复合添加剂的共沉淀法制备及ZnO压敏陶瓷研究

doi:10.3724/SP.J.1077.2012.12105

无机材料学报 ›› 2012, Vol. 27 ›› Issue (12): 1277-1282.DOI: 10.3724/SP.J.1077.2012.12105 CSTR: 32189.14.SP.J.1077.2012.12105

复合添加剂的共沉淀法制备及ZnO压敏陶瓷研究

陈培荣^1,2, 季幼章², 杨晴³

(1. 安徽农业大学理学院, 合肥230036; 2. 中国科学院等离子体物理研究所, 合肥 230031; 3. 中国科学技术大学化学与材料科学学院, 合肥230026)

收稿日期:2012-02-22 修回日期:2012-05-26 出版日期:2012-12-20 网络出版日期:2012-11-19
作者简介:陈培荣(1964–), 男, 博士, 副教授. E-mail: chenpeirong@ahau.edu.cn
基金资助:
国家自然科学基金(21071136); 安徽省教育厅自然科学重大项目(KJ2012ZD11)

Preparation of Composite Additives Powder by Coprecipitation Method and Investgation of ZnO Varistor Ceramics

CHEN Pei-Rong^1,2, JI You-Zhang², YANG Qing³

(1. School of Science, Anhui Agricultural University, Hefei 230036, China; 2. Institute of Plasama Physics, Chinese Academy of Sciences, Hefei 230031, China; 3. School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China)

Received:2012-02-22 Revised:2012-05-26 Published:2012-12-20 Online:2012-11-19
About author:CHEN Pei-Rong. E-mail: chenpeirong@ahau.edu.cn
Supported by:
National Natural Science Foundation of China (21071136); Natural Science Foundation of Anhui Provincial Education Department (KJ2012ZD11)

摘要/Abstract

摘要： 采用共沉淀法合成的复合添加剂粉体制备ZnO压敏陶瓷,用TG-DTA热分析沉淀物前驱体, 通过XRD、SEM、EDS和DLS表征复合粉体的物相、形貌、组成元素、粒度及其分布, 测试压敏陶瓷性能、并观察其结构.结果表明, 550℃煅烧前驱体生成各添加剂氧化物的混合物; 650℃煅烧1 h形成组成为(Bi_1.14Co_0.26Mn_0.29)(Sb_1.14Cr_0.57Ni_0.29)O_6.25焦绿石型复合添加剂粉体, 复合粉体平均粒径为0.26 μm; 复合粉体制备的ZnO压敏陶瓷的电位梯度为330 V/mm、非线性系数为47、漏电流为5 μA/cm², 电性能参数分别优于固相法混合添加剂粉体制备的压敏陶瓷, 这归因于复合粉体制备的压敏陶瓷具有更均匀的显微结构.

关键词: ZnO压敏陶瓷, 焦绿石, 复合粉体, 添加剂, 共沉淀

Abstract: ZnO varistor ceramic was prepared from composite additives powder synthesized by coprecipitation method. The coprecipitate precursor was investigated by thermogravimetric and differential thermal analysis. Phase formation, morphologies, component elements and particle size distribution of the obtained powder were characterized by X-ray diffraction, scanning electron microscope, energy dispersive X-ray spectroscope and dynamic laser scattering. Electrical properties of the prepared ZnO varistor ceramics were measured, then microstructure features of the ceramics were also observed. The results show that the mixture powder of each additive oxide is obtained by calcination of the precursor at 550℃, while the composite additives powder with pyrochlore-type composition of (Bi_1.14Co_0.26Mn_0.29)(Sb_1.14Cr_0.57Ni_0.29)O_6.25 and average particle size of 0.26 μm is achieved at 650℃ for 1 h. ZnO varistor ceramic prepared from the resulted composite additives powder exhibits a higher breakdown voltage (E_b=330 V/mm), a higher nonlinearity coefficient (α=47) and a lower leakage current (I_L=5 μA/cm²) than that prepared from conventional mixed oxide powder. The improvement in electrical properties is attributed to the more uniform microstructure.

Key words: ZnO varistor, pyrochlore, composite powder, additives, coprecipitation

中图分类号:

TQ135
TB321

陈培荣, 季幼章, 杨晴. 复合添加剂的共沉淀法制备及ZnO压敏陶瓷研究[J]. 无机材料学报, 2012, 27(12): 1277-1282.

CHEN Pei-Rong, JI You-Zhang, YANG Qing. Preparation of Composite Additives Powder by Coprecipitation Method and Investgation of ZnO Varistor Ceramics[J]. Journal of Inorganic Materials, 2012, 27(12): 1277-1282.

参考文献

[1] Levison L M, Philipp H R. ZnO varistor–a review. American Ceramic Society Bulletin, 1986, 65(4): 639–646.

[2] Gupta T K. Application of zinc oxide varistors. Journal of the American Ceramic Society, 1990, 73(7): 1817–1840.

[3] Gupta T K, Miller A C. Improved stability of ZnO varistor via donor and acceptor doping at the grain boundary. Journal of Materials Research, 1988, 3(4): 745–754.

[4] WANG Lan-Yi, XU Zheng-Kui, TANG Guo-Yi. The development trends of ZnO varistor ceramic powders. Journal of Functional Materials, 2008, 39(8): 1237–1241.

[5] 王振林, 李盛涛. 氧化锌压敏陶瓷制造及应用. 北京: 科学出版社, 2009: 199–276.

[6] Milo?evi? O, Uskokovi? D, Karanovi?, L J, et al. Synthesis of ZnO-based varistor precursor powders by means of the reaction spray process. Journal of Materials Science, 1993, 28(19): 5211–5217.

[7] LIU Su-Qin, HUANG Ke-Long, SONG Zhi-Fang, et al. Preparation of rare earth oxide doped ZnO varistor by Sol-Gel and its electrical properties. Journal of Inorganic Materials, 2000, 15(2): 376–380.

[8] Zhang J C, Cao S X, Zhang R Y, et al. Effect of fabrication conditions on I-V properties for ZnO varistor with high concentration additives by Sol-Gel technique. Current Applied Physics, 2005, 5(4): 381–386.

[9] PENG Zhong-Dong, YANG Jian-Hong, ZOU Zhong, et al. Thermodynamic analysis on preparing doped zinc oxide varistor ceramic powders by coprecipitation process. Journal of Inorganic Materials, 1999, 14(5): 733–738.

[10] YUAN Fang-Li, LING Yuan-Bing, LI Jin-Lin, et al. ZnO varistors prepared by chemical coprecipitation powders. Journal of Inorganic Materials, 1998, 13(2): 171–175.

[11] Banerjee A, Ramamohan T R, Patni M J. Smart technique for fabrication of zinc oxide varistor. Materials Research Bulletin, 2001, 36(7): 1259–1267.

[12] Toplan H O, Karakas Y. Processing and phase evolution in low voltage varistor prepared by chemical processing. Ceramics International, 2001, 27(7): 761–765.

[13] Wang M H, Yao C, Zhang N F. Degradation characteristics of low-voltage ZnO varistor manufactured by chemical coprecipitation processing. Journal of Materals Processing Technology, 2008, 202(1): 406–411.

[14] Cheng L H, Li G R, Zheng L Y, et al. Analysis of high-voltage ZnO varistor prepared from a novel chemically aided method. Journal of American Ceramic Society, 2010, 93(9): 2522–2525.

[15] XIE Jian-Jun, SHI Ying, HU Yao-Ming, et al. Synthesis study of Lu3Al5O12(Ce) nanoscaled powder by coprecipitation. Journal of Inorganic Materials, 2009, 24(1): 79–82.

[16] ZHANG Hong, ZHANG Zhe, MA Guo-Qiang, et al. Coprecipitation synthesis and oxide ionic conductivities of Ce0.8Sm0.2O1.9-based nanocomposite materials. Journal of Inorganic Materials, 2009, 24(3): 353–356.

[17] YANG Yu-Ling, LI Xue-Ming, FENG Wen-Lin, et al. Synthesis and characteristic of CaMoO4:Eu3+ red phosphor for W-LED by coprecipitation. Journal of Inorganic Materials, 2010, 25(10): 1015–1019.

[18] YANG Yan, LI Sheng-Tao. CaCu3Ti4O12 ceramics prepared by coprecipitation method. Journal of Inorganic Materials, 2010, 25(8): 835–839.

[19] SHI Ying, CHEN Qi-Wei, SHI Jian-Lin. Effect of precipitants on morphologies of Lu2O3 phospors by coprecipitation process. Journal of Inorganic Materials, 2008, 23(4): 824–828.

[20] Subasri R, Asha M, Hembram K, et al. Microwave sintering of doped nanocrystalline ZnO and characterization for varistor applications. Materials Chemistry and Physics, 2009, 115(2): 677–684.

[21] Anas S, Mangalaraja R V, Poothayal M, et al. Direct synthesis of varistor-grade doped nanocrystalline ZnO and its densification through a step-sintering technique. Acta Materials, 2007, 55(17): 5792–5801.

[22] WAN Shuai, L? Wen-Zhong. Electrical properties and kinetic of crystalline grain growth of low-voltage ZnO varistor doped with Zn-B glass. Journal of Inorganic Materials, 2010, 25(2): 151–156.

复合添加剂的共沉淀法制备及ZnO压敏陶瓷研究

Preparation of Composite Additives Powder by Coprecipitation Method and Investgation of ZnO Varistor Ceramics

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈甜, 罗媛, 朱刘, 郭学益, 杨英. 有机-无机共添加增强柔性钙钛矿太阳能电池机械弯曲及环境稳定性能[J]. 无机材料学报, 2024, 39(5): 477-484.
[2]	王马超, 唐扬敏, 邓明雪, 周真真, 刘小峰, 王家成, 刘茜. 共沉淀法制备Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺双钙钛矿及其近红外发光性能[J]. 无机材料学报, 2023, 38(9): 1083-1088.
[3]	江依义, 沈旻, 宋半夏, 李南, 丁祥欢, 郭乐毅, 马国强. 双功能电解液添加剂对锂离子电池高温高电压性能的影响[J]. 无机材料学报, 2022, 37(7): 710-716.
[4]	付宇坤, 曾敏, 饶先发, 钟盛文, 张慧娟, 姚文俐. 锂离子电池高镍LiNi_0.8Mn_0.2O₂正极材料的微波合成及其Co、Al共改性[J]. 无机材料学报, 2021, 36(7): 718-724.
[5]	刘雯雯, 胡志蕾, 王立, 曹梦莎, 张晶, 张婧, 张帅, 袁宁一, 丁建宁. L-3-(4-吡啶基)-丙氨酸钝化钙钛矿太阳电池界面缺陷[J]. 无机材料学报, 2021, 36(6): 629-636.
[6]	郭猛, 张丰年, 苗洋, 刘宇峰, 郁军, 高峰. La(Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2)O₃钙钛矿高熵陶瓷粉体的制备及其电学性能[J]. 无机材料学报, 2021, 36(4): 431-435.
[7]	刘子玉, TOCI Guido, PIRRI Angela, PATRIZI Barbara, 冯亚刚, 陈肖朴, 胡殿君, 田丰, 吴乐翔, VANNINIMatteo, 李江. 固体激光用Nd:Lu₂O₃透明陶瓷的制备和光学性能研究[J]. 无机材料学报, 2021, 36(2): 210-216.
[8]	黄新友, 刘玉敏, 刘洋, 李晓英, 冯亚刚, 陈肖朴, 陈鹏辉, 刘欣, 谢腾飞, 李江. 醇水共沉淀法制备Yb:YAG透明陶瓷及其性能研究[J]. 无机材料学报, 2021, 36(2): 217-224.
[9]	李晓英, 刘强, 胡泽望, 姜楠, 石云, 李江. 碳酸氢铵与金属阳离子摩尔比对共沉淀法合成铽镓石榴石纳米粉体及陶瓷性能的影响[J]. 无机材料学报, 2019, 34(7): 791-797.
[10]	韦家蓓, TOCIGuido, PIRRIAngela, PATRIZIBarbara, 冯亚刚, VANNINIMatteo, 李江. 共沉淀纳米粉体制备Yb:CaF₂激光陶瓷及其性能研究[J]. 无机材料学报, 2019, 34(12): 1341-1348.
[11]	熊浩, 张渤昕, 贾巍, 张青红, 谢华清. 高分子PVP添加剂对钙钛矿太阳电池稳定性的提升[J]. 无机材料学报, 2019, 34(1): 96-102.
[12]	古毓康, 曹磊, 万勇, 高建国. 铝合金基底微碳球作为润滑油添加剂的摩擦学性能及其润滑机理[J]. 无机材料学报, 2017, 32(6): 625-630.
[13]	伍青峰, 崔亚娟, 张海龙, 周怡, 兰丽, 王健礼, 陈耀强. 改进共沉淀法以提高三效催化剂中铈锆复合氧化物的热稳定性[J]. 无机材料学报, 2017, 32(3): 331-336.
[14]	敖昕, 吴相伟, 吴田, 吴梅芬, 温兆银. 工作温度对钠-氯化镍电池正极结构及电化学性能的影响[J]. 无机材料学报, 2017, 32(12): 1243-1249.
[15]	湛菁, 陆二聚, 蔡梦, 马雅琳, 张传福. 棒状多孔NiCo₂O₄粉末的可控制备及其电催化性能研究[J]. 无机材料学报, 2017, 32(1): 11-17.