Sn对Ge-Se-Te玻璃结构与光学特性的影响

doi:10.3724/SP.J.1077.2014.13286

无机材料学报 ›› 2014, Vol. 29 ›› Issue (3): 279-283.DOI: 10.3724/SP.J.1077.2014.13286 CSTR: 32189.14.SP.J.1077.2014.13286

Sn对Ge-Se-Te玻璃结构与光学特性的影响

尹冬梅, 屠德阳, 车丙晨, 张芳芳, 林常规, 戴世勋

(宁波大学高等技术研究院, 红外材料与器件实验室, 宁波 315211)

收稿日期:2013-05-27 修回日期:2013-07-03 出版日期:2014-03-20 网络出版日期:2014-02-18
作者简介:尹冬梅(1987-), 女, 硕士研究生. E-mail: yindongmei@mail.nbu.edu.cn
基金资助:
国家自然科学基金(61177087);973计划项目子课题(2012CB722703);教育部新世纪优秀人才计划 (NCET-10-0976);浙江省杰出青年基金(R1101263);宁波市新型光电功能材料及器件创新团队(2009B21007);宁波大学王宽诚幸福基金

Effect of Sn Addition on the Structure and Optical Properties of Ge-Se-Te Chalcogenide Glasses

YIN Dong-Mei, TU De-Yang, CHE Bing-Chen, ZHANG Fang-Fang, LIN Chang-Gui, DAI Shi-Xun

(Laboratory of Infrared Materials and Devices, The Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China)

Received:2013-05-27 Revised:2013-07-03 Published:2014-03-20 Online:2014-02-18
About author:YIN Dong-Mei. E-mail: yindongmei@mail.nbu.edu.cn
Supported by:
National Natural Science Foundation of China (61177087);National Program on Key Basic Research Profect (973 Program)(2012CB722703) Program for New Century Excellent Talents in University (NCET-10-0976);Zhejiang Provincial Natural Science Foundation of China(R1101263);Program for Innovative Research Team of Ningbo City (2009B21007);K.C. Wong Magna Fund in Ningbo University

摘要/Abstract

摘要：

采用熔融淬冷法制备了系列Ge₃Se₅Te₂Sn_x(x=0、0.4、0.8、1.2、1.6、2.0, mol%)硫系玻璃。采用X射线衍射(XRD)图谱、差示扫描量热曲线(DSC)、可见/近红外光谱、傅里叶红外(FTIR)光谱、显微拉曼光谱等手段对玻璃的物化性能及结构进行表征, 研究发现Sn的引入导致Ge-Se-Te玻璃系统物化性能的变化: 玻璃的转变温度T_g降低、红外截止波长发生红移, 并有效地降低了杂质吸收峰对样品红外透过率的影响。利用Philips网络约束理论计算的玻璃平均配位数及拉曼光谱的变化, 讨论了引入Sn对Ge-Se-Te玻璃的影响。

关键词: 硫系玻璃, 热稳定性, 红外透过范围

Abstract:

A series of Ge₃Se₅Te₂Sn_x(x=0, 0.4, 0.8, 1.2, 1.6, 2.0, mol%) chalcogenide glasses were prepared by traditional melt-quenching method. The physiochemical properties and structure changes of glasses were characterized by employing the techniques of X-ray diffraction (XRD), differential scanning calorimetry (DSC), visible-near IR spectrum, Fourier transform infrared spectrum (FTIR), and Raman spectroscope. Physiochemical properties of Ge-Se-Te glasses change with the addition of Sn, including glass transition temperature (T_g) decreacing and infrared cut-off wavelength shifting toward long wavelength which effectively inhibits the absorption peaks of impurities in the mid-IR spectral region. In addition, the origination behind these phenomena is discussed by the average coordination number calculated from Philips network-constrained theory and structural evolution of Raman spectra.

Key words: chalcogenide glasses, thermal stability, infrared spectroscopy

中图分类号:

TQ171

尹冬梅, 屠德阳, 车丙晨, 张芳芳, 林常规, 戴世勋. Sn对Ge-Se-Te玻璃结构与光学特性的影响[J]. 无机材料学报, 2014, 29(3): 279-283.

YIN Dong-Mei, TU De-Yang, CHE Bing-Chen, ZHANG Fang-Fang, LIN Chang-Gui, DAI Shi-Xun. Effect of Sn Addition on the Structure and Optical Properties of Ge-Se-Te Chalcogenide Glasses[J]. Journal of Inorganic Materials, 2014, 29(3): 279-283.

图/表 4

图1 GSTSx系列玻璃的XRD图谱

Fig. 1 XRD patterns of GSTSxglass samples

表1 GSTSx玻璃样品的物化特性参数

Table1 Physiochemical properties of GSTSxglass samples BE* represents bandgap energy

Samples	T_g/±2℃	T_x/±2℃	ΔT/±2℃	BE*/eV	Z
GSTS0	277	370	93	1.046	2.60
GSTS0.4	265	365	100	0.957	2.65
GSTS0.8	239	360	121	0.879	2.70
GSTS1.2	220	350	130	0.819	2.75
GSTS1.6	225	321	96	0.791	2.79

图2 GSTSx玻璃样品的近红外透过光谱(a)和FTIR透过光谱(b)

Fig. 2 Near-infrared transmission spectra (a) and FTIR transmission spectra of GSTSx glass samples (b)

图3 GSTSx玻璃样品的约化拉曼谱

Fig. 3 Reduced Raman spectra of GSTSx glass samples

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Sn对Ge-Se-Te玻璃结构与光学特性的影响

Effect of Sn Addition on the Structure and Optical Properties of Ge-Se-Te Chalcogenide Glasses

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