Comparative Study on Tribological Behavior of Sb2S3 Nano-bundles and Nano-particles in Liquid Paraffin

doi:10.3724/SP.J.1077.2011.00643

Abstract

Abstract: The tribological properties of Sb₂S₃nano-bundles as an additive in liquid paraffin were evaluated on a four-ball tester, thereafter the performance of Sb₂S₃nano-bundles was compared with that of Sb₂S₃ nano-particles. The comparative analyses of friction coefficients, wear scar diameters and morphology of worn surfaces show that Sb₂S₃nano-bundles and nano-particles can both improve tribological properties of base oil, Sb₂S₃ nano-bundles exhibit better friction reduction and anti-wear properties than Sb₂S₃ nano-particles at relative low load, and they possess very similar tribological performance at relative high load. As far as the load carrying ability is concerned, the performance of nano-particles is obviously better than nano-bundles. It is inferred that the sliding-rolling friction transition emerges when lubricated with nano-bundles/oil mixture at low load, which contributes to the good lubricating effect of the nano-bundles.

Key words: Sb₂S₃, morphology, lubricating additive, tribological properties

CLC Number:

TH117

ZHANG Ling, CHEN Jian-Min, CHEN Lei, WAN Hong-Qi, ZHOU Hui-Di. Comparative Study on Tribological Behavior of Sb₂S₃ Nano-bundles and Nano-particles in Liquid Paraffin[J]. Journal of Inorganic Materials, 2011, 26(6): 643-648.

References

[1] Hisakado T, Tsukizoe T, Yoshikawa H. Lubrication mechanism of solid lubricants in oils. J. Lubri. Technol., 1983, 105: 245-252.

[2] Herron N, Wang Y, Eckert H. Synthesis and characterization of surface-capped, size-quantized CdS clusters. chemical control of cluster size. J. Am. Chem. Soc., 1990, 112(4): 1322-1326.

[3] Zhang Z J, Zhang J, Xue Q J. Synthesis and characterization of molybdenum disulfide nanocluster. J. Phys. Chem., 1994, 98(49): 12973-12977.

[4] Joly-Pottuz L, Vacher B, Ohmae N, et al. Anti-wear and friction reducing mechanisms of carbon nano-onions as lubricant additives. Tribol. Lett., 2008, 30(1): 69-80.

[5] Liu W M, Wang X B. Nanolubricants Made of Metals. Martin J M, Ohmae N (ed.). Nanolubricants. John Wiley & Sons, Inc, New York, 2008: 175-202.

[6] 肖高峰, 马雪慧, 赵彦保, 等(XIAO Gao-Feng, et al). 花状结构纳米铟的制备及其摩擦学性能. 物理化学学报(Acta Phys.-Chim. Sin.), 2008, 24(10): 1864-1868.

[7] Ye W Y, Cheng T F, Ye Q, et al. Preparation and tribological properties of tetrafluorobenzoic acid-modified TiO2 nanoparticles as lubricant additives. Mater. Sci. Eng. A, 2003, 359(1/2): 82-85.

[8] Liu, W M, Chen, S. An investigation of the tribological behaviour of surface-modified ZnS nanoparticles in liquid paraffin. Wear, 2000, 238(2): 120-124.

[9] Li J S, Xu X H, Wang Y G, et al. Tribological studies on a novel borate ester containing benzothiazol-2-yl and disulfide group as multifunctional additive. Tribol. Int., 2010, 43(5/6): 1048-1053.

[10] 顾卓明, 顾彩香, 陈志刚. 含纳米碳酸钙、稀土粒子润滑油的摩擦学性能. 润滑与密封, 2005(6): 9-11.

[11] 乔玉林, 徐滨士, 马世宁, 等. 含纳米金刚石复合润滑油添加剂的摩擦学性能. 石油炼制与化工, 1999, 30(3): 12-15.

[12] Hernández Battez A, González R, Viesca J L, et al. CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants. Wear, 2008, 265(3/4): 422-428.

[13] Zhang L, Wang H Q, Chen L, et al. Surface-modified Sb2S3 nanoparticles and their tribological behaviors in liquid paraffin. J. Disper. Sci. Technol., 2011, 32(6): 846-850.

[14] Zhang L, Chen L, Wan H Q, et al. Preparation of shuttle-like Sb2S3 nanorod-bundles via a solvothermal approach under alkaline condition. Cryst. Res. Technol., 2010, 45(2): 178-182.

[15] Wu Q S, Zhang G X, Ding Y P. Soft-template synthesis and optical properties of Sb2S3 semiconductor quasi-nanospheres. J. Nanopart. Res., 2006, 8(5): 737-742.

[16] 赵修臣, 刘颖, 余智勇. 纳米粒子作润滑油添加剂的研究与展望. 润滑与密封. 2002(6): 80-82.

[17] Rapoport L, Bilik Y, Feldman Y, et al. Hollow nanoparticles of WS2 as potential solid-state lubricants. Nature, 1997, 387: 791-793.

[18] 孙玉彬, 李业霞, 梁永民, 等. 二烷基二硫代氨基甲酸锑在聚--烯烃中的摩擦性能及其摩擦化学作用机制的研究. 润滑与密封, 2007, 32(7): 101-107.

[19] Huang W J, Dong J X, Li F F, et al. Study of the tribological behavior of S-(carboxylpropyl)-N-dialkyldithiocarbamic acid as additives in water-based fluid. Wear, 2002, 252(3/4): 306-310.

[20] An C H, Tang K B, Yang Q, et al. Formation of crystalline stibnite bundles of rods by thermolysis of an antimony(III) diethyldithiocarbamate complex in ethylene glycol. Inorg. Chem., 2003, 42(24): 8081-8086.

Comparative Study on Tribological Behavior of Sb₂S₃ Nano-bundles and Nano-particles in Liquid Paraffin

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