Synthesis and Luminescence Properties of Eu3+-doped Bi4Si3O12

doi:10.3724/SP.J.1077.2011.11200

Journal of Inorganic Materials ›› 2011, Vol. 26 ›› Issue (12): 1341-1344.DOI: 10.3724/SP.J.1077.2011.11200

• Research Letter • Previous Articles

Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂

ZHANG Yan, XU Jia-Yue, Zhang Ting-Ting

(School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 200235, China)

Received:2011-04-01 Revised:2011-06-03 Published:2011-12-20 Online:2011-11-11
About author:ZHANG Yan(1977-), male, PhD, lecturer. E-mail: yanzhang@sit.edu.cn
Supported by:
National Natural Science Foundation of China (50972093); National Key Basic Research Program (2011CB612310); Shanghai Municipal Education Commission (J51504, 09ZZ196, 10XD1403800, yyy09005); SIT Research Project on Optical Functional Crystals (TDP 2009-03, 1020K116001 - YJ2009-01)

Abstract

Abstract: Eu³⁺-doped Bi₄Si₃O₁₂ phosphors were synthesized by the conventional solid state reaction. X-ray diffraction analysis confirmed the formation of Bi₄Si₃O₁₂: Eu3+. The excitation spectra of Eu3+-doped Bi₄Si₃O₁₂ show an intense broad band with maximum at 265 nm related to Eu³⁺→O^2- charge transfer transition. Photoluminescence spectra indicate that the phosphor emits strong red light centered at 614 nm under UV light excitation. Due to high emission intensity and a good excitation profile, the Eu³⁺-doped Bi₄Si₃O₁₂ phosphor may be a promising candidate in solid state lighting applications.

Key words: bismuth silicate, phosphor, europium luminescence

CLC Number:

TQ174

ZHANG Yan, XU Jia-Yue, Zhang Ting-Ting. Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂[J]. Journal of Inorganic Materials, 2011, 26(12): 1341-1344.

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Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂

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