Journal of Inorganic Materials

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Effect of Moulding Techniques on Electro-adsorption Desalination of Carbon Nanotube Electrodes

ZHANG Deng-Song1,2, SHI Li-Yi1,2,3, FANG Jian-Hui1,2,3, DAI Kai1, ZHANG Li-Ying1   

  1. 1. School of Material Science and Engineering, Shanghai University, Shanghai 200444, China; 2. College of Science, Shanghai University, Shanghai 2000444, Chine; 3.
    Research Center of Nanoscience and Nanotechnology of Shanghai University, Shanghai 200444, China
  • Received:2004-12-06 Revised:2005-01-06 Published:2006-01-20 Online:2006-01-20

Abstract: The carbon nanotube electrodes with different kinds and quantities of binders, using methods such as press molding at room-temperature and hot-press molding combined with carbonization, were
moulded. The charge-discharge tests of the electrodes were performed in saltwater by the DC-5 battery testing instrument, and the specific electro-adsorption capacitance and equivalent resistance
were compared. The results are as follows: the electrodes can be molded at room-temperature with 10% polytetrafluoroethylene (PTFE) or 15% polyvinylidene fluoride (PVDF) and at high temperature
with 20% phenolic resin (PR), and the specific electro-adsorption capacitance decreases and the equivalent resistance increases with the increasing content of the binders. The surface structure,
morphology, specific electro-adsorption capacitance, equivalent resistance and hydrophilicity of the electrodes were investigated, and the electro-adsorption desalination performances were compared.
The results show that the electrode hot-pressed with 20% PR, after carbonization, with high specific surface area, many pores, good hydrophilicity, high specific electro-adsorption capacitance and low
equivalent resistance, has the best electro-adsorption desalination performance.

Key words: carbon nanotubes, electrode, moulding, desalination

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