠光颜料的制造加工与应用. 北京: 化学工业出版社, 2005: 198-199.
[18]	YANG ZHI-PING, GUO ZHI, WANG WEN-JIE, et al. Effect of Pr3+ molar ratio CaTiO3: Pr3+ red phosphor. Journal of Functional Materials and Devices, 2003, 9(4): 473-476.
[19]	SREERAM KALARICAL JANARDHANAN, ABY CHERUVAT,HOOR POULOSE, et al. Colored cool colorants based on rare earth metal ions. Solar Energy Materials and Solar Cells, 2008, 92(11): 1462-1467.
[20]	PENG CHONG, HOU ZHI-YAO, ZHANG CUI-MIAO, et al. Synthesis and luminescent properties of CaTiO3- Pr3+ microfibers prepared by electrospinning method. Optics Express, 2010, 18(7): 7543-7553.
[21]	DIALLO P T, JEANLOUIS K, BOUTINAUD P.Improvement of the optical performances of Pr3+ in CaTiO3. Journal of Alloys and Compounds, 2001, 323: 218-222.
[22]	YIN SHENG-YU, CHEN DONG-HUA, TANG WAN-JUN, et al. Synthesis of CaTiO3: Pr, Al phosphors by Sol-Gel method and their luminescence properties. Journal of Materials Science, 2007, 42(8): 2886-2890.
[23]	DIALLO P T, BOUTINAUD P, MAHIOU R, et al.Red luminescence in Pr3+-doped calcium titanates. Physica Status Solidi, 1997, 160(1): 255-263.
[24]	JIA W, JIA D, RODRIGUEZ T, et al. UV excitation and trapping centers in CaTiO3:Pr3+. Journal of Luminescence, 2006, 119-120: 13-18.
[25]	DING DI, WANG HON G-ZHI, LI YAO-GANG, et al. Synthesis and luminescence properties of La3Si8O4N11:Ln (Ln=Ce3+, Sm3+) nanofibers via electrospinning. Journal of Inorganic Materials, 2013, 28(8): 885-890.
[26]	JING XIAO-MING, LIAO RONG, CEN GUI-LI, et al. Preparation of mica iron pearlite paints with metallic lustre. Journal of Southwest University for Nationalities (Natural Science Edition), 2002, 28(3): 310-313.

镨掺杂钛酸钙/云母钛荧光效果珠光颜料的制备及其性能研究

Preparation and Properties of CaTiO₃:Pr³⁺/TiO₂-mica Fluorescent Pearlescent Pigments

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 26

相关文章 15

编辑推荐

Metrics

本文评价

[1]	汤新丽, 丁自友, 陈俊锐, 赵刚, 韩颖超. 基于稀土铕离子荧光标记的磷酸钙纳米材料体内分布与代谢研究[J]. 无机材料学报, 2025, 40(7): 754-764.
[2]	范小暄, 郑永炅, 徐丽荣, 姚子敏, 曹硕, 王可心, 王绩伟. 基于富氧空位LiYScGeO₄: Bi³⁺长余辉光催化剂的自激活余辉驱动有机污染物芬顿降解[J]. 无机材料学报, 2025, 40(5): 481-488.
[3]	海热古·吐逊, 郭乐, 丁嘉仪, 周嘉琪, 张学良, 努尔尼沙·阿力甫. 上转换荧光探针辅助的光学成像技术在肿瘤显影中的应用研究进展[J]. 无机材料学报, 2025, 40(2): 145-158.
[4]	陈甲, 范依然, 闫文馨, 韩颖超. 聚丙烯酸-钙(铈)纳米团簇荧光探针用于无机磷定量检测研究[J]. 无机材料学报, 2024, 39(9): 1053-1062.
[5]	史瑞, 刘伟, 李林, 李欢, 张志军, 饶光辉, 赵景泰. BaSrGa₄O₈: Tb³⁺力致发光材料的制备及性能[J]. 无机材料学报, 2024, 39(10): 1107-1113.
[6]	杨颖康, 邵怡晴, 李柏良, 吕志伟, 王路路, 王亮君, 曹逊, 吴宇宁, 黄荣, 杨长. Cl掺杂对CuI薄膜发光性能增强研究[J]. 无机材料学报, 2023, 38(6): 687-692.
[7]	杨佳雪, 李雯, 王燕, 朱昭捷, 游振宇, 李坚富, 涂朝阳. Dy³⁺: Y₃Al₅O₁₂晶体的光谱与黄色激光性能[J]. 无机材料学报, 2023, 38(3): 350-356.
[8]	钱新宇, 王无敌, 宋青松, 董永军, 薛艳艳, 张晨波, 王庆国, 徐晓东, 唐慧丽, 曹桂新, 徐军. 0.6%Pr, x%La:CaF₂的发光性能研究和Judd-Ofelt分析[J]. 无机材料学报, 2023, 38(3): 357-362.
[9]	杜邱静, 刘天智, 陈菊锋, 陈航榕. 普鲁士蓝基HClO荧光纳米探针及其对肿瘤细胞的特异性检测[J]. 无机材料学报, 2023, 38(1): 55-61.
[10]	陆晨辉, 葛万银, 宋盼盼, 张盼锋, 徐美美, 张伟. 用于白光LED稀土Eu掺杂SiAlON基荧光粉的发光性能[J]. 无机材料学报, 2023, 38(1): 97-104.
[11]	邓陶丽, 陈河莘, 黑玲丽, 李淑星, 解荣军. 第二相引入荧光转换材料实现激光驱动高均匀性白光光源[J]. 无机材料学报, 2022, 37(8): 891-896.
[12]	关旭峰, 李桂芳, 卫云鸽. Na_1-_xM_xCaEu(WO₄)₃ (M=Li, K)红色荧光粉的微观结构与热猝灭特性研究[J]. 无机材料学报, 2022, 37(6): 676-682.
[13]	李琪, 黄羿, 钱滨, 许贝贝, 陈莉英, 肖文戈, 邱建荣. 橙黄光玻璃陶瓷的光固化成型与无压烧结[J]. 无机材料学报, 2022, 37(3): 289-296.
[14]	张枫娟, 韩博宁, 曾海波. 钙钛矿量子点光伏与荧光聚光电池: 现状与挑战[J]. 无机材料学报, 2022, 37(2): 117-128.
[15]	彭星淋, 李淑星, 刘泽华, 姚秀敏, 解荣军, 黄政仁, 刘学建. 大功率固态照明用荧光陶瓷研究进展[J]. 无机材料学报, 2021, 36(8): 807-819.

镨掺杂钛酸钙/云母钛荧光效果珠光颜料的制备及其性能研究

Preparation and Properties of CaTiO3:Pr3+/TiO2-mica Fluorescent Pearlescent Pigments

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 26

相关文章 15

编辑推荐

Metrics

本文评价

Preparation and Properties of CaTiO₃:Pr³⁺/TiO₂-mica Fluorescent Pearlescent Pigments