超级电容器氧化锰电极材料的研究进展

无机材料学报

超级电容器氧化锰电极材料的研究进展

张治安; 杨邦朝; 邓梅根; 胡永达

电子科技大学微电子与固体电子学院, 成都 610054

收稿日期:2004-04-21 修回日期:2004-05-24 出版日期:2005-05-20 网络出版日期:2005-05-20

Progress of Research on Manganese Oxide for Electrode Material of Supercapacitors

ZHANG Zhi-An; YANG Bang-Chao; DENG Mei-Gen; HU Yong-Da

College of Microelectronics and Solid State Electronics; University of Electronic Science and Technology of China; Chengdu 610054; China

Received:2004-04-21 Revised:2004-05-24 Published:2005-05-20 Online:2005-05-20

摘要/Abstract

摘要： 氧化锰资源广泛、价格低廉、环境友善、电化学性能良好,有着较好的应用前景,已成为优良的超级电容器电极材料.本文简要介绍了超级电容器氧化锰粉末电极和薄膜电极的特点和制备工艺,综述了合成氧化锰的各种制备技术及其取得的进展和存在的主要问题,并分析了通过掺杂和复合来提高氧化锰电极比容量和导电性的思路和解决方案.

关键词: 超级电容器, 氧化锰, 电极材料, 制备技术

Abstract: Manganese oxide has been considered to be a promising electrode material for supercapacitors in
terms of its low cost, natural abundance, environmental friendliness and superior electrochemical performance. Characteristics and fabrications
of manganese oxide film electrode and powder electrode were discussed. Synthetic methods of preparing manganese oxide were summarized
systematically and the recent developments and main obstacles in the research of manganese oxide were reviewed. Moreover, the solutions to
improve the specific capacitance and electric conductivity by a doping and composite method were also discussed.

Key words: supercapacitor, manganese oxide, electrode material, synthetic method

中图分类号:

TM53

张治安,杨邦朝,邓梅根,胡永达. 超级电容器氧化锰电极材料的研究进展[J]. 无机材料学报.

ZHANG Zhi-An,YANG Bang-Chao,DENG Mei-Gen,HU Yong-Da. Progress of Research on Manganese Oxide for Electrode Material of Supercapacitors[J]. Journal of Inorganic Materials.

参考文献

[1] Conway B E. Electrichemical Supercapacitors, New York: Plenum Publishers, 1999.
[2] Kotz R, Carlen M. Electrochim. Acta, 2000, 45: 2483--2498.
[3] Burke A. J. Power Sources, 2000, 91: 37--50.
[4] Huggins R A. Solid State Ionics, 2000, 134: 179--195.
[5] Sarangapani S, Tilak B V, Chen C P. J. Electrochem. Soc., 1996, 143: 3791--3799.
[6] Zheng J P, Cygan P J, Jow T R. J. Electrochem. Soc., 1995, 142: 2699--2703.
[7] Liu K C, Anderson M A. J. Electrochem. Soc., 1996, 143: 124--130.
[8] 王晓峰, 孔祥华, 刘庆国, 等. 功能材料, 2002, 33 (5): 513--517.
[9] Lin C, Ritter J A, Popov B N J. Electrochem. Soc., 1998, 145: 4097--4101.
[10] 曹林, 周盈科, 陆梅, 等. 科学?通报, 2003, 48 (7): 668--670.
[11] 夏熙, 刘玲. 电源技术, 1997, 21 (3): 120--126.
[12] 努尔买买提, 夏熙(Nurmaimaiti, et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (5): 802--806.
[13] 李娟, 李清文, 夏熙, 等. 应用?科学学报, 1999, 17 (2): 245--249.
[14] 房振乾, 刘文西, 陈玉如. 电源技术, 2003, 27 (3): 267--283.
[15] Lee H Y, Goodenough J B. J. Solid State Chem., 1999, 144: 220--223.
[16] 闪星, 董国君, 景晓燕, 等. 无机化学学报, 2001, 17 (5): 669--674.
[17] Jeong Y U, Manthiram A. J. Electrochem. Soc., 2002, 149: A1419--A1422.
[18] Toupin M, Brousse T, Belanger D. Chem. Mater., 2002, 14: 3946--3952.
[19] Reddy R N, Reddy R G. J. Power Sources, 2003, 124: 330--337.
[20] 周益明, 忻新泉. 无机化学学报, 1999, 15 (3): 273--292.
[21] 张宝宏, 张娜. 物理化学学报, 2003, 19 (3): 286--288.
[22] Lee H Y, Manivannan V, Goodenough J B. C. R. Acad. Sci. Series IIc Chem., 1999, 2: 565--577.
[23] Reddy R N, Reddy R G. EPD Congress 2002 on Fundamentals of Advanced Materials for Energy Conversion, Feb 17-21 2002, Seattle, WA, United States.
[24] 刘献明, 张校刚(LIU Xian-Ming, et al). 无机材料学报(Journal of Inorganic Materials), 2003, 18 (5): 1022--1026.
[25] Hu C C, Tsou T W. Electrochem. Commun., 2002, 4: 105--109.
[26] Hu C C, Wang C C. J. Electrochem. Soc., 2003, 150: A1079--A1084.
[27] Chang J K, Tsai W T. J. Electrochem. Soc., 2003, 150: A1333--A1338.
[28] Jiang J H, Kucernak A. Electrochim. Acta, 2002, 47: 2381--2386.
[29] Pang S C, Anderson M A, Chapman T W. J. Electrochem. Soc., 2000, 147: 444--450.
[30] Chin S F, Pang S C, Anderson M A. J. Electrochem. Soc., 2002, 149: A379--A384.
[31] Broughton J N, Brett M J. Electrochem. Solid-State Lett., 2002, 5 (12): A279--A282.
[32] Djurfors B, Broughton J N, Brett M J, et al. J. Mat. Sci., 2003, 38: 4817--4830.
[33] 夏熙, 张春霞. 电源技术, 2002, 26 (3): 147--151.
[34] 夏熙, 龚良玉. 化学学报, 2002, 60 (1): 87--92.
[35] 唐致远, 耿新, 王占良, 等. 应用化学, 2002, 19 (10): 936--940.
[36] Kim H S, Popov B N. J. Electrochem. Soc., 2003, 150: D56--D62.
[37] 刘献明, 张校刚, 包淑娟, 等. 功能材料与器件学报, 2003, 9 (3): 267--271.
[38] Chen Y S, Hu C C. Electrochem. Solid-State Lett., 2003, 6 (10): A210--A213.
[39] Lee H Y, Kim S W, Lee H Y. Electrochem. Solid-State Lett., 2001, 4 (3): A19--A22.
[40] Barsukov V, Chivikov S. Electrochem. Acta, 1996, 41: 1773--1779.
[41] Arbizzani C, Mastragostino M, Meneghello L. Electrochem. Acta, 1996, 41: 21--26.
[42] An K H, Jeon K K, Heo J K, et al. J. Electrochem. Soc., 2002, 149: A1058--A1062.
[43] Chen W C, Wen T C. J. Power Source, 2003, 117: 273--282.
[44] Hong M S, Lee S H, Kim S W. Electrochem. Solid-State Lett., 2002, 5 (10): A227--A230.
[45] Brousse T, Belanger D. Electrochem. Solid-State Lett., 2003, 6 (11): A244--A248.
[46] 闪星, 张密林, 董国君, 等. 电源技术, 2002, 26 (2): 92--94.