Journal of Inorganic Materials

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Effect of defect Dipole Thermal-stability on the Electromechanical Properties of Fe Doped PZT Piezoelectric Ceramics

SUN Yuxuan1,2, WANG Zheng1, SHI Xue1, SHI Ying1,2, DU Wentong1,2, MAN Zhenyong1, ZHENG Liaoying1, LI Guorong1   

  1. 1. Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
    2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2024-05-14 Revised:2024-09-24 Published:2024-11-29 Online:2024-11-29
  • Contact: LI Guorong, professor. E-mail: grli@mail.sic.ac.cn
  • Supported by:
    Natural Science Foundation of China (U2241242); National Key R&D Program of China (2023YFB3812000, 2021YFA0716502)

Abstract: The accepted doping ion in Ti4+-site of PZT-based piezoelectric ceramics is a well-known method to increase Qm, since the acceptor coupled by oxygen vacancy becomes defect dipole, which prevent the domain rotation. A serious problem is that generally, Qm decreases as the temperature (T) increases, since the oxygen vacancies is decoupled from the defect dipoles. Here, we report that Qm of PSZT ceramics doped by 0.40% Fe2O3 (in mole), abnormally increases as T increases, which Qm and d33 at room temperature and Curie temperature TC is about 507, 292 pC/N, and 345 ℃, respectively. The maximum Qm of 824 was achieved around 120-160 ℃, which is 63% higher than the value at room temperature, while the dynamic piezoelectric constant d31 was just slightly decreased by about 3.9%. XRD (X-ray Diffraction) and PFM (Piezoresponse Force Microscopy) results show that The interplanar spacing and the fine domains form as temperature increases, and the TSDC (Thermally Stimulated Depolarization Current) shows that the defect dipoles is stable up to 240 ℃, we think that the aggregation of oxygen vacancies near the fine domains and defect dipole which is stable up to 240 ℃, pin domain rotation, resulting in the enhanced Qm in the increasing temperature. This result give a possibility to design a high Qm in high temperature.

Key words: defect dipoles, temperature characteristic, oxygen vacancies, electro-mechanical properties, mechanical quality factor, hardening doping

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