二维过渡金属硫属化合物氧还原反应催化剂的研究进展

doi:10.15541/jim20220128

无机材料学报 ›› 2022, Vol. 37 ›› Issue (7): 697-709.DOI: 10.15541/jim20220128 CSTR: 32189.14.10.15541/jim20220128

所属专题：【能源环境】燃料电池(202409)；【信息功能】MAX层状材料、MXene及其他二维材料(202409)

• 综述 • 下一篇

二维过渡金属硫属化合物氧还原反应催化剂的研究进展

孙炼(), 顾全超, 杨雅萍, 王洪磊, 余金山, 周新贵()

国防科技大学空天科学学院, 新型陶瓷纤维及其复合材料重点实验室, 长沙 410073

收稿日期:2022-03-08 修回日期:2022-04-12 出版日期:2022-07-20 网络出版日期:2022-04-26
通讯作者: 周新贵, 教授. E-mail: zhouxinguilmy@163.com
作者简介:孙炼(1993-), 男, 博士研究生. E-mail: sunlian12@nudt.edu.cn
基金资助:
国家重点研发计划(2018YFB1900603)

Two-dimensional Transition Metal Dichalcogenides for Electrocatalytic Oxygen Reduction Reaction

SUN Lian(), GU Quanchao, YANG Yaping, WANG Honglei, YU Jinshan, ZHOU Xingui()

Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China

Received:2022-03-08 Revised:2022-04-12 Published:2022-07-20 Online:2022-04-26
Contact: ZHOU Xingui, professor. E-mail: zhouxinguilmy@163.com
About author:SUN Lian (1993-), male, PhD candidate. E-mail: sunlian12@nudt.edu.cn
Supported by:
National Key R&D Plan(2018YFB1900603)

摘要/Abstract

摘要：

氧还原(ORR)反应是燃料电池等清洁能源阴极的关键反应, 其反应动力学复杂, 阴极需使用Pt等贵金属催化剂。然而Pt价格昂贵, 且载体炭黑在高电位环境下稳定性欠佳, 导致电池部件成本高且寿命短。二维过渡金属硫属化合物(2D TMDs)具有高比表面积与可调节的电学性能, 且稳定性强, 有望在维持活性的同时提高燃料电池阴极的耐久性。本文梳理了近年来2D TMDs在ORR催化剂领域的最新研究进展: 首先概述了2D TMDs的结构、性质及ORR反应机理; 其次分析了调控2D TMDs的ORR性能策略, 包括异质元素掺杂、相转变、缺陷工程与应力工程等, 介绍了2D TMDs基异质结构对ORR性能的提升作用; 最后, 针对该领域目前存在的挑战进行展望与总结。

关键词: 氧还原反应, 二维材料, 过渡金属硫属化合物, 电催化, 综述

Abstract:

Oxygen reduction reaction (ORR) is the key reaction in cathode for fuel cells. Because of the sluggish kinetics, platinum (Pt) is widely used as the electrocatalysts for ORR. However, the high cost of Pt and poor stability of carbon black support under high voltage limit the commercialization and durability of fuel cells. Two-dimensional transition metal dichalcogenides (2D TMDs) possess large specific area, tunable electronic structure, and high chemical stability, making them a good candidate for ORR catalysts with high activity and durability. This paper reviews the recent progress of 2D TMDs-based ORR electrocatalysts. First, crystal structure, electronic properties, and ORR reaction mechanism are briefly introduced. Then some strategies for adjusting ORR performance of 2D TMDs are summarized, including heteroatom doping, phase conversion, defect engineering, and strain engineering. Meanwhile, the ORR activity enhancement arising from 2D TMDs-based heterostructures is also analyzed. Finally, perspectives are given for current issues and their possible solutions.

Key words: oxygen reduction reaction, two-dimensional material, transition metal dichalcogenide, electrocatalysis, review

中图分类号:

O614

孙炼, 顾全超, 杨雅萍, 王洪磊, 余金山, 周新贵. 二维过渡金属硫属化合物氧还原反应催化剂的研究进展[J]. 无机材料学报, 2022, 37(7): 697-709.

SUN Lian, GU Quanchao, YANG Yaping, WANG Honglei, YU Jinshan, ZHOU Xingui. Two-dimensional Transition Metal Dichalcogenides for Electrocatalytic Oxygen Reduction Reaction[J]. Journal of Inorganic Materials, 2022, 37(7): 697-709.

图/表 11

图1 2D TMDs的结构与晶型

Fig. 1 Structures and crystal forms of 2D TMDs

图2 (a) 块体结构MoS2, (b) 三层结构MoS2, (c) 双层结构MoS2与(d) 单层结构MoS2经过计算后得到的带隙[26]

Fig. 2 Calculated band structures of (a) bulk MoS2, (b) quadrilayer MoS2, (c) bilayer MoS2, and (d) monolayer MoS2[26]

图3 ORR催化剂的设计理论[3,41]

Fig. 3 Designing strategy for ORR catalysts[3,41] (a) ORR mechanism with blue arrow representing dissociative mechanism, red arrows representing associative mechanism, and purple arrows representing the parts involving both mechanisms[3]; (b) “Volcano plots” showing relationship between oxygen binding energy and maximal activity[41] Colorful figures are available on website

表1 典型2D TMDs层状结构ORR催化剂的性能

Table 1 Properties of typical 2D TMDs-based ORR catalysts

Catalyst	Electrolyte	Onset potential / V (vs. RHE)	Half-wave potential / V (vs. RHE)	Electrons transfer number, n	Ref.
P-MoS₂-0.2	0.1 mol·L^-1 KOH	0.96	0.80	3.60	[45]
I-PdSe₂-50	0.1 mol·L^-1 KOH	-	0.76	3.67	[46]
Ag/MoS₂	0.1 mol·L^-1 KOH	0.90	0.83	3.98	[47]
2H+1T-FeSe@NC	1.0 mol·L^-1 KOH	0.97	0.80	3.90	[48]
O-MoS₂-87	0.1 mol·L^-1 KOH	0.94	0.80	3.49	[49]

图4 2D TMDs的M位掺杂[53,55]

Fig. 4 M-position doping for 2D TMDs[53,55] (a) ORR energy barrier for Pt-MoSe2 with insets showing crystal structures[53] ; (b) TEM images of Pt-SAs/2D TMDs prepared by galvanic replacement[55]

图5 2D TMDs的X位掺杂[45,61]

Fig. 5 X-position doping of 2D TMDs[45,61] (a) ORR polarization curves of P-MoS2 in 0.1 mol·L-1 KOH[45]; (b) Corresponding possible reaction mechanism[61]

图6 由2H-MoS2相转变制备1T-MoS2纳米片的(a)示意图及其(b)在0.1 mol·L-1 KOH的ORR极化曲线与(c)K-L曲线[68]

Fig. 6 (a) Preparative schematic illustration by phase conversion from 2H-MoS2, (b) ORR polarization curves in 0.1 mol·L-1 KOH, and (c) corresponding K-L plots of 1T-MoS2[68] Colorful figures are available on website

图7 2D TMDs的缺陷工程与应力工程调控[46,49,65]

Fig. 7 Defect and strain engineering of 2D TMDs[46,49,65] (a) TEM images and (b) O1s XPS spectra of defected I-PdSe2[46]; (c) Schematic illustration of synthesis of O-MoS2 (d) ORR polarization curves in 0.1 mol·L-1 KOH of O-MoS2[49]; (e) AFM (left) and TEM (middle and right) images of 2H-1T WS2 showing the formation of strain[65]

表2 典型2D TMDs异质结构ORR催化剂的性能

Table 2 Properties of typical 2D TMDs heterostructures-based ORR catalysts

Catalyst	Electrolyte	Onset potential / V (vs. RHE)	Half-wave potential / V (vs. RHE)	Electrons transfer number, n	Ref.
Pt/MoS₂-rGO	0.1 mol·L^-1 HClO₄	0.90	0.80	-	[85]
MoS₂-CNT	0.1 mol·L^-1 KOH	0.65	-	~4.00	[86]
MoS₂/S-PC	0.5 mol·L^-1 H₂SO₄	-	0.86	4.00	[87]
Ni₃S₂/MoS₂	0.1 mol·L^-1 KOH	0.95	0.88	3.99	[88]
hBN-MoS₂	0.1 mol·L^-1 KOH	0.80	0.60	4.00	[89]
FePc-MoS₂	0.1 mol·L^-1 KOH	-	0.89	4.00	[90]

图8 2D TMDs@碳材料异质结ORR催化剂[85,92]

Fig. 8 2D TMDs@carbon materials heterostructure ORR catalysts[85,92] (a) TEM images and (b) activity variations of Pt/MoS2-rGO[85]; (c) SEM image and (d) power density of microbial fuel cells based on N-MoS2/C catalysts[92] Colorful figures are available on website

图9 其它2D TMDs基异质结构ORR催化剂[88⇓-90]

Fig. 9 Other 2D TMDs-based heterostructure ORR catalysts[88⇓-90] (a) TEM image of Ni3S2/MoS2 and (b) corresponding ORR polarization curves in 0.1 mol·L-1 KOH[88]; (c) TEM image of hBN/MoS2 and its (d) ORR durability test[89]; (e) Structure of FePc-MoS2 and (f) its integrated partial density of states IPDOS[90]

参考文献 102

[1]	HAO C, LIU Z R, LIU W, et al. Research progress of carbon- supported metal single atom catalysts for oxygen reduction reaction. Journal of Inorganic Materials, 2021, 36(8): 820-834. DOI
[2]	RAHMAN M A, WANG X J, WEN C E. High energy density metal-air batteries: a review. Journal of The Electrochemical Society, 2013, 160(10): A1759-A1771.
[3]	LIU Z Y, ZHAO Z P, PENG B S, et al. Beyond extended surfaces: understanding the oxygen reduction reaction on nanocatalysts. Journal of the American Chemical Society, 2020, 142(42): 17812-17827. DOI URL
[4]	XIANG J, LIU B, LIU B, et al. A self-terminated electrochemical fabrication of electrode pairs with angstrom-sized gaps. Electrochemistry Communications, 2006, 8(4): 577-580. DOI URL
[5]	TIAN X L, ZHAO X, SU Y Q, et al. Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells. Science, 2019, 366(6467): 850-856. DOI URL
[6]	LI M F, ZHAO Z P, CHENG T, et al. Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction. Science, 2016, 354(6318): 1414-1419. DOI URL
[7]	ZENG R R, WANG K, SHAO W, et al. Investigation on the coordination mechanism of Pt-containing species and qualification of the alkaline content during Pt/C preparation via a solvothermal polyol method. Chinese Journal of Catalysis, 2020, 41(5): 820-829. DOI URL
[8]	WANG J J, YIN G P, SHAO Y Y, et al. Effect of carbon black support corrosion on the durability of Pt/C catalyst. Journal of Power Sources, 2007, 171(2): 331-339. DOI URL
[9]	JIMÉNEZ-MORALES I, REYES-CARMONA A, DUPONT M, et al. Correlation between the surface characteristics of carbon supports and their electrochemical stability and performance in fuel cell cathodes. Carbon Energy, 2021, 3(4): 654-665. DOI URL
[10]	KONG F P, SHI W Z, SONG Y J, et al. Surface/near-surface structure of highly active and durable Pt-based catalysts for oxygen reduction reaction: a review. Advanced Energy and Sustainability Research, 2021, 2(7): 2100025.
[11]	JIANG Y F, YANG L J, SUN T, et al. Significant contribution of intrinsic carbon defects to oxygen reduction activity. ACS Catalysis, 2015, 5(11): 6707-6712. DOI URL
[12]	LAI Q X, ZHENG J, TANG Z M, et al. Optimal configuration of N-doped carbon defects in 2D turbostratic carbon nanomesh for advanced oxygen reduction electrocatalysis. Angewandte Chemie International Edition, 2020, 59(29): 11999-12006. DOI URL
[13]	LANG X Y, HAN G F, XIAO B B, et al. Mesostructured intermetallic compounds of platinum and non-transition metals for enhanced electrocatalysis of oxygen reduction reaction. Advanced Functional Materials, 2015, 25(2): 230-237. DOI URL
[14]	NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films. Science, 2004, 306(5696): 666-669. DOI URL
[15]	LI D D, LI T, HAO G Y, et al. IrO₂ nanoparticle-decorated single- layer NiFe LDHs nanosheets with oxygen vacancies for the oxygen evolution reaction. Chemical Engineering Journal, 2020, 399: 125738.
[16]	LI R, WANG S H, CHEN X X, et al. Highly anisotropic and water molecule-dependent proton conductivity in a 2D homochiral copper(II) metal-organic framework. Chemistry of Materials, 2017, 29(5): 2321-2331. DOI URL
[17]	WANG Z T, LI H, YAN S C, et al. Synthesis of a two-dimensional covalent organic framework with the ability of conducting proton along skeleton. Acta Chimica Sinica, 78(1): 63-68. DOI URL
[18]	WANG X, RAGHUPATHY R K M, QUEREBILLO C J, et al. Interfacial covalent bonds regulated electron-deficient 2D black phosphorus for electrocatalytic oxygen reactions. Advanced Materials, 2021, 33(20): 2008752.
[19]	LIN Y, CONNELL J W. Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene. Nanoscale, 2012, 4(22): 6908-6939. DOI URL
[20]	LI Y B, QIN Y Q, CHEN K, et al. Molten salt synthesis of nanolaminated Sc₂SnC MAX phase. Journal of Inorganic Materials, 2021, 36(7): 773-778. DOI URL
[21]	WANG S S, YU Y, ZHANG S Q, et al. Atomic-scale studies of overlapping grain boundaries between parallel and quasi-parallel grains in low-symmetry monolayer ReS₂. Matter, 2020, 3(6): 2108-2123. DOI URL
[22]	DING J H, ZHAO H R, ZHAO X P, et al. How semiconductor transition metal dichalcogenides replaced graphene for enhancing anticorrosion. Journal of Materials Chemistry A, 2019, 7(22): 13511-13521. DOI URL
[23]	ZHU C R, GAO D Q, DING J, et al. TMD-based highly efficient electrocatalysts developed by combined computational and experimental approaches. Chemical Society Reviews, 2018, 47(12): 4332-4356. DOI URL
[24]	XIAO Y, ZHOU M Y, LIU J L, et al. Phase engineering of two- dimensional transition metal dichalcogenides. Science China Materials, 2019, 62(6): 759-775. DOI URL
[25]	LIU D Y, HONG J H, LI X B, et al. Synthesis of 2H-1T′ WS₂-ReS₂ heterophase structures with atomically sharp interface via hydrogen- triggered one-pot growth. Advanced Functional Materials, 2020, 30(16): 1910169.
[26]	SPLENDIANI A, SUN L, ZHANG Y B, et al. Emerging photoluminescence in monolayer MoS₂. Nano Letters, 2010, 10(4): 1271-1275. DOI URL
[27]	BALASUBRAMANYAM S, SHIRAZI M, BLOODGOOD M A, et al. Edge-site nanoengineering of WS₂ by low-temperature plasma- enhanced atomic layer deposition for electrocatalytic hydrogen evolution. Chemistry of Materials, 2019, 31(14): 5104-5115. DOI URL
[28]	SARMA P V, KAYAL A, SHARMA C H, et al. Electrocatalysis on edge-rich spiral WS₂ for hydrogen evolution. ACS Nano, 2019, 13(9): 10448-10455. DOI URL
[29]	LIU J Y, JIANG X, LI X T, et al. Time- and momentum-resolved image-potential states of 2H-MoS₂ surface. Physical Chemistry Chemical Physics, 2021, 23(46): 26336-26342. DOI URL
[30]	JIANG X, ZHENG Q J, LAN Z G, et al. Real-time GW-BSE investigations on spin-valley exciton dynamics in monolayer transition metal dichalcogenide. Science Advances, 7(10): eabf3759. DOI URL
[31]	JING Q H, ZHANG H, HUANG H, et al. Ultrasonic exfoliated ReS₂nanosheets: fabrication and use as co-catalyst for enhancing photocatalytic efficiency of TiO₂ nanoparticles under sunlight. Nanotechnology, 2019, 30(18): 184001.
[32]	LI H, YIN Z Y, HE Q Y, et al. Fabrication of single- and multilayer MoS₂ film-based field-effect transistors for sensing NO at room temperature. Small, 2012, 8(1): 63-67. DOI URL
[33]	ZHANG Q Y, MEI L, CAO X H, et al. Intercalation and exfoliation chemistries of transition metal dichalcogenides. Journal of Materials Chemistry A, 2020, 8(31): 15417-15444. DOI URL
[34]	LI S W, LIU Y C, ZHAO X D, et al. Molecular engineering on MoS₂ enables large interlayers and unlocked basal planes for high- performance aqueous Zn-ion storage. Angewandte Chemie International Edition, 2021, 60(37): 20286-20293. DOI URL
[35]	CHEN X Y, WANG Z M, WEI Y Z, et al. High phase-purity 1T-MoS₂ ultrathin nanosheets by a spatially confined template. Angewandte Chemie International Edition, 2019, 58(49): 17621-17624. DOI URL
[36]	VAN DER ZANDE A M, HUANG P Y, CHENET D A, et al. Grains and grain boundaries in highly crystalline monolayer molybdenum disulphide. Nature Materials, 2013, 12(6): 554-561. DOI URL
[37]	ZHOU J D, LIN J H, HUANG X W, et al. A library of atomically thin metal chalcogenides. Nature, 2018, 556(7701): 355-359. DOI URL
[38]	WANG S S, RONG Y M, FAN Y, et al. Shape evolution of monolayer MoS₂ crystals grown by chemical vapor deposition. Chemistry of Materials, 2014, 26(22): 6371-6379. DOI URL
[39]	ZHANG Y, YAO Y Y, SENDEKU M G, et al. Recent progress in CVD growth of 2D transition metal dichalcogenides and related heterostructures. Advanced Materials, 2019, 31(41): 1901694.
[40]	HUANG H W, LI K, CHEN Z, et al. Achieving remarkable activity and durability toward oxygen reduction reaction based on ultrathin Rh-doped Pt nanowires. Journal of the American Chemical Society, 2017, 139(24): 8152-8159. DOI URL
[41]	NØRSKOV J K, ROSSMEISL J, LOGADOTTIR A, et al. Origin of the overpotential for oxygen reduction at a fuel-cell cathode. The Journal of Physical Chemistry B, 2004, 108(46): 17886-17892. DOI URL
[42]	CUI Y, ZHOU C W, LI X Z, et al. High performance electrocatalysis for hydrogen evolution reaction using nickel-doped CoS₂ nanostructures: experimental and DFT insights. Electrochimica Acta, 2017, 228: 428-435. DOI URL
[43]	WU L F, DZADE N Y, CHEN N, et al. Cu electrodeposition on nanostructured MoS₂ and WS₂and implications for HER active site determination. Journal of The Electrochemical Society, 2020, 167(11): 116517.
[44]	WANG Z W, LI W L, ZHENG Y P, et al. How does the active site in the MoSe₂ surface affect its electrochemical performance as anode material for metal-ion batteries? Applied Surface Science, 2020, 526: 146637.
[45]	HUANG H, FENG X, DU C C, et al. High-quality phosphorus- doped MoS₂ ultrathin nanosheets with amenable ORR catalytic activity. Chemical Communications, 2015, 51(37): 7903-7906. DOI URL
[46]	KOH S W, HU J, HWANG J M, et al. Two-dimensional palladium diselenide for the oxygen reduction reaction. Materials Chemistry Frontiers, 2021, 5(13): 4970-4980. DOI URL
[47]	VATTIKUTI S V P, NAGAJYOTHI P C, DEVARAYAPALLI K C, et al. Hybrid Ag/MoS₂ nanosheets for efficient electrocatalytic oxygen reduction. Applied Surface Science, 2020, 526: 146751.
[48]	CAO Y F, HUANG S C, PENG Z Q, et al. Phase control of ultrafine FeSe nanocrystals in a N-doped carbon matrix for highly efficient and stable oxygen reduction reaction. Journal of Materials Chemistry A, 2021, 9(6): 3464-3471. DOI URL
[49]	HUANG H, FENG X, DU C C, et al. Incorporated oxygen in MoS₂ ultrathin nanosheets for efficient ORR catalysis. Journal of Materials Chemistry A, 2015, 3(31): 16050-16056. DOI URL
[50]	SARKAR D, XIE X J, KANG J H, et al. Functionalization of transition metal dichalcogenides with metallic nanoparticles: implications for doping and gas-sensing. Nano Letters, 2015, 15(5): 2852-2862. DOI URL
[51]	CHEN E, XU W, CHEN J, et al. 2D layered noble metal dichalcogenides (Pt, Pd, Se, S) for electronics and energy applications. Materials Today Advances, 2020, 7: 100076.
[52]	SOLOMON G, KOHAN M G, VAGIN M, et al. Decorating vertically aligned MoS₂ nanoflakes with silver nanoparticles for inducing a bifunctional electrocatalyst towards oxygen evolution and oxygen reduction reaction. Nano Energy, 2021, 81: 105664.
[53]	UPADHYAY S N, PAKHIRA S. Mechanism of electrochemical oxygen reduction reaction at two-dimensional Pt-doped MoSe₂ material: an efficient electrocatalyst. Journal of Materials Chemistry C, 2021, 9(34): 11331-11342. DOI URL
[54]	HWANG J, NOH S H, HAN B. Design of active bifunctional electrocatalysts using single atom doped transition metal dichalcogenides. Applied Surface Science, 2019, 471: 545-552. DOI URL
[55]	SHI Y, MA Z R, XIAO Y Y, et al. Electronic metal-support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction. Nature Communications, 2021, 12(1): 3021. DOI URL
[56]	SHI Y, WANG J, WANG C, et al. Hot electron of Au nanorods activates the electrocatalysis of hydrogen evolution on MoS₂ nanosheets. Journal of the American Chemical Society, 2015, 137(23): 7365-7370. DOI URL
[57]	CHEN Z X, LENG K, ZHAO X X, et al. Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide. Nature Communications, 2017, 8(1): 14548. DOI URL
[58]	QI K, YU S S, WANG Q Y, et al. Decoration of the inert basal plane of defect-rich MoS₂ with Pd atoms for achieving Pt-similar HER activity. Journal of Materials Chemistry A, 2016, 4(11): 4025-4031. DOI URL
[59]	TIAN S F, TANG Q. Activating transition metal dichalcogenide monolayers as efficient electrocatalysts for the oxygen reduction reaction via single atom doping. Journal of Materials Chemistry C, 2021, 9(18): 6040-6050. DOI URL
[60]	ZHANG H Y, TIAN Y, ZHAO J X, et al. Small dopants make big differences: enhanced electrocatalytic performance of MoS₂ monolayer for oxygen reduction reaction (ORR) by N- and P-doping. Electrochimica Acta, 2017, 225: 543-550. DOI URL
[61]	LIU C, DONG H L, JI Y J, et al. Origin of the catalytic activity of phosphorus doped MoS₂ for oxygen reduction reaction (ORR) in alkaline solution: a theoretical study. Scientific Reports, 2018, 8(1): 13292. DOI URL
[62]	WANG H T, TSAI C, KONG D S, et al. Transition-metal doped edge sites in vertically aligned MoS₂ catalysts for enhanced hydrogen evolution. Nano Research, 2015, 8(2): 566-575. DOI URL
[63]	GAO C, RAO D W, YANG H, et al. Dual transition-metal atoms doping: an effective route to promote the ORR and OER activity on MoTe₂. New Journal of Chemistry, 2021, 45(12): 5589-5595. DOI URL
[64]	GONG Y J, YUAN H T, WU C L, et al. Spatially controlled doping of two-dimensional SnS₂ through intercalation for electronics. Nature Nanotechnology, 2018, 13(4): 294-299. DOI URL
[65]	VOIRY D, YAMAGUCHI H, LI J W, et al. Enhanced catalytic activity in strained chemically exfoliated WS₂ nanosheets for hydrogen evolution. Nature Materials, 2013, 12(9): 850-855. DOI URL
[66]	WANG Y Y, WANG M R, LU Z S, et al. Enabling multifunctional electrocatalysts by modifying the basal plane of unifunctional 1T′- MoS₂ with anchored transition metal single atoms. Nanoscale, 2021, 13(31): 13390-13400. DOI URL
[67]	ZHAO B, SHEN D Y, ZHANG Z C, et al. 2D metallic transition- metal dichalcogenides: structures, synthesis, properties, and applications. Advanced Functional Materials, 2021, 31(48): 2105132.
[68]	SADIGHI Z, LIU J P, ZHAO L, et al. Metallic MoS₂ nanosheets: multifunctional electrocatalyst for the ORR, OER and Li-O₂ batteries. Nanoscale, 2018, 10(47): 22549-22559. DOI URL
[69]	LIN Y C, DUMCENCO D O, HUANG Y S, et al. Atomic mechanism of the semiconducting-to-metallic phase transition in single- layered MoS₂. Nature Nanotechnology, 2014, 9(5): 391-396. DOI URL
[70]	LIN Y C, DUMCENCO D O, KOMSA H P, et al. Properties of individual dopant atoms in single-layer MoS₂: atomic structure, migration, and enhanced reactivity. Advanced Materials, 2014, 26(18): 2857-2861. DOI URL
[71]	DING W, HU L, DAI J M, et al. Highly ambient-stable 1T-MoS₂ and 1T-WS₂ by hydrothermal synthesis under high magnetic fields. ACS Nano, 2019, 13(2): 1694-1702.
[72]	PRABHU P, JOSE V, LEE J M. Design strategies for development of TMD-based heterostructures in electrochemical energy systems. Matter, 2020, 2(3): 526-553. DOI URL
[73]	WANG S, ZHANG D, LI B, et al. Ultrastable in-plane 1T-2H MoS₂ heterostructures for enhanced hydrogen evolution reaction. Advanced Energy Materials, 2018, 8(25): 1801345.
[74]	YIN Y, HAN J C, ZHANG Y M, et al. Contributions of phase, sulfur vacancies, and edges to the hydrogen evolution reaction catalytic activity of porous molybdenum disulfide nanosheets. Journal of the American Chemical Society, 2016, 138(25): 7965-7972. DOI URL
[75]	ZHU J, WANG Z C, DAI H, et al. Boundary activated hydrogen evolution reaction on monolayer MoS₂. Nature Communications, 2019, 10(1): 1348. DOI URL
[76]	MENG Y N, GAO Y, LI K, et al. Vacancy-induced oxygen reduction activity in Janus transition metal dichalcogenides. ChemElectroChem, 2020, 7(20): 4233-4238. DOI URL
[77]	YANG J, WANG Z Y, HUANG C X, et al. Compressive strain modulation of single iron sites on helical carbon support boosts electrocatalytic oxygen reduction. Angewandte Chemie International Edition, 2021, 60(42): 22722-22728. DOI URL
[78]	XU X, LIANG T, KONG D, et al. Strain engineering of two- dimensional materials for advanced electrocatalysts. Materials Today Nano, 2021, 14: 100111.
[79]	ZHAO S Y, WANG K, ZOU X L, et al. Group VB transition metal dichalcogenides for oxygen reduction reaction and strain-enhanced activity governed by p-orbital electrons of chalcogen. Nano Research, 2019, 12(4): 925-930. DOI URL
[80]	LI H, CONTRYMAN A W, QIAN X F, et al. Optoelectronic crystal of artificial atoms in strain-textured molybdenum disulphide. Nature Communications, 2015, 6(1): 7381. DOI URL
[81]	TIWARI A P, YOON Y, NOVAK T G, et al. Lattice strain formation through spin-coupled shells of MoS₂ on Mo₂C for bifunctional oxygen reduction and oxygen evolution reaction electrocatalysts. Advanced Materials Interfaces, 2019, 6(22): 1900948.
[82]	HAN C, WANG Y D, LEI Y P. Recent progress on nano-heterostructure photocatalysts for solar fuels generation. Journal of Inorganic Materials, 2015, 30(11): 1121-1130. DOI URL
[83]	MAO Y H, MA X C, WU D X, et al. Interfacial polarons in van der Waals heterojunction of monolayer SnSe₂ on SrTiO₃ (001). Nano Letters, 2020, 20(11): 8067-8073. DOI URL
[84]	LIU Y, ZHAO G J, ZHANG J X, et al. First-principles investigation on the interfacial interaction and electronic structure of BiVO₄/WO₃ heterostructure semiconductor material. Applied Surface Science, 2021, 549: 149309.
[85]	ANWAR M T, YAN X H, ASGHAR M R, et al. MoS₂-rGO hybrid architecture as durable support for cathode catalyst in proton exchange membrane fuel cells. Chinese Journal of Catalysis, 2019, 40(8): 1160-1167. DOI URL
[86]	LEE C, OZDEN S, TEWARI C S, et al. MoS₂-carbon nanotube porous 3D network for enhanced oxygen reduction reaction. ChemSusChem, 2018, 11(17): 2960-2966. DOI URL
[87]	PARK H S, HAN S B, KWAK D H, et al. Sulfur-doped porphyrinic carbon nanostructures synthesized with amorphous MoS₂ for the oxygen reduction reaction in an acidic medium. ChemSusChem, 2017, 10(10): 2202-2209. DOI URL
[88]	MAO J X, LIU P, DU C C, et al. Tailoring 2D MoS₂ heterointerfaces for promising oxygen reduction reaction electrocatalysis. Journal of Materials Chemistry A, 2019, 7(15): 8785-8789. DOI URL
[89]	ROY D, PANIGRAHI K, DAS B K, et al. Boron vacancy: a strategy to boost the oxygen reduction reaction of hexagonal boron nitride nanosheet in hBN-MoS₂ heterostructure. Nanoscale Advances, 2021, 3(16): 4739-4749. DOI URL
[90]	KWON I S, KWAK I H, KIM J Y, et al. Two-dimensional MoS₂/Fe-phthalocyanine hybrid nanostructures as excellent electrocatalysts for hydrogen evolution and oxygen reduction reactions. Nanoscale, 2019, 11(30): 14266-14275. DOI URL
[91]	XIN S L, LIU Z Q, MA L, et al. Visualization of the electrocatalytic activity of three-dimensional MoSe₂@reduced graphene oxide hybrid nanostructures for oxygen reduction reaction. Nano Research, 2016, 9(12): 3795-3811. DOI URL
[92]	HAO L, YU J, XU X, et al. Nitrogen-doped MoS₂/carbon as highly oxygen-permeable and stable catalysts for oxygen reduction reaction in microbial fuel cells. Journal of Power Sources, 2017, 339: 68-79. DOI URL
[93]	SHANG X, YAN K L, LIU Z Z, et al. Oxidized carbon fiber supported vertical WS₂ nanosheets arrays as efficient 3D nanostructure electrocatalyts for hydrogen evolution reaction. Applied Surface Science, 2017, 402: 120-128. DOI URL
[94]	CHENG C, HE B W, FAN J J, et al. An inorganic/organic S-scheme heterojunction H₂-production photocatalyst and its charge transfer mechanism. Advanced Materials, 2021, 33(22): 2100317.
[95]	CHEN J L, QIAN G F, ZHANG H, et al. PtCo@PtSn heterojunction with high stability/activity for pH-universal H₂ evolution. Advanced Functional Materials, 2022, 32(5): 2107597.
[96]	SUN L, WANG B, WANG Y D. High-temperature gas sensor based on novel Pt single atoms@SnO₂ nanorods@SiC nanosheets multi- heterojunctions. ACS Applied Materials & Interfaces, 2020, 12(19): 21808-21817.
[97]	HE L H, CUI B B, LIU J M, et al. Fabrication of porous CoO_x/mC@MoS₂ composite Loaded on g-C₃N₄ nanosheets as a highly efficient dual electrocatalyst for oxygen reduction and hydrogen evolution reactions. ACS Sustainable Chemistry & Engineering, 2018, 6(7): 9257-9268.
[98]	CHUONG N D, THANH T D, KIM N H, et al. Hierarchical heterostructures of ultrasmall Fe₂O₃-encapsulated MoS₂/N-graphene as an effective catalyst for oxygen reduction reaction. ACS Applied Materials & Interfaces, 2018, 10(29): 24523-24532.
[99]	BAI J M, MENG T, GUO D L, et al. Co₉S₈@MoS₂ core-shell heterostructures as trifunctional electrocatalysts for overall water splitting and Zn-air batteries. ACS Applied Materials & Interfaces, 2018, 10(2): 1678-1689.
[100]	LI W M, YU A P, HIGGINS D C, et al. Biologically inspired highly durable iron phthalocyanine catalysts for oxygen reduction reaction in polymer electrolyte membrane fuel cells. Journal of the American Chemical Society, 2010, 132(48): 17056-17058. DOI URL
[101]	SAMANTA M, GHOSH S, MUKHERJEE M, et al. Enhanced electrocatalytic oxygen reduction reaction from organic-inorganic heterostructure. International Journal of Hydrogen Energy, 2022, 47(10): 6710-6720. DOI URL
[102]	ZHOU X L, HAO H, ZHANG Y J, et al. Patterning of transition metal dichalcogenides catalyzed by surface plasmons with atomic precision. Chem, 2021, 7(6): 1626-1638. DOI URL

二维过渡金属硫属化合物氧还原反应催化剂的研究进展

Two-dimensional Transition Metal Dichalcogenides for Electrocatalytic Oxygen Reduction Reaction

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