单分散球形YAG透明陶瓷粉体的喷雾造粒制备及其性能表征

doi:10.15541/jim20140533

无机材料学报 ›› 2015, Vol. 30 ›› Issue (5): 487-492.DOI: 10.15541/jim20140533 CSTR: 32189.14.10.15541/jim20140533

单分散球形YAG透明陶瓷粉体的喷雾造粒制备及其性能表征

张乐^1,2, 周天元^1,2, 杨浩^1,2, 乔学斌^1,2, 王忠英^2,3, 章健^1,2, 唐定远^1,2

(1. 江苏师范大学物理与电子工程学院, 徐州 221116; 2. 江苏师范大学江苏省先进激光材料与器件重点实验室, 徐州 221116; 3. 南京工业大学材料科学与工程学院, 南京 210009)

收稿日期:2014-10-20 修回日期:2014-11-24 出版日期:2015-05-20 网络出版日期:2015-04-28
基金资助:
国家自然科学基金(51402133, 51302115, 61405081); 江苏高校优势学科建设工程资助项目(PAPD)

Preparation and Characterization of Monodispersed and Spherical YAG Powder for Transparent Ceramic by Spray Drying

ZHANG Le^1,2, ZHOU Tian-Yuan^1,2, YANG Hao^1,2, QIAO Xue-Bin^1,2, WANG Zhong-Ying^2,3, ZHANG Jian^1,2, TANG Ding-Yuan^1,2

(1. School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China; 2. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Jiangsu Normal University, Xuzhou 221116, China; 3. College of Materials Science and Engineering, Nanjing Technological University, Nanjing 210009, China)

Received:2014-10-20 Revised:2014-11-24 Published:2015-05-20 Online:2015-04-28
Supported by:
National Natural Science Foundation of China(51402133, 51302115, 61405081); Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)

摘要/Abstract

摘要：

采用无水乙醇基浆料结合喷雾造粒工艺制备YAG透明陶瓷粉体, 通过扫描电子显微镜、压汞仪、能谱仪及紫外–可见–红外透过光谱系统研究了不同PVB粘结剂添加量下YAG造粒颗粒的形貌、尺寸、成型性能及其破碎行为, 对成型素坯的孔分布及烧制透明陶瓷的显微结构及光学性能进行了详细表征。在优化PVB添加量为1.0wt%时, 造粒粉体为实心单分散颗粒, 球形度高、化学均匀性好, 其平均粒径约为40 μm, 成型性能优异; 在75 MPa压力下, 造粒颗粒完全破碎形成密实均一的坯体结构。烧结后的YAG透明陶瓷显微结构均一, 无气孔及其他缺陷, 光学质量优异。

关键词: 透明陶瓷, YAG, 喷雾造粒, 粘结剂

Abstract:

YAG transparent ceramic powders were prepared by spray drying method with anhydrous ethanol suspension. The morphology, size, forming performance and crushing behavior of granulated particles with different PVB binder contents, the pore distribution in green compacts as well as the microstructure and optical properties of sintered ceramics were investigated by SEM, mercury injection, EDS and UV-Visible-Infrared transmission spectroscopy. The optimal content of PVB is 1.0wt%. The granulated particles exhibit excellent forming performance with mono-dispersed and fully dense aggregates. They have high spherical degree and high chemical uniformity. Their mean size is ~40 μm. The granulated particels are completely crushed under 75 MPa pressure and form uniform and compact structure of green compacts. The sintered YAG transparent ceramics have good optical properties with homogeneous microstructure and without pore and defects.

Key words: transparent ceramics, YAG, spray drying, binder

中图分类号:

TQ174

张乐, 周天元, 杨浩, 乔学斌, 王忠英, 章健, 唐定远. 单分散球形YAG透明陶瓷粉体的喷雾造粒制备及其性能表征[J]. 无机材料学报, 2015, 30(5): 487-492.

ZHANG Le, ZHOU Tian-Yuan, YANG Hao, QIAO Xue-Bin, WANG Zhong-Ying, ZHANG Jian, TANG Ding-Yuan. Preparation and Characterization of Monodispersed and Spherical YAG Powder for Transparent Ceramic by Spray Drying[J]. Journal of Inorganic Materials, 2015, 30(5): 487-492.

参考文献

[1] IKESUE A, AUNG Y L. Ceramic laser materials. Nat. Photonics, 2008, 2(12): 721–727.
[2] IKESUE A, KINOSHITA T, KAMATA K, et al. Fabrication and optical properties of high-performance polycrystalline Nd: YAG ceramics for solid-state lasers. J. Am. Ceram. Soc., 1995, 78(4): 1033–1040.
[3] WANG S F, ZHANG J, LUO D W, et al. Transparent ceramics: Processing, materials and applications. Prog. Solid State Chem., 2013, 41(1/2): 20–54.
[4] LI J, PAN Y B, ZENG Y P, et al. The history, development, and future prospects for laser ceramics: a review. Int. J. Ref. Met. Hard Mater., 2013, 39(Special): 44–52.
[5] JIANG DONG-LIANG. Transparent ceramics: one of the most important field of research and development of inorganic materials. Journal of Inorganic Materials, 2009, 24(5): 873–881.
[6] 施剑林, 冯涛. 无机光学透明材料–透明陶瓷. 上海: 上海科学普及出版社, 2007.
[7] GE L, LI J, ZHOU Z W, et al. Fabrication of composite YAG/Nd:YAG/YAG transparent ceramics for planar waveguide laser. Opt. Mater. Express, 2014, 4(5): 1042–1049.
[8] BA X W, LI J, PAN Y B, et al. Preparation of composite YAG transparent ceramics by aqueous tape casting route. Rare Metal Mater. Eng., 2013, 42(1A): 234–237.
[9] ZHOU JUN, PAN YU-BAI, LI JIANG, et al. Fabrication of YAG transparent ceramics using slip casting with ethanol. Journal of Inorganic Materials, 2011, 26(3): 254–256.
[10] PAN YU-BAI, XU JUN, WU YU-SONG, et al. Fabrication and laser output of Nd:YAG transparent ceramic. Journal of Inorganic Materials, 2006, 21(05): 1278–1280.
[11] JI YA-MING, JIANG DAN-YU; FENG TAO, et al. Fabrication and developments of transparent ceramics. Journal of Inorganic Materials, 2004, 19(2): 275–282.
[12] NANDIYANTO A B D, OKUYAMA K. Progress in developing spray-drying methods for the production of controlled morphology particles: From the nanometer to submicrometer size ranges. Adv. Powder Technol., 2011, 22(1): 1–19.
[13] 曹永革, 黄秋凤, 郭旺, 等. 一种稀土掺杂钇铝石榴石透明陶瓷的制备方法. 中国, CN200910112277.2. 2011.03.16.
[14] LIU YUAN, GUO WANG, HUANG ZHI, et al. Preparation of modified powders by spray drying for transparent ceramics of yttrium aluminum garnet. Journal of University of Science and Technology Beijing, 2010, 32(12): 1586–1590.
[15] LIU W B, ZHANG W X, LI J, et al. Preparation of spray-dried powders leading to Nd:YAG ceramics: The effect of PVB adhesive. Ceram. Int., 2012, 38(1): 259–264.
[16] SERANTONI M, PIANCASTELLI A, COSTA A L, et al. Improvements in the production of Yb:YAG transparent ceramic materials: spray drying optimisation. Opt. Mater., 2012, 34(6): 995–1001.
[17] ESPOSITO L, PIANCASTELLI A, COSTA A L, et al. Experimental features affecting the transparency of YAG ceramics. Opt. Mater., 2011, 33(5): 713–721.
[18] SUH W H, JANG A R, SUH Y H, et al. Porous, hollow, and ball-in-ball metal oxide microspheres: preparation, endocytosis, and cytotoxicity. Adv. Mater., 2006, 18(14): 1832–1837.
[19] TSETSEKOU A, AGRAFIOTIS C, LEON I, et al. Optimization of the rheological properties of alumina slurries for ceramic processing applications Part II: Spray-drying. J. Eur. Ceram. Soc., 2001, 21(4): 493–506.
[20] XUE J, JOG M A, JENG S M, et al. Effect of geometric parameters on simplex atomizer performance. Aiaa J., 2004, 42(12): 2408–2415.
[21] ELVERSSON J, MILLQVIST-FUREBY A. Particle size and density in spray drying - effects of carbohydrate properties. J. Pharm. Sci., 2005, 94(9): 2049–2060.
[22] ECKHARD S, NEBELUNG M. Investigations of the correlation between granule structure and deformation behavior. Powder Technol., 2011, 206(1/2): 79–87.

单分散球形YAG透明陶瓷粉体的喷雾造粒制备及其性能表征

Preparation and Characterization of Monodispersed and Spherical YAG Powder for Transparent Ceramic by Spray Drying

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李捷, 罗志新, 崔阳, 张广珩, 孙鲁超, 王京阳. 大气等离子喷涂Y₃Al₅O₁₂/Al₂O₃陶瓷涂层的CMAS腐蚀抗力[J]. 无机材料学报, 2024, 39(6): 671-680.
[2]	吕朝阳, 徐勇, 杨久延, 涂广升, 涂兵田, 王皓. MgF₂助剂对MgAl_1.9Ga_0.1O₄透明陶瓷的制备与光学性能的影响[J]. 无机材料学报, 2024, 39(5): 531-538.
[3]	石小兔, 张庆礼, 孙贵花, 罗建乔, 窦仁勤, 王小飞, 高进云, 张德明, 刘建党, 叶邦角. 提拉法下Yb:YAG单晶缺陷的正电子湮没研究[J]. 无机材料学报, 2023, 38(3): 316-321.
[4]	杨佳雪, 李雯, 王燕, 朱昭捷, 游振宇, 李坚富, 涂朝阳. Dy³⁺: Y₃Al₅O₁₂晶体的光谱与黄色激光性能[J]. 无机材料学报, 2023, 38(3): 350-356.
[5]	王志强, 吴济安, 陈昆峰, 薛冬峰. 大尺寸Er,Yb:YAG单晶的生长及其性能[J]. 无机材料学报, 2023, 38(3): 329-334.
[6]	靳喜海, 董满江, 阚艳梅, 梁波, 董绍明. 透明AlON陶瓷凝胶浇注成型及其无压烧结制备[J]. 无机材料学报, 2023, 38(2): 193-198.
[7]	汪德文, 王俊平, 袁厚呈, 刘章, 周进, 邓佳杰, 王鑫, 吴贲华, 章健, 王士维. 真空反应烧结制备米级尺寸钇铝石榴石(YAG)透明陶瓷[J]. 无机材料学报, 2023, 38(12): 1483-1484.
[8]	李文俊, 王皓, 涂兵田, 谌强国, 郑凯平, 王为民, 傅正义. 宽光谱透过Mg_0.9Al_2.08O_3.97N_0.03透明陶瓷的制备与性能研究[J]. 无机材料学报, 2022, 37(9): 969-975.
[9]	母利成, 杨金萍, 王俊平, 赵瑾, 刘梦玮, 汪德文, 章健. 环氧树脂改性自发凝固成型制备YAG透明陶瓷[J]. 无机材料学报, 2022, 37(9): 941-946.
[10]	刘强, 王倩, 陈鹏辉, 李晓英, 章立轩, 谢腾飞, 李江. 两步烧结法制备红色Ce:8YSZ透明陶瓷及其性能研究[J]. 无机材料学报, 2022, 37(8): 911-917.
[11]	陈俊云, 孙磊, 靳田野, 罗坤, 赵智胜, 田永君. 无黏结剂层状BN增韧cBN刀具材料的研究[J]. 无机材料学报, 2022, 37(6): 623-628.
[12]	肖舒琳, 戴中华, 李定妍, 张凡博, 杨利红, 任晓兵. 氧化镧掺杂铌酸钾钠陶瓷的电、光性能研究[J]. 无机材料学报, 2022, 37(5): 520-526.
[13]	程梓秋, 王雁斌, 刘欣, 代正发, 陈昊鸿, 田丰, 陈鹏辉, 李江. 高功率激光照明用Al₂O₃-YAG:Ce复相陶瓷荧光体的组分设计与性能优化[J]. 无机材料学报, 2022, 37(12): 1358-1364.
[14]	徐小科, 邓明雪, 刘茜, 余建定, 周真真, 张翔, 贺欢. 可用于快速高温热处理的多束激光并行加热系统[J]. 无机材料学报, 2022, 37(1): 107-112.
[15]	荆延秋, 刘强, 苏莎, 李晓英, 刘子玉, 王静雅, 李江. 1.5 μm被动调Q可饱和吸收体用Co:MgAl ₂O₄透明陶瓷的制备[J]. 无机材料学报, 2021, 36(8): 877-882.