硅基氧化物发光玻璃及其制备技术研究进展

doi:10.15541/jim20160188

摘要/Abstract

摘要：

由于具有高透过率、优异的化学稳定性和易于机械加工等优势, 硅基氧化物玻璃是一种理想的基质材料。通过引入不同的发光组分, 获得不同光学性能的光功能玻璃被广泛应用于多个领域。然而, 这些发光组分在玻璃制备过程中易挥发、分解, 稳定性较低, 所以功能发光玻璃的制备技术仍面临着新的挑战。本文综述了掺杂铋离子、量子点及荧光粉硅基发光玻璃的发展现状及其制备技术。通过比较高温熔融法、溶胶-凝胶法、固相烧结法及放电等离子体烧结技术(简称SPS)的优缺点, 本文着重介绍了SPS技术应用于发光玻璃制备的研究进展及优势, 并对这种新制备技术的发展趋势进行了评述和展望。

关键词: 硅基玻璃, 铋元素, 量子点, 荧光粉, 放电等离子体烧结技术, 发光材料, 综述

Abstract:

Due to high transmittance, excellent chemical stability, ease of machining, and other advantages, silicon-based oxide glass is considered to be an ideal matrix material. By introducing different lighting dopants, the optical glass with different properties has been widely used in many fields. However, the preparation technologies of the optical glass are facing new challenges because of these volatile and unstable lighting dopants which easy to be decomposed. This review introduces the development status and the preparation techniques of the silicon-based light-emitting glass containing bismuth ions, quantum dots and phosphors. By comparing the melting method, Sol-Gel, solid-state sintering and spark plasma sintering (SPS), the research progress and superiority of SPS technology applied in optical glass preparation are focused on and the developments of this new preparation technology are also reviewed.

Key words: silicon-based glass, Bi, quantum dots, phosphors, spark plasma sintering, optical materials, review

中图分类号:

TQ171

王连军, 周蓓莹, 顾士甲, 江莞. 硅基氧化物发光玻璃及其制备技术研究进展[J]. 无机材料学报, 2016, 31(10): 1013-1022.

WANG Lian-Jun, ZHOU Bei-Ying, GU Shi-Jia, JIANG Wan. Research Progress on Silicon-based Luminescent Glass and Its Preparation Techniques[J]. Journal of Inorganic Materials, 2016, 31(10): 1013-1022.

图/表 10

图1 常温下铋离子和Tm3+, Er3+离子在玻璃中的荧光光谱[15]

Fig. 1 Emission spectra of Bismuth doped silica glass and Tm3+, Er3+ doped glasses[15]

图2 掺杂CdS纳米颗粒的介孔二氧化硅玻璃层随老化时间变化的荧光谱图[26]

Fig. 2 Photoluminescence (PL) spectral evolution of CdS NPs incorporated mesoporous SiO2 film with respect to ageing time as indicated in the figure in ambient condition[26]

图3 (a)不同热处理时间的掺杂CdSe量子点玻璃LEDs的色谱图, LEDs发光照片位于右侧; (b)和(c)为LED的电致发光与光致发光谱图[27]

Fig. 3 (a) CIE color coordination of the LEDs with silicate glass embedded CdSe QDs for varying duration times. The actual photographs of the LEDs were displayed on the right side. The insets (b) and (c) show EL + PL spectra of the LEDs[27]

图4 Ce3+激活的YAG荧光粉和微晶玻璃发光性能比较图[33]

Fig. 4 Comparison of transmitted luminescence of Ce3+ activated garnet luminescent powder phosphor and ceramics[33]

图5 固相烧结法制备样品的SEM照片实物图及发光光谱[58- 59]

Fig. 5 SEM image, photograph and luminescence spectra of as-prepared by solid state sintering[58-59]

图6 SPS固化得到的透明样品的高分辨透射电镜照片(HRTEM)[39]

Fig. 6 HRTEM image of the SPS as-consolidated transparent sample[39]

图7 不同温度下烧结样品的实物照片[65]

Fig. 7 Photographs of samples sintered at different temperatures[65]

图8 (a)SBA-15粉体, (b)经SPS于1173K烧结得到的样品, (c)经SPS于1293K烧结得到的硅基玻璃的TEM照片, (d)在温度与压力作用下, 介孔结构坍塌转换成玻璃的示意图[40]

Fig. 8 TEM images of original SBA-15 (a), sintered sample treated by SPS at 1173 K (b) and the silica glass sintered by SPS at 1293 K (c). Schematic of collapse of mesoporous structure and transformation to glass under combination of temperature and pressure(d)[40]

图9 制备含Au纳米晶玻璃的过程示意图[68]

Fig. 9 Schematic illustration of preparation for silica glass incorporated with Au NPs[68]

图10 (a)掺杂Ag纳米颗粒的SBA-15粉体的TEM图片,(b)Ag纳米颗粒的HRTEM图片, (c)烧结样品的TEM图片, (d)(c)图中黑点的EDX图谱[69]

Fig. 10 (a) TEM image of Ag NPs/SBA-15 and (b) HRTEM image of single Ag nanoparticle from (a); (c) TEM image of the sintered sample and (d) EDX spectrum taken on the dark spherical spots in (c)[69]

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