Journal of Inorganic Materials ›› 2024, Vol. 39 ›› Issue (5): 531-538.DOI: 10.15541/jim20230587

Special Issue: 【信息功能】透明陶瓷与闪烁晶体(202409)

• RESEARCH ARTICLE • Previous Articles     Next Articles

Effect of MgF2 Additive on Preparation and Optical Properties of MgAl1.9Ga0.1O4 Transparent Ceramics

LÜ Zhaoyang1,2(), XU Yong1,2, YANG Jiuyan1,2, TU Guangsheng1,2, TU Bingtian1,2, WANG Hao1,2()   

  1. 1. State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
    2. Hubei Longzhong Laboratory, Wuhan University of Technology Xiangyang Demonstration Zone, Xiangyang 441000, China
  • Received:2023-12-21 Revised:2024-01-20 Published:2024-05-20 Online:2024-02-22
  • Contact: WANG Hao, professor. E-mail: shswangh@whut.edu.cn
  • About author:LÜ Zhaoyang (1999-), male, Master candidate. E-mail: lvzhaoyang2021@163.com
  • Supported by:
    National Key Research and Development Program of China(2023YFB3812000);National Natural Science Foundation of China(52272072);Hubei Longzhong Laboratory Independent Innovation Research Project(2022ZZ-13)

Abstract:

Currently, the preparation of MgAl1.9Ga0.1O4 transparent ceramics which possess excellent optical properties, is still relying on combining aqueous gel-casting and prolonged pressureless pre-sintering. In this work, MgF2 was used as a sintering additive, and densification process of pressureless pre-sintering was adjusted by a transient liquid phase. MgAl1.9Ga0.1O4 transparent ceramics with different sizes were prepared by dry pressing, pressureless pre-sintering, and hot isostatic pressing treatment. The effects of MgF2 additive on microstructure, optical, and mechanical properties of the samples were systematically analyzed. The results indicated that MgF2 melted at ~1230 ℃, contributing to increase of density and grain size of the pre-sintered body, while the residual MgF2 was oxidized to MgO and dissolved into the MgAl1.9Ga0.1O4 lattice in the subsequent sintering process. The 2.04 mm thick transparent ceramic sample with 0.20% (in mass fraction) MgF2 has an in-line transmittance of 76.5%-83.4% in the UV and visible regions. Moreover, the sample has high optical quality with low scattering on incident light. In addition, the characteristic flexural strength of this ceramics is 167.1 MPa, which is close to that of the fine-grained MgAl2O4 transparent ceramics, but the Weibull modulus (8.81±0.29) is higher. This study provided a new option for the preparation of large MgAl1.9Ga0.1O4 transparent ceramic materials with good optical properties.

Key words: transparent ceramic, MgAl1.9Ga0.1O4, MgF2, transient liquid phase sintering, optical property

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