一步水热模板法制备Cu-TiO2异质结构纳米粒子

doi:10.3724/SP.J.1077.2012.12188

无机材料学报 ›› 2012, Vol. 27 ›› Issue (9): 1003-1008.DOI: 10.3724/SP.J.1077.2012.12188 CSTR: 32189.14.SP.J.1077.2012.12188

• 研究快报 • 上一篇

一步水热模板法制备Cu-TiO₂异质结构纳米粒子

赵鹏君^1,2, 吴荣¹, 侯娟^1,2, 常爱民¹, 关芳^1,2, 张博^1,2

(1. 中国科学院新疆理化技术研究所, 新疆电子信息材料与器件重点实验室, 乌鲁木齐 830011; 2. 中国科学院研究生院, 北京 100049)

收稿日期:2012-03-27 修回日期:2012-05-11 出版日期:2012-09-20 网络出版日期:2012-08-28
作者简介:ZHAO Peng-Jun (1986–), male, candidate of master degree. E-mail: zhaopengjun110@163.com
基金资助:
“Western Light Joint Scholar Foundation” Program of Chinese Academy of Sciences( LHXZ200902); China Postdoctoral Science Foundation(20100471679, 201104704)

One-step Self Assemble of Cu-TiO₂ Heterogeneous Nanoparticles Using a Soft Template

ZHAO Peng-Jun^1,2, WU Rong¹, HOU Juan^1,2, CHANG Ai-Min¹, GUAN Fang^1,2, ZHANG Bo^1,2

(1. Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi 830011, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China)

Received:2012-03-27 Revised:2012-05-11 Published:2012-09-20 Online:2012-08-28
About author:ZHAO Peng-Jun (1986–), male, candidate of master degree. E-mail: zhaopengjun110@163.com
Supported by:
“Western Light Joint Scholar Foundation” Program of Chinese Academy of Sciences( LHXZ200902); China Postdoctoral Science Foundation(20100471679, 201104704)

摘要/Abstract

摘要： 以聚乙二醇(PEG)为软模板剂, 采用一步水热法合成了具有异质结构的铜–二氧化钛复合纳米粒子. 利用X射线衍射谱(XRD)、透射电子显微镜(TEM)等分别对制备材料的相组成、微观结构进行了研究. 结果表明, 一步水热法制备的异质纳米粒子由单一立方相铜和锐钛矿相二氧化钛组成. 高分辨透射电子显微镜(HRTEM)在单一粒子中观测到清晰的铜(101)和二氧化钛(111)晶面构成的界面. 该界面有助于二氧化钛光生电子–空穴对的分离. 同时, 所制备纳米粒子的颗粒尺寸和光吸收特性可以通过改变PEG分子链长进行微调. 本研究还对水热过程的反应机理进行了讨论, 结果表明: PEG与铜氨络合物通过氢键连接, 其链长对于粒子尺寸的影响在于PEG对Cu颗粒的尺寸进行的调节, 而此过程中二氧化钛的晶粒尺寸并无明显变化. 紫外–可见吸收光谱表明该异质纳米粒子与普通二氧化钛纳米粉体相比, 对可见光区光谱有较为强烈的吸收. 该界面纳米材料是一种有潜在应用价值的光催化材料和太阳能电池材料.

关键词: Cu-TiO₂, PEG, 异质结构, 水热, 可见光吸收

Abstract: Cu-TiO₂ heterostructure nanoparticles were successfully synthesized via a novel one-step self-assemble hydrothermal method using polyethylene glycol as the soft template. The nanospheres were characterized in light of the chemical composition and morphology using X-ray diffraction (XRD) and transmission electron microscope (TEM), respectively. The products are composed of cubic copper and anatase TiO₂. Interfaces between Cu (101) and TiO₂ (111) were observed by HRTEM. In addition, the nanoparticles size could be controlled by adjusting the polymerization degrees of PEG. The accommodations of the particle sizes were mainly caused by Cu nanospheres rather than TiO₂. A possible synthetic mechanism which interprets the formation of Cu-TiO₂ heterogeneous nanoparticles could be ascribed to the hydrogen bonds between Cu(NH₃)²⁺ and PEG. UV-Vis absorption spectra indicated that the prepared product has strong absorbency in the visible region. Therefore, the unique interface nanomaterial could be used as a potential class of the materials platform as visible-light-driven photocatalyst and electrode on enhancing the photoelectric properties of solar cells.

Key words: Cu-TiO₂, PEG, heterogeneous, hydrothermal method, visible-light absorption

中图分类号:

O643

赵鹏君, 吴荣, 侯娟, 常爱民, 关芳, 张博. 一步水热模板法制备Cu-TiO₂异质结构纳米粒子 [J]. 无机材料学报, 2012, 27(9): 1003-1008.

ZHAO Peng-Jun, WU Rong, HOU Juan, CHANG Ai-Min, GUAN Fang, ZHANG Bo. One-step Self Assemble of Cu-TiO₂ Heterogeneous Nanoparticles Using a Soft Template[J]. Journal of Inorganic Materials, 2012, 27(9): 1003-1008.

参考文献

[1] Zhang H, Yu H, Han Y, et al. Rutile TiO2 microspheres with exposed nano-acicular single crystals for dye-sensitized solar cells. Nano Res., 2011, 4(10): 938–947.

[2] Yella A, Lee H W, Tsao H N, et al. Porphyrin-sensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency. Science, 2011, 334(6056): 629–634.

[3] Yoon S, Manthiram A. Hollow core-shell mesoporous TiO2 spheres for lithium ion storage. J. Phys. Chem. C, 2011, 115(19): 9410–9416.

[4] Wang J, Zhou Y, Hu Y, et al. Facile synthesis of nanocrystalline TiO2 mesoporous microspheres for lithium-ion batteries. J. Phys. Chem. C, 2011, 115(5): 2529–2536.

[5] Zhao X, Liu M, Zhu Y. Fabrication of porous TiO2 film via hydrothermal method and its photocatalytic performances. Thin Solid Films, 2007, 515(18): 7127–7134.

[6] Zhang W, Zou L, Wang L. Photocatalytic TiO2/adsorbent nanocomposites prepared via wet chemical impregnation for wastewater treatment: a review. Appl. Catal. A, 2009, 371(1/2): 1–9.

[7] Li N, Liu G, Zhen C, et al. Battery performance and photocatalytic activity of mesoporous anatase TiO2 nanospheres/graphene composites by template-free self-assembly. Adv. Funct. Mater., 2011, 21(9): 1717–1722.

[8] Wang N, Han L, He, H, et al. A novel high-performance photovoltaic–thermoelectric hybrid device. Energy Environ. Sci., 2011, 4(9): 3676–3679.

[9] Wang D, Yu B, Wang C, et al. A novel protocol toward perfect alignment of anodized TiO2 nanotubes. Adv. Mater., 2009, 21(19): 1964–1967.

[10] Wang H, Miyauchi M, Ishikawa Y, et al. Single-crystalline rutile TiO2 hollow spheres: room-temperature synthesis, tailored visible- light-extinction, and effective scattering layer for quantum dot-sensitized solar cells. J. Am. Chem. Soc., 2011, 133(47): 19102–19109.

[11] Chen X, Mao S S. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev., 2007, 107(7): 2891–2959.

[12] Jung H G, Yoon C S, Prakash J, et al. Mesoporous anatase TiO2 with high surface area and controllable pore size by F ion doping: applications for high-power Li-ion battery anode. J. Phys. Chem. C, 2009, 113(50): 21258–21263.

[13] Yuan J, Wang E, Chen Y, et al. Doping mode, band structure and photocatalytic mechanism of B–N-codoped TiO2. Appl. Surf. Sci., 2011, 257(16): 7335–7342.

[14] Liu G, Wang X, Chen Z, et al. The role of crystal phase in determining photocatalytic activity of nitrogen doped TiO2. J. Colloid Interface Sci., 2009, 329(2): 331–338.

[15] Zhen J W, Bhattcahrayya A, Wu P, et al. The origin of visible light absorption in chalcogen element (S, Se, and Te)-doped anatase TiO2 photocatalysts. J. Phys. Chem. C, 2010, 114(15): 7063–7069.

[16] Wang D, Liu Y, Wang C, et al. Highly flexible coaxial nanohybrids made from porous TiO2 nanotubes. ACS Nano, 2009, 3(5): 1249–1257.

[17] Wang Q, Zhu K, Reale N R, et al. Constructing ordered sensitized heterojunctions: bottom-up electrochemical synthesis of p-type semiconductors in oriented n-TiO2 nanotube arrays. Nano Lett., 2009, 9(2): 806–813.

[18] Tanabe I, Matsubara K, Sakai N, et al. Photoelectrochemical and optical behavior of single upright Ag nanoplates on a TiO2 film. J. Phys. Chem. C, 2011, 115(5): 1695–1701.

[19] Wu X F, Song H Y, Yoon J M, et al. Synthesis of core-shell Au@TiO2 nanoparticles with truncated wedge-shaped morphology and their photocatalytic properties. Langmuir, 2009, 25(11): 6438–6447.

[20] Park W Y, Kim G H, Seok J Y, et al. A Pt/TiO2/Ti Schottky-type selection diode for alleviating the sneak current in resistance switching memory arrays. Nanotechnology, 2010, 21(19): 195201–1–5.

[21] Zheng Z, Huang B, Qin X, et al. Facile in situ synthesis of visible- light plasmonic photocatalysts M@TiO2(M = Au, Pt, Ag) and evaluation of their photocatalytic oxidation of benzene to phenol. J. Mater. Chem., 2011, 21: 9079–9087.

[22] Zhang L, Xia D, Shen Q. Synthesis and characterization of Ag@TiO2 core-shell nanoparticlesand TiO2 nanobubbles. J. Nanopart. Res., 2006, 8(1): 23–28.

[23] Feng C, Zhang J, Lang R, et al. Unusual photo-induced adsorption– desorption behavior of propylene on Ag/TiO2 nanotube under visible light irradiation. Appl. Surf. Sci., 2011, 257(6): 1864–1870.

[24] Sun Y H, Zhang M, Dong F, et al. Effect of Cl? anions on photocatalytic decomposition of gaseous ozone over Au@Ag/TiO2 catalyst. Res. Chem. Intermed., 2009, 35(6/7): 817–826.

[25] Cui Y, Liu L, Li B, et al. Fabrication of tunable core-shell structured TiO2 mesoporous microspheres using linear polymer polyethylene glycol as templates. J. Phys. Chem. C, 2010, 114(6): 2434–2439.

[26] Chastain J, Moulder J F, Stickle W F, et al. Handbook of X-ray Photoelectron Spectroscopy. Perkin-Elmer Corporation. 1992: 44–45, 72–74.

[27] Xu S, Ng J, Zhang X, et al. Fabrication and comparison of highly efficient Cu incorporated TiO2 photocatalyst for hydrogen generation from water. Int J. Hydrogen. Energy, 2010, 35(11): 5254–5261.

一步水热模板法制备Cu-TiO₂异质结构纳米粒子

One-step Self Assemble of Cu-TiO₂ Heterogeneous Nanoparticles Using a Soft Template

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